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trans-dinitro- and trans-dinitratoruthenium complexes [RuNO(NH3)2(NO2)2(OH)] and [RuNO(NH3)2(H2O)(NO3)2]NO3·H2O

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Abstract

Methods for the synthesis of trans-diammino complexes [RuNO(NH3)2(NO2)2(OH)] (I) and [RuNO(NH3)2(H2O)(NO3)2](NO3)·H2O (II) are suggested. The compounds were studied by IR spectroscopy and X-ray phase and X-ray structural analyses. Crystal data: space group P-1; a = 6.2328(2) Å, b = 11.0488(3) Å, c = 11.0981(4) Å, α = 71.942(1)°, β = 83.291(1)°, γ = 86.877(1)° (I); space group P21; a = 6.6290(2) Å, b = 13.4389(5) Å, c = 7.0180(2) Å, β 114.281(1)° (II). Complex II readily lost some part of crystal water on storage in open air.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Il’in, V. A. Emel’yanov & I. A. Baidina

  2. Novosibirsk State University, Novosibirsk, Russia

    M. A. Il’in, E. V. Kabin, V. A. Emel’yanov & V. A. Vorob’yov

Authors
  1. M. A. Il’in
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  2. E. V. Kabin
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  3. V. A. Emel’yanov
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  4. I. A. Baidina
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  5. V. A. Vorob’yov
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Correspondence to M. A. Il’in.

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Original Russian Text Copyright © 2009 by M. A. Il’in, E. V. Kabin, V. A. Emel’yanov, I. A. Baidina, and V. A. Vorob’yov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 2, pp. 341–348, March–April, 2009.

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Il’in, M.A., Kabin, E.V., Emel’yanov, V.A. et al. trans-dinitro- and trans-dinitratoruthenium complexes [RuNO(NH3)2(NO2)2(OH)] and [RuNO(NH3)2(H2O)(NO3)2]NO3·H2O. J Struct Chem 50, 328–334 (2009). https://doi.org/10.1007/s10947-009-0045-8

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  • DOI: https://doi.org/10.1007/s10947-009-0045-8

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