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Thermal decomposition of ammonium perchlorate in the presence of bimetallic additives

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Abstract

The catalytic activity of the thermolysis products of double complex compounds in the decomposition reaction of ammonium perchlorate was studied. The products used are C1.4N1.6H3CoFe (I), C6N8Co4Fe3 (II), O11Co4Fe3 (III), O8.5(CN)0.3Cu3Fe2 (IV), and reactive CuO. All active phases decrease the temperature of complete decomposition of NH4ClO4, and the order of temperature decreasing is the following: III (120 °C) > IV > III (80 °C) ≫ CuO.

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Correspondence to D. P. Domonov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1041–1044, June, 2018.

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Domonov, D.P., Pechenyuk, S.I. Thermal decomposition of ammonium perchlorate in the presence of bimetallic additives. Russ Chem Bull 67, 1041–1044 (2018). https://doi.org/10.1007/s11172-018-2177-5

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  • DOI: https://doi.org/10.1007/s11172-018-2177-5

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