Abstract
Excess molar enthalpies hE and excess molar volumes vE of the binary liquid mixtures 2-hexanone+n-alkane (from n-heptane to n-decane) have been determined for various values of the mole fraction of hexanone at 35°C and atmospheric pressure. Excess molar enthalpies were determined by Calvet microcalorimetry and vE from densities measured by vibratingtube densimetry. The results are compared with the predictions of several group contribution models.
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Legido, J.L., Lorenzana, M.T., Jimenez, E. et al. Thermodynamic properties of binary mixtures of 2-hexanone withn-alkanes at 35°C. J Solution Chem 19, 1095–1102 (1990). https://doi.org/10.1007/BF00649454
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DOI: https://doi.org/10.1007/BF00649454