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Experimental and theoretically estimated excess molar enthalpies for tert-butyl methyl ether+ 1-pentanol+octane at 298.15 K

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Abstract

Forming part of the scientific project entitled ‘Study on physical properties of mixtures hydrocarbon+alcohol+ether like alternative fuels’, the present article reports experimental data of excess molar enthalpies for the ternary mixture {x 1 tert-butyl methyl ether (MTBE)+x 21-pentanol+(1−x 1−x 2)octane} and the involved binary mixture {x 1-pentanol+(1−x) octane} at the temperature of 298.15 K and atmospheric pressure. No experimental excess enthalpy values were found in the currently available literature for the ternary mixture under study. The group contribution model of the UNIFAC (in the versions of Larsen, and Gmehling) were used to estimate excess enthalpy values. Several empirical expressions for estimating ternary properties from binary results were also tested.

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Authors and Affiliations

  1. Departamento de Física Aplicada, Universidade de Santiago, Campus Universitario Sur, 15782, Santiago de Compostela, Spain

    P. V. Verdes & María Inmaculada Paz Andrade

  2. Departamento de Física Aplicada, Facultade de Ciencias, Universidade de Vigo, 36200, Vigo, Spain

    Marta M. Mato & J. L. Legido

  3. Departamento de Física, Facultade de Ciencias, Campus A Zapateira, Universidade de A Coruña, 15070, A Coruña, Spain

    E. Jiménez

Authors
  1. P. V. Verdes
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  2. Marta M. Mato
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  3. E. Jiménez
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  4. J. L. Legido
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  5. María Inmaculada Paz Andrade
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Correspondence to María Inmaculada Paz Andrade.

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Verdes, P.V., Mato, M.M., Jiménez, E. et al. Experimental and theoretically estimated excess molar enthalpies for tert-butyl methyl ether+ 1-pentanol+octane at 298.15 K. J Therm Anal Calorim 89, 73–79 (2007). https://doi.org/10.1007/s10973-006-8308-5

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  • DOI: https://doi.org/10.1007/s10973-006-8308-5

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