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Synthesis and Crystal Structure of Nitrotriammine Complex of Nitrosoruthenium(II) [RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O

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Abstract

Procedures for the synthesis of the [RuNO(NH3 3(NO2)(OH)]Cl·0.5H2O complex have been developed. The compound was investigated by IR spectroscopy, and also by powder and single crystal X-ray diffraction. Crystal data for H11CIN5O4.5Ru: a = 6.5752(7) Å, b = 11.0900(18) Å, c = 12.296(2) Å, ά = 79.692(13)°, β = 85.088(11)°, γ = 87.395(11)°, V = 878.5(2) Å3, Z = 4, d calc = 2.190 g/cm3, space group \(P\bar 1\). The structure is formed by [RuNO(NH3)3(NO2)(OH)]+] complex cations, Cl− anions, and crystallization water molecules. The complex crystallizes as yellow transparent prisms belonging to the triclinic crystal system; it is soluble in water and insoluble in ethanol and acetone. The crystals are stable when kept in a closed beaker, but gradually degrade in dry air.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Emel’yanov, S. A. Gromilov & I. A. Baidina

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  1. V. A. Emel’yanov
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  2. S. A. Gromilov
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  3. I. A. Baidina
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Original Russian Text Copyright © 2004 by V. A. Emel’yanov, S. A. Gromilov, and I. A. Baidina

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 923–932, September–October, 2004.

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Emel’yanov, V.A., Gromilov, S.A. & Baidina, I.A. Synthesis and Crystal Structure of Nitrotriammine Complex of Nitrosoruthenium(II) [RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O. J Struct Chem 45, 879–888 (2004). https://doi.org/10.1007/s10947-005-0073-y

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  • DOI: https://doi.org/10.1007/s10947-005-0073-y

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