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Interaction of Molybdenum(VI) with Methyliminodiacetic Acid at Different Ionic Strengths by Using Parabolic, Extended Debye-Hückel and Specific Ion Interaction Models

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Abstract

The main aim of this research is to study the complexation of molybdenum(VI) with methyliminodiacetic acid in NaClO4 aqueous solutions at pH = 6.00 and ionic strengths (0.1<I/mol⋅dm−3<1.0) at 25 °C by using potentiometric and UV spectrophotometric measurements in order to obtain thermodynamic stability constants at I=0 mol⋅dm−3. A comparison with previous literature data was made for the stability constants, though few data were available. The stability constants data have been analyzed and interpreted by using extended Debye-Hückel theory, specific ion interaction theory and parabolic model. Finally it might be concluded that parabolic model applies better for this complexation reaction.

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Authors and Affiliations

  1. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Kavosh Majlesi, Mohammadreza Gholamhosseinzadeh & Saghar Rezaienejad

  2. Islamic Azad University, Tehran, Iran

    Saghar Rezaienejad

Authors
  1. Kavosh Majlesi
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  2. Mohammadreza Gholamhosseinzadeh
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  3. Saghar Rezaienejad
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Correspondence to Kavosh Majlesi.

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Majlesi, K., Gholamhosseinzadeh, M. & Rezaienejad, S. Interaction of Molybdenum(VI) with Methyliminodiacetic Acid at Different Ionic Strengths by Using Parabolic, Extended Debye-Hückel and Specific Ion Interaction Models. J Solution Chem 39, 665–679 (2010). https://doi.org/10.1007/s10953-010-9531-z

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  • DOI: https://doi.org/10.1007/s10953-010-9531-z

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