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Kinetic studies of the crystallization process of glass-ceramics based on basalt

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Abstract

The crystallization kinetic of the basalt glass ceramic of the oxide composition, (%): SiO2 − 50.82; Al2O3 − 12.05; Fe2O3 − 9.28; CaO − 15.48; MgO − 11.08; Na2O+K2O − 1.14; TiO2 − 0.15, with addition of 10% TiO2 as nucleating agent has been studied using thermal analysis under non-isothermal conditions.

In this order, the non-isothermal DTA curves were obtained at different heating rates between 4 and 20°C min−1 in the temperature range of 25–1000°C using a Derivatograph-C (MOM, Hungary). The kinetic parameters of the crystallization process were calculated on the basis of Ozawa-Flynn-Wall, Friedman, Budrugeac-Segal and non-parametric kinetic methods.

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Authors and Affiliations

  1. Research Center ‘Thermal Analysis in the Environmental Field, West University of Timişoara, Str. Pestalozzi 16, 300115, Timişoara, Romania

    T. Vlase

  2. Faculty of Industrial Chemistry and Environmental Engineering, University Politehnica of Timişoara, P-ţa Victoriei no. 2, 300006, Timişoara, Romania

    C. Pǎcurariu, R. I. Lazǎu & I. Lazǎn

Authors
  1. T. Vlase
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  2. C. Pǎcurariu
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  3. R. I. Lazǎu
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  4. I. Lazǎn
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Correspondence to T. Vlase.

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Vlase, T., Pǎcurariu, C., Lazǎu, R.I. et al. Kinetic studies of the crystallization process of glass-ceramics based on basalt. J Therm Anal Calorim 88, 625–629 (2007). https://doi.org/10.1007/s10973-006-8016-1

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