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Thermal behavior of ammonium octafluorodirhenate(III)

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Abstract

The thermal behavior of (NH4)2[Re2F8]·2H2O salt was studied in the temperature range 150–700 °C under flowing nitrogen gas. The decomposition products were studied by powder X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Results are consistent with the formation of (NH4)2[Re2F8] salt at 150 °C, amorphous rhenium metal at 300 and 400 °C, and crystalline rhenium metal at 500 and 700 °C. A mechanism of formation of rhenium metal from (NH4)2[Re2F8]·2H2O was proposed. The effect of crystallite size and lattice strain was evaluated at 500 and 700 °C from powder XRD peak broadenings using both Williamson–Hall and the modified Scherrer methods.

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Acknowledgements

Thanks are due to Jonathan George for technical assistance. This material is based upon work performed under the auspices of the Consortium on Nuclear Security Technologies (CONNECT) supported by the Department of Energy/National Nuclear Security Administration under Award Number DE-NA0003948. In addition, part of this material is based upon work supported by the Department of Energy National Nuclear Security Administration through the Nuclear Science and Security Consortium under Award Number DE-NA0003180.

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  1. Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Parkway, Las Vegas, NV, 89154, USA

    James Louis-Jean, Harry Jang & Frederic Poineau

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  1. James Louis-Jean
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  2. Harry Jang
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Correspondence to James Louis-Jean or Frederic Poineau.

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Louis-Jean, J., Jang, H. & Poineau, F. Thermal behavior of ammonium octafluorodirhenate(III). Res Chem Intermed 49, 371–379 (2023). https://doi.org/10.1007/s11164-022-04867-7

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