Skip to main content
SpringerLink
Log in

The crystallization kinetics of the Bi2O3-added MgO–Al2O3–SiO2–TiO2 glass ceramics system produced from industrial waste

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

In this study, the influence of Bi2O3 on the crystallization kinetics of the MgO–Al2O3–SiO2–TiO2 glass ceramics system produced from industrial waste was investigated. The Bi2O3-added MgO–Al2O3–SiO2–TiO2 glass ceramics systems were prepared by melting method. The crystallization behaviour and crystallization kinetics of a sample with glass ceramic composition were examined. DTA and XRD analysis revealed the crystallization of Ca0.965Mg2Al16O27 cordierite (Mg2Al4Si5O18) and Fe2TiO5 phases. The activation energy for the crystallization of cordierite phase has been evaluated, and the crystallization mechanism has been studied by applying DTA measurements taken at various heating rates. The results indicate that the dominant crystallization mechanism for this system is bulk crystallization dominated by three-dimensional growth. At 2.5, 5 and 10% Bi2O3 addition, the crystallization activation energy was calculated to be 336 ± 4, 218 ± 1 and 170 ± 3 kJ mol−1, and the viscous flow activation energy was measured to be 377 ± 2, 403 ± 7 and 407 ± 21 kJ mol−1, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Wang J, Liu C, Zhang G, Xie J, Han J, Zhao X. Crystallization properties of magnesium aluminosilicate glass-ceramics with and without rare-earth oxides. J Non-Cryst Solids. 2015;419:1–5.

    Article  CAS  Google Scholar 

  2. Almeida EP, Brito IP, Ferreira HC, Lira HL, Santana LNL, Neves GA. Cordierite obtained from compositions containing kaolin waste, talc and magnesium oxide. Ceram Int. 2018;44:10984–89.

    Article  CAS  Google Scholar 

  3. Njoya D, Elimbi A, Fouejio D, Hajjaji M. Effects of two mixtures of kaolin-talc-bauxite and firing temperatures on the characteristics of cordierite- based ceramics. J Build Eng. 2016;8:99–106.

    Article  Google Scholar 

  4. Aşkın A, Tatar İ, Kılınç Ş, Tezel Ö. The utilization of waste Magnesite in the production of the cordierite ceramic. Energy Proc. 2017;107:137–43.

    Article  CAS  Google Scholar 

  5. Chen G-H, Liu X-Y. Sintering, crystallization and properties of MgO–Al2O3 –SiO2 system glass-ceramics containing ZnO. J Alloys Compd. 2007;431:282–6.

    Article  CAS  Google Scholar 

  6. Goel A, Shaaban ER, Melo FCL, Ribeiro MJ, Ferreira JMF. Non-isothermal crystallization kinetic studies on MgO–Al2O3–SiO2–TiO2 glass. J Non-Cryst Solids. 2007;353:2383–91.

    Article  CAS  Google Scholar 

  7. Djordjević N. Influence of Bi2O3 on sintering and crystallization of cordierite ceramics. Sci Sinter. 2005;37:189–97.

    Article  CAS  Google Scholar 

  8. Zang P, Gao L, Yuan Q, Peng H, Ren X, Zhang D. Crystallization behaviour and performance of MgO–Al2O3 –SiO2 glass-ceramics by sintering. Adv Mater Res. 2010;92:65–71.

    Article  CAS  Google Scholar 

  9. Dittmer M, Müller M, Rüssel C. Self-organized nanocrystallinity in MgO–Al2O3–SiO2 glasses with ZrO2 as nucleating agent. Mater Chem Phys. 2010;124:1083–8.

    Article  CAS  Google Scholar 

  10. Song L, Wu J, Li Z, Hao X, Yu Y. Crystallization mechanisms and properties of α-cordierite glass–ceramics from K2O–MgO–Al2O3–SiO2 glasses. J Non-Cryst Solids. 2015;419:16–26.

    Article  CAS  Google Scholar 

  11. Mahadevan S, Giridhar A, Singh AK. Calorimetric measurements on As–Sb–Se glasses. J Non-Cryst Solids. 1986;88:11–34.

    Article  CAS  Google Scholar 

  12. Belhouchet H, Hamidouche R, Torrecillas R, Fantozzi G. The non-isothermal kinetics of mullite formation in boehmite–zircon mixtures. J Therm Anal Calorim. 2014;116:795–803.

    Article  CAS  Google Scholar 

  13. Hu A-M, Li M, Mao D-L. Crystallization of spodumene-diopside in the las glass ceramics with Cao and Mgo addition. J Therm Anal Calorim. 2007;90:185–9.

    Article  CAS  Google Scholar 

  14. Başaran C, Canikoğlu N, Toplan HÖ, Toplan N. The crystallization kinetics of MgO–Al2O3–SiO2-TiO2 glass ceramics system produced from industrial waste. J Therm Anal Calorim. 2016;125:695–701.

    Article  CAS  Google Scholar 

  15. Obradovic N, Dordevic N, Filipovic S, Nikolic N, Kosanovic D, Mitric M, Markovic S, Pavlovic V. Influence of mechanochemical activation on sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive. Powder Technol. 2012;218:157–61.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by Commission for Scientific Research Projects (BAPK) in Sakarya University (Project number: 2016-01-08-030).

Author information

Authors and Affiliations

  1. Metallurgy and Materials Engineering, Sakarya University, 54187, Adapazarı, Sakarya, Turkey

    Cansu Başaran, Nil Toplan & H. Özkan Toplan

Authors
  1. Cansu Başaran
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nil Toplan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Özkan Toplan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. Özkan Toplan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Başaran, C., Toplan, N. & Toplan, H.Ö. The crystallization kinetics of the Bi2O3-added MgO–Al2O3–SiO2–TiO2 glass ceramics system produced from industrial waste. J Therm Anal Calorim 134, 313–321 (2018). https://doi.org/10.1007/s10973-018-7525-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-018-7525-z

Keywords

Search

Navigation