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Experimental excess molar volumes of the ternary mixture and comparisonwith several empirical methods

Tert-butylmethylether+1-propanol+nonane at 298.15 K

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Abstract

Experimental excess molar volumes for the ternary system {x 1MTBE+x 21-propanol+(1–x 1–x 2)nonane} and the three involved binary mixtures have been determined at 298.15 K and atmospheric pressure. Excess molar volumes were determined from the densities of the pure liquids and mixtures, using a DMA 4500 Anton Paar densimeter.

The ternary mixture shows maximum values around the binary mixture MTBE+nonane and minimum values for the mixture MTBE+propanol. The ternary contribution to the excess molar volume is negative, with the exception of a range located around the rich compositions of 1-propanol.

Several empirical equations predicting ternary mixture properties from experimental binary mixtures have been applied.

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Authors and Affiliations

  1. Departamento de Física Aplicada, Facultad de Físicas, Campus Universitario Sur, Universidad de Santiago de Compostela, Santiago de Compostela, Spain, 15782

    Cebreiro S. M. & Paz Andrade M. I.

  2. Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Vigo, Vigo, Spain, 36200

    Mato M. M. & Legido J. L.

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  1. Mato M. M.
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  2. Cebreiro S. M.
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  3. Legido J. L.
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  4. Paz Andrade M. I.
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Correspondence to Paz Andrade M. I..

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Mato, M.M., Cebreiro, S.M., Legido, J.L. et al. Experimental excess molar volumes of the ternary mixture and comparisonwith several empirical methods. J Therm Anal Calorim 84, 279–283 (2006). https://doi.org/10.1007/s10973-005-7287-2

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