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Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III)

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Abstract

Thermal decomposition of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III), of general formula [(C2H5)4N][FeBr4−nCln] (n=1, 3, 4), has been studied using the TG-MS, DTA and DTG techniques. The measurements were carried out in an argon atmosphere over the temperature range 293–1073 K. Solid products of the thermal decomposition were identified by Mössbauer spectroscopy.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Gdańsk, Sobieskiego 18, 80-952, Gdańsk, Poland

    D. Wyrzykowski & Z. Warnke

  2. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Cracow, Poland

    Agnieszka Pattek-Janczyk & Katarzyna Zaremba

  3. Institute of General and Ecological Chemistry, Technical University of Łódź, Żwirki 36, 90-924, Łódź, Poland

    T. Maniecki

Authors
  1. D. Wyrzykowski
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  2. Agnieszka Pattek-Janczyk
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  3. T. Maniecki
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  4. Katarzyna Zaremba
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  5. Z. Warnke
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Correspondence to Z. Warnke.

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Wyrzykowski, D., Pattek-Janczyk, A., Maniecki, T. et al. Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III). J Therm Anal Calorim 91, 279–284 (2008). https://doi.org/10.1007/s10973-006-8269-8

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  • DOI: https://doi.org/10.1007/s10973-006-8269-8

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