Skip to main content
Log in

Preparation and photocatalytic activity of Mo-doped WO3 nanowires

  • Research Paper
  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

Mo-doped WO3 nanowires were fabricated by a hydrothermal method in the presence of K2SO4. The physical properties of prepared nanowires were characterized by X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results show that the obtained products are nanowires with diameters ranging between 10 and 20 nm, and lengths of about 600 nm. Its photoactivity was evaluated through the photodegradation of methylene blue (MB) in aqueous solution. Effects of the molybdenum concentration on the photoactivity of the obtained samples were investigated detailedly. The experimental results indicated that the Mo-doping enhanced the photoactivity of WO3 nanowires.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig.3
Fig. 4
Fig. 5
Fig. 6
Fig.7
Fig. 8

Similar content being viewed by others

References

  • Bamwenda GR, Arakawa H (2001) The visible light induced photocatalytic activity of tungsten trioxide powders. Appl Catal A 210:181–191

    Article  CAS  Google Scholar 

  • Chen CC (2007) Degradation pathways of ethyl violet by photocatalytic reaction with ZnO dispersions. J Mol Catal A 264:82–89

    Article  CAS  Google Scholar 

  • Gondal MA, Sayeed MN, Arfaj A (2007) Activity comparison of Fe2O3, NiO, WO3 and TiO2 semiconductor catalysts in phenol degradation by laser enhanced photo-catalytic process. Chem Phys Lett 445:325–330

    Article  CAS  ADS  Google Scholar 

  • Gondal MA, Dastageer A, Khalil A (2009) Synthesis of nano-WO3 and its catalytic activity for enhanced antimicrobial process for water purification using laser induced photo-catalysis. Catal Comm 11:214–219

    Article  CAS  Google Scholar 

  • Gu G, Zheng B, Han WQ, Roth S, Liu J (2002) Tungsten oxide nanowires on tungsten substrates. Nano Lett 2:849–851

    Article  CAS  ADS  Google Scholar 

  • Guo Y, Quan X, Lu N, Zhao H, Chen S (2007) High photocatalytic capability of selfassembled nanoporous WO3 with preferential orientation of (002) planes. Environ Sci Technol 41:4422–4427

    Article  CAS  PubMed  Google Scholar 

  • Lee K, Seo WS, Park JT (2003) Synthesis and optical properties of colloidal tungsten oxide nanorods. J Am Ceram Soc 125:3408–3409

    CAS  Google Scholar 

  • Li XL, Lou TJ, Sun XM, Li YD (2004) Highly sensitive WO3 hollow-sphere gas sensors. Inorg Chem 43:5442–5449

    Article  CAS  PubMed  Google Scholar 

  • Liu H, Peng T, Ke D, Peng Z, Yan C (2007) Preparation and photocatalytic activity of dysprosium doped tungsten trioxide nanoparticles. Mater Chem Phys 104:377–383

    Article  CAS  Google Scholar 

  • Liu Y, Zhang YC, Xu XF (2009) Hydrothermal synthesis and photocatalytic activity of CdO2 nanocrystals. J Hazard Mater 163:1310–1314

    Article  CAS  PubMed  Google Scholar 

  • Qamar M, Gondal MA, Hayat K, Yamani ZH, Al-Hooshani K (2009a) Laser-induced removal of a dye C.I. Acid Red 87 using n-type WO3 semiconductor catalyst. J Hazard Mater 170:584–589

    Article  CAS  PubMed  Google Scholar 

  • Qamar M, Gondal MA, Yamani ZH (2009b) Synthesis of highly active nanocrystalline WO3 and its application in laser-induced photocatalytic removal of a dye from water. Catal Comm 10:1980–1984

    Article  CAS  Google Scholar 

  • Stengl V, Bakardjieva S, Murafa N (2009) Preparation and photocatalytic activity of rare earth doped TiO2 nanoparticles. Mater Chem Phys 114:217–226

    Article  CAS  Google Scholar 

  • Wang HY, Xu P, Wang TM (2002) The preparation and properties study of photocatalytic nanocrystalline/nanoporous WO3 thin films. Mater Des 23:331–336

    CAS  Google Scholar 

  • Wang S, Shi X, Shao G, Duan X, Yang H, Wang T (2008) Preparation, characterization and photocatalytic activity of multi-walled carbon nanotube-supported tungsten trioxide composites. J Phys Chem Solids 69:2396–2400

    Article  CAS  ADS  Google Scholar 

  • Xin G, Guo W, Ma T (2009) Effect of annealing temperature on the photocatalytic activity of WO3 for O2 evolution. Appl Surf Sci 256:165–169

    Article  CAS  ADS  Google Scholar 

  • Yu J, Qi L (2009) Template-free fabrication of hierarchically flower-like tungsten trioxide assemblies with enhanced visible-light-driven photocatalytic activity. J Hazard Mater 169:221–227

    Article  CAS  PubMed  Google Scholar 

  • Yu JG, Su YR, Cheng B (2007) Template-free fabrication and enhanced photocatalytic activity of hierarchical macro-/mesoporous titania. Adv Funct Mater 17:1984–1990

    Article  CAS  Google Scholar 

  • Yu J, Qi L, Cheng B, Zhao X (2008a) Effect of calcination temperatures on microstructures and photocatalytic activity of tungsten trioxide hollow microspheres. J Hazard Mater 160:621–628

    Article  CAS  PubMed  Google Scholar 

  • Yu JG, Yu HG, Guo HT, Li M, Mann S (2008b) Spontaneous formation of a tungsten trioxide sphere-in-shell superstructure by chemically induced selftransformation. Small 4:87–91

    Article  CAS  PubMed  Google Scholar 

  • Yu J, Yu X, Huang B, Zhang X, Dai Y (2009) Hydrothermal synthesis and visible-light photocatalytic activity of novel cage-like ferric oxide hollow spheres. Cryst Growth Des 9:1474–1480

    Article  CAS  Google Scholar 

  • Zhang M, An T, Hu X, Wang C, Sheng G, Fu J (2004) Preparation and photocatalytic properties of a nanometer ZnO-SnO2 coupled oxide. Appl Catal A 260:215–222

    Article  CAS  Google Scholar 

  • Zhao X, TL Cheung Y, Zhang X, Ng DHL, Yu J (2006) Facile preparation of strontium tungstate and tungsten trioxide hollow spheres. J Am Ceram Soc 89:2960–2963

    CAS  Google Scholar 

  • Zhu YQ, Hu W, Hsu WK, Terrones M, Grobert N, Hare JP, Kroto HW, Walton DRM, Terrones H (1999) Tungsten oxide tree-like structures. Chem Phys Lett 309:327–334

    Article  CAS  ADS  Google Scholar 

Download references

Acknowledgment

We wish to acknowledge the financial support from the National Natural Science Foundation of China (no. 20873020).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xu Chun Song.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Song, X.C., Yang, E., Liu, G. et al. Preparation and photocatalytic activity of Mo-doped WO3 nanowires. J Nanopart Res 12, 2813–2819 (2010). https://doi.org/10.1007/s11051-010-9859-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11051-010-9859-8

Keywords

Navigation