Abstract
Hybrid nanocomposites were obtained in this study by solid–solid reaction based on calixarenic derivatives and natural Tunisian clay: clay-calixarene. For this purpose, two calixarenic derivatives were synthesized and their properties were studied. Results show their affinity towards bivalent mercury and lithium by complexation in a homogeneous medium and vis-a-vis the rubidium by extraction of water to dichloromethane. The clay was purified and characterized by means of X-ray diffraction, X-ray fluorescence, cation exchange capacity and BET techniques. Intercalation of the calixarenes in the interfoliar space of the clay has been demonstrated by the spacing of the basal space after reaction and the comparison of infrared spectra confirms that the reaction has taken place. In addition, these hybrids have developed important specific surfaces area. Both nanocomposites prepared are among the first synthesis of clay-calixarenic hybrids in solid state. According to the calixarenic structures, it is assumed that these materials were of class II hybrids.
Similar content being viewed by others
References
C. Sanchez, B. Julian, P. Belleville, M. Popall, J. Mater. Chem. 15, (35–36), 3559 (2005)
C. Sanchez, P. Belleville, M. Popall, L. Nicole, Chem. Soc. Rev. 40(2), 696 (2011)
L. Nicole, L. Rozes, C. Sanchez, Adv. Mat. 22(29), 3208 (2010)
K.C. Krogman, T. Druffel, M.K. Sunkara, Nanotechnology. 16(7), S338 (2005)
C. Li, M. Liu, L. Yan, N. Liu, D. Li, J. Liu, X. Wang, J. Lumin. 190, 1–5 (2017)
V.A. Soloukhin, W. Posthumus, J.C. Brokken-Zijp, J. Loos, Polymer 43(23), 6169 (2002)
E. Barna, B. Bommer, J. Kursteiner, A. Vital, V.O. Trzebiatowski, W. Koch, B. Schmid, T. Graule, Appl. Sci. Manuf. 36(4), 473 (2005)
S. Takahashi, H.A. Goldberg, C.A. Feeney, D.P. Karim, M. Farrell, K. Oleary, D.R. Paul, Polymer 47(9), 3083 (2006)
T.-P. Nguyen, S.-H. Yang, Polymer-Based Nanocomposites for Energy and Environmental Applications (Elsevier, New York, 2018)
G. Schottner, K. Rose, U. Posset, J. Sol-Gel Sci. Technol. 27(1), 71 (2003)
S. Shankar, A. Oun, J. WhanRhim, Int. J. Biol. Macromol. 107, 17 (2018)
E. Bagheri, L. Ansari, K. Abnous, S.M. Taghdisi, F. Charbgoo, M. Ramezani, M.A. bolandi, J. Controll. Release 277, 57 (2018)
S. Khelifi, F. Ayari, A. Choukchou Braham, D.B. Chehimi, J. Porous Mater. 25(3), 885–896 (2017)
A.B. Othman, Y.H. Lee, K. Ohto, R. Abidi, Y. Kim, J. Vicens, J. Incl. Phenom. Macrocycl. Chem. 62(1–2), 187 (2008)
N. Khaorapapong, M. Ogawa, Appl. Clay Sci. 35(1–2), 31 (2007)
I. Mantin, Comptes Rendus des Séances de l’Académie des Sciences, Série D: Sciences Naturelles 269, 815 (1969)
F. Ayari, E. Srasra, M. Trabelsi-Ayadi, Desalination 185(1–3), 391 (2005)
A. Aarfane, A. Salhi, M. Elkrati, S. Tahiri, M. Monkade, E.K. Lhadi, M. Bensitel, J. Mater. Environ. Sci. 5(6), 1927 (2014)
I.L. Konan, J. Soro, J.Y. Andji, S. Oyetola, G. Kra, J. Soc. Ouest-Afr chim. 30, 29 (2010)
O. Touret, C.H. Pons, D. Tessier, Y. Tardy, Clay Miner. 25(2), 217 (1990)
R.L. Frost, J. Kristof, É Makó, W.N. Martens, Langmuir. 18(17), 6491 (2002)
R.L. Frost, É Makó, J. Kristof, J.T. Kloprogge, Mol. Biomol. Spectrosc. 58(13), 2849 (2002)
É Makó, R.L. Frost, J. Kristof, E. Horvath, J. Colloid Interface Sci. 244(2), 359 (2001)
W.P. Kelley, Am. Minerlog. 30(1–2), 1 (1945)
W.P. Kelley, W.H. Dore, A.O. Woodford, S.M. Brown, Soil Sci. 48(3), 201 (1939)
W.P. Kelley, H. Jenny, S.M. Brown, Soil Sci. 41(4), 259 (1936)
S. Brunauer, L.S. Deming, W.E. Deming, E. Teller, J. Am. Chem. Soc. 62(7), 1723 (1940)
S. Yariv, I. Lapides, J. Mater. Synth. Process. 8(3–4), 223 (2000)
R. Hoffmann, G. Brindley, Geochim et Cosmochim Acta. 20(1), 15 (1960)
F.H. Frimmel, Chem. Soils, Angew. Chem. 102(4), 463 (1990)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Othman, A.B., Ayari, F., Abidi, R. et al. Hybrid material based on clay and calixarenic derivatives. J Porous Mater 26, 493–504 (2019). https://doi.org/10.1007/s10934-018-0630-3
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-018-0630-3