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Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide

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Abstract

The enthalpies of dissolution for 5,5′-Bistetrazole-1, 1′-dihydroxy ((H2O)2BTO) and disodium 5,5′-Bistetrazole-1,1′-diolate ([Na2(H2O)4]BTO) in dimethyl sulfoxide (DMSO) at 298.15 K were studied by using a C-80 Calvet microcalorimeter. Empirical formulae for the calculation of the molar enthalpies of dissolution (Δdiss H), relative partial molar enthalpies (Δdiss H partial), and relative apparent molar enthalpies (Δdiss H apparent) were deduced by the experimental results of the dissolution processes of (H2O)2BTO and [Na2(H2O)4]BTO in DMSO. Finally, the corresponding kinetic equations describing the dissolution processes were dα/dt = 10−2.60(1−α)0.61 for the dissolution of (H2O)2BTO in DMSO, and dα/dt = 10−2.69(1−α)0.62 for the dissolution of [Na2(H2O)4]BTO in DMSO.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

    Hu Niu, Shusen Chen, Shaohua Jin, Lijie Li, Xiaojun Wang, Chunyuan Zhang, Haoming Zou & Qinghai Shu

  2. Research Institute of Gansu Yin’guang Chemical Industry Group, Baiyin, China

    Xiaojun Wang

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  1. Hu Niu
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  2. Shusen Chen
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  3. Shaohua Jin
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  4. Lijie Li
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  6. Chunyuan Zhang
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  7. Haoming Zou
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  8. Qinghai Shu
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Correspondence to Qinghai Shu.

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Niu, H., Chen, S., Jin, S. et al. Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide. J Therm Anal Calorim 128, 615–620 (2017). https://doi.org/10.1007/s10973-016-5909-5

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  • DOI: https://doi.org/10.1007/s10973-016-5909-5

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