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Simple relaxation model of the reversible part of the StepScan® DSC record of glass transition

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Abstract

The results of the StepScan® DSC obtained for 15Na2O⋅xMgO⋅(10–x)CaO⋅75SiO2 glasses were described in the frame of the commonly accepted theory of the glass transition. A new simplified model of the reversible part of StepScan® DSC record was developed on the basis of the Tool Narayanaswamy Moynihan relaxation theory. Equivalence between the formal activation energy of enthalpy relaxation process on one side, and the viscous flow activation enthalpy on the other side, was found.

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References

  1. A Sipp P Richet (2002) J. Non-Cryst. Solids 298 202 Occurrence Handle1:CAS:528:DC%2BD38XitFCgsr0%3D Occurrence Handle10.1016/S0022-3093(02)00948-1

    Article  CAS  Google Scholar 

  2. KJ Rao et al. (2002) Structural Chemistry of Glasses Elsevier Amsterdam

    Google Scholar 

  3. CA Angell KL Ngai GB McKenna PF McMillan SW Martin (2000) J. Appl. Phys. 88 3113 Occurrence Handle1:CAS:528:DC%2BD3cXmt1aqsro%3D Occurrence Handle10.1063/1.1286035

    Article  CAS  Google Scholar 

  4. GW Scherer et al. (1986) Relaxation in Glass and Composites J. Wiley & Sons New York

    Google Scholar 

  5. GW Scherer (1986) J. Am. Ceram. Soc. 69 374 Occurrence Handle10.1111/j.1151-2916.1986.tb04764.x

    Article  Google Scholar 

  6. OS Narayanaswamy (1971) J. Am. Ceram. Soc. 54 491 Occurrence Handle1:CAS:528:DyaE3MXltlant70%3D Occurrence Handle10.1111/j.1151-2916.1971.tb12186.x

    Article  CAS  Google Scholar 

  7. AQ Tool (1945) J. Res. Nat. Bur. Stand. 34 199 Occurrence Handle1:CAS:528:DyaH2MXhs1yjsw%3D%3D

    CAS  Google Scholar 

  8. AQ Tool (1946) J. Am. Ceram. Soc. 29 240 Occurrence Handle1:CAS:528:DyaH28XjsFShsw%3D%3D Occurrence Handle10.1111/j.1151-2916.1946.tb11592.x

    Article  CAS  Google Scholar 

  9. I Gutzow J Schmelzer et al. (1995) The Vitreous State Springer New York

    Google Scholar 

  10. B. Cassel, P. Scotto and B. Sichina, StepScan DSC: An alternative to the conventional modulated techniques. PerkinElmer Application Note, PeTech-34.

  11. B Wunderlich (2004) J. Therm. Anal. Cal. 78 7 Occurrence Handle1:CAS:528:DC%2BD2cXns1Oltrk%3D Occurrence Handle10.1023/B:JTAN.0000042150.03836.27

    Article  CAS  Google Scholar 

  12. I MacDonald S Clarke R Pillar M Ginic-Markovic J Matisons (2005) J. Therm. Anal. Cal. 80 781 Occurrence Handle1:CAS:528:DC%2BD2MXks1Cjt7o%3D Occurrence Handle10.1007/s10973-005-0729-z

    Article  CAS  Google Scholar 

  13. Z Černošek J Holubová E Černošková M Liška (2002) J. Optoelectron. Adv. Mater. 4 489

    Google Scholar 

  14. P Boolchand DG Georgiev B Goodman (2001) J. Optoelectron. Adv. Mater. 3 703 Occurrence Handle1:CAS:528:DC%2BD3MXns1ymsLY%3D

    CAS  Google Scholar 

  15. P Boolchand DG Georgiev M Micoulaut (2002) J. Optoelectron. Adv. Mater. 4 823 Occurrence Handle1:CAS:528:DC%2BD3sXitlGn

    CAS  Google Scholar 

  16. L Cai P Boolchand (2002) Philos. Mag. B 82 1649 Occurrence Handle1:CAS:528:DC%2BD38XosV2hsr0%3D Occurrence Handle10.1080/13642810210166748

    Article  CAS  Google Scholar 

  17. J. Holubová, Z. Černošek and E. Černošková, Conf. on Non-Crystalline Inorganic Materials 2003, April 8–12, 2003, Bonn, Germany, Book of Abstracts, p. 99.

  18. J Holubová et al. (2004) Thesis University Pardubice Pardubice

    Google Scholar 

  19. J Holubová Z Černošek E Černošková (2005) J. Optoelectron. Adv. Mater. 7 2671

    Google Scholar 

  20. M Chromčíková J Holubová M Liška Z Černošek E Černošková (2005) Ceramics 49 86

    Google Scholar 

  21. PW Atkins et al. (1986) Physical Chemistry, 3rd ed. W. H. Freeman Comp. New York 221

    Google Scholar 

  22. M. Liška, Z. Černošek, J. Holubová, M. Chromčíková, L. Vozár and E. Černošková, New features of the glass transition revealed by the StepScan DSC. Book of Abstracts of the 17th European Conference on Thermo-physical Properties, p. 325, September 5–8, 2005, Bratislava, ISBN 80-8050-874-7.

  23. M. Liška, Z. Černošek, J. Holubová, M. Chromčíková, L. Vozár and E. Černošková, Int. J. Thermophys., submitted.

  24. J Holubová Z Černošek E Černošková M Liška (2003) J. Non-Cryst. Solids 326–327 135 Occurrence Handle10.1016/S0022-3093(03)00392-2

    Article  Google Scholar 

  25. M. Chromčíková, Ceram.-Silik., to be published.

  26. Certificate of Viscosity Values, Standard Sample No. 711 Lead-Silica Glass, U. S. Department of Commerce, National Bureau of Standards, Washington, D.C. 20235.

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Authors and Affiliations

  1. Vitrum Laugaricio (VILA) – Joint Glass Center of Institute of Inorganic Chemistry SAS, A. Dubček University of Trenčín and RONA Lednické Rovne, Trenčín, Slovak Republic, 91150, Študentská 2

    Chromčiková Mária & Liška M.

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  1. Chromčiková Mária
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  2. Liška M.
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Correspondence to Chromčiková Mária.

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Chromčiková, M., Liška, M. Simple relaxation model of the reversible part of the StepScan® DSC record of glass transition. J Therm Anal Calorim 84, 703–708 (2006). https://doi.org/10.1007/s10973-005-7546-2

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  • DOI: https://doi.org/10.1007/s10973-005-7546-2

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