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Structure of iron-carbon melts. About stability of cementite in melts

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Metal Science and Heat Treatment Aims and scope

A model of the structure of Fe – Fe3 C melts in the temperature range 1300 – 1700°C is developed on the basis of recent experimental data. In accordance with the model, the solubility of carbon in liquid iron is limited (about 2%). Stable dispersed particles of the second phase (cementite) form in the melt at a higher carbon content.

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References

  1. G. N. Elanskii and D. G. Elanskii, Structure and Properties of Metallic Melts [in Russian], MGVMI, Moscow (2006).

    Google Scholar 

  2. A. A. Vertman and A. M. Samarin, Properties of Iron Melts [in Russian], Nauka, Moscow (1969).

    Google Scholar 

  3. Yu. L. Kirillov, Phase Diagram of the Iron – Carbon System [in Russian], Metallurgizdat, Moscow (1953).

    Google Scholar 

  4. V. M. Zamyatin, A Study of Properties of Iron-Carbon Melts, Author’s Abstract of Candidate’s Thesis [in Russian], UPI, Sverdlovsk (1977).

  5. M. V. Voloshchenko, et al., “A study of the structure of iron melts,” Litein. Proizvod., No. 2, 5 – 8 (1976).

  6. A. G. Prigunova and S. S. Petrov, “Precision study of microinhomogeneous melts,” Probl. Metallurg. Proizv., No. 101, 99 – 103 (1990).

  7. A. G. Prigunova, Yu. N. Taran, and S. S. Petrov, “A method for computing microgroups in melts from results of sedimentation analysis,” Rasplavy, No. 5, 3 – 8 (1991).

  8. I. V. Sally, Physical Fundamentals of Structure Formation in Melts [in Russian], Metallurgiya, Moscow (1963).

    Google Scholar 

  9. R. Ruhl and M. Cohen, “Splat quenching of iron – carbon alloys,” Trans. Met. Soc. AIME, 245, 241 – 249 (1969).

    CAS  Google Scholar 

  10. V. S. Kraposhin and K. V. Shalevich, “Phase composition of iron-carbon alloys after hardening from liquid state,” Metally, No. 5, 107 – 112 (1989).

  11. A. S. Aronin, V. S. Kraposhin, and K. V. Shalevich,” “Structure of high-carbon iron alloys after hardening from liquid state,” Metallofizika, 12(4) (1990).

  12. I. S. Miroshnichenko, Hardening from Liquid State [in Russian], Metallurgiya, Moscow (1982).

    Google Scholar 

  13. Hosen Ry and V. I. Rimland, “A study of properties of rapidly hardened cast iron,” Metally, No. 4, 8 – 10 (1987).

  14. V. M. Zalkin, The Nature of Eutectic Alloys and the Effect of Contact Melting [in Russian], Metallurgiya, Moscow (1987).

    Google Scholar 

  15. B. A. Melnik, “An x-ray study of the structure of liquid iron,” Metally, No. 6, 52 – 54 (1981).

  16. B. A. Melnik, “An x-ray study of the structure of iron-carbon melts,” Metally, No. 4, 42 – 46 (1979).

  17. V. M. Zalkin, “About the nature of eutectics,” Zh. Fiz. Khim., 40(10), 2655 – 2658 (1966).

    CAS  Google Scholar 

  18. V. M. Zalkin, “About the structure of melts in binary metallic systems with eutectic phase diagram,” Zh. Fiz. Khim., 46(1), 8 – 12 (1972).

    CAS  Google Scholar 

  19. V. M. Zalkin, “About the recent state of the theory of eutectics,” Zh. Fiz. Khim., 58(6), 1320 – 1328 (1984).

    CAS  Google Scholar 

  20. V. M. Zalkin, “About the structure of liquid irons,” Litein. Proizvod., No. 8, 5 – 7 (1984).

  21. V. M. Zalkin, “Some concepts of the theory of eutectic alloys,” Metalloved. Term. Obrab. Met., No. 4, 3 – 10 (2009).

  22. A. G. Il’inskii, S. I. Slyusarenko, and V. Hoyer, “Structure of Ge-Te alloys in liquid state,” Metallofizika, 14(12), 35 – 42 (1992).

    Google Scholar 

  23. A. G. Il’inskii, V. A. Korobov, and S. I. Slyusarenko, “A model of microinhomogeneous structure of liquid alloys,” Metallofizika, 15(5), 87 – 93 (1993).

    Google Scholar 

  24. Ya. I. Dutchak, N. M. Klym, and S. I. Mudryi, “A study of Tl – Te alloys,” Zh. Fiz. Khim., 54(4), 875 – 880 (1980).

    CAS  Google Scholar 

  25. S. Steeb and H. Entress, Z. Metallkunde, 57 (1966).

  26. N. A. Vatolin and E. A. Pastukhov, Diffraction Studies of the Structure of High-Temperature Melts [in Russian], Nauka, Moscow (1980).

    Google Scholar 

  27. W. Knoll and S. Steeb, Phys. Chem. Liquids, 4(1) (1973).

  28. V. I. Dobatkin and V. I. Elagin, Granulated Aluminum Alloys [in Russian], Metallurgiya, Moscow (1981).

    Google Scholar 

  29. V. S. Kraposhin and S. D. Sil’chenkov, “What is the difference between martensitic and normal transformations,” Metalloved. Term. Obrab. Met., No. 11, 28 – 36 (2008).

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Correspondence to V. S. Kraposhin.

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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 1, pp. 15 – 18, January, 2010.

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Zalkin, V.M., Kraposhin, V.S. Structure of iron-carbon melts. About stability of cementite in melts. Met Sci Heat Treat 52, 3–6 (2010). https://doi.org/10.1007/s11041-010-9221-x

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