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Lanthanum Effect on the Isothermal High Temperature Oxidation Behavior at 1,000 °C of a Phosphoric Acid-Treated AISI 304 Stainless Steel

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Abstract

Many studies have shown that a phosphoric-acid treatment improves the high temperature oxidation resistance in air of some alloys. Interestingly, though, the phosphoric-acid treatment generates a structural modification of the steel surface which is catastrophic for the high-temperature oxidation behavior at 1,000 °C. The aim of our work was to test the effect of a reactive element sol–gel coating on high-temperature oxidation resistance of phosphoric acid-treated AISI 304 steel. The oxide scale growth mechanisms were studied by exposing La-coated and uncoated phosphoric acid-treated 304 steel samples to high-temperature conditions in air. A phosphoric-acid treatment modified the structural composition and the surface morphology of the AISI 304 steel by the formation of a FeH2P3O10 structure, leading to hematite formation and to a breakaway phenomenon. Lanthanum coating, after initial phosphoric-acid treatment, led to the formation of LaCrO3 which limited through-scale cracking and reduced the growth of iron oxides.

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Authors and Affiliations

  1. Laboratoire Vellave sur l’Elaboration et l’Etude des Matériaux—E.A. 3864, Département de Chimie—Science des Matériaux, Clermont Université-UdA—Institut Universitaire de Technologie, 8 rue J.B. Fabre, B.P. 70219, 43006, Le Puy-en-Velay, France

    Frederic Riffard, Jeremie Fondard, Philippe Moulin, Sebastien Perrier & Henri Buscail

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  1. Frederic Riffard
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  2. Jeremie Fondard
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  3. Philippe Moulin
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  4. Sebastien Perrier
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  5. Henri Buscail
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Correspondence to Frederic Riffard.

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Riffard, F., Fondard, J., Moulin, P. et al. Lanthanum Effect on the Isothermal High Temperature Oxidation Behavior at 1,000 °C of a Phosphoric Acid-Treated AISI 304 Stainless Steel. Oxid Met 81, 191–201 (2014). https://doi.org/10.1007/s11085-013-9455-2

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  • DOI: https://doi.org/10.1007/s11085-013-9455-2

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