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Preparation and Performance of Novel Flavonoid Phenols-Based Biomass-Modified Phenol Formaldehyde Resins

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Abstract

Low toxicity, environmentally friendly and sustainable bio-based phenol–formaldehyde (PF) resins are the primary factors and health goals that researchers need to consider when modifying PF resins. Two novel biomass-modified PF resins were synthesized using two flavonoid phenols of daidzein and naringenin with rigid backbone structures. The results show that compared with ordinary PF, the introduction of daidzein and naringenin during the synthesis of N-PF and D-PF can delay the curing reaction and results in higher curing peak temperatures. The appropriate substitution rate of daidzein and naringenin can improve the crosslinking degree, resulting in N-PF and D-PF with higher thermal stability, ablation resistance and mechanical properties. The highest carbon yield YC800 for N-PF is 59.81% (56.85%for PF-1), and the highest YC800 for D-PF is 64.39% (PF-2 with 58.15%). The maximum tensile strength and flexural strengths of N-PF are respective 33.86 MPa and 110.42 MPa (28.77 and 79.89 MPa for PF-1), and the maximum tensile strength and flexural strengths of D-PF are respective 35.61 MPa and 103.17 MPa (24.48 and 55.79 MPa for PF-2). The D-PF and N-PF resins modified and enhanced by daidzein and naringenin have lower friction coefficient and more excellent wear resistance than pure PF.

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Acknowledgements

The work was supported by National Natural Science Foundation of China, Innovative and Entrepreneurial Building Team Project of Jiangsu Province and New Green Materials Project of Hangmo New Materials Group Co., Ltd. The authors wish to express their appreciation to the Analytical Center at Jiangsu University for the measurements of samples.

Funding

National Natural Science Foundation of China (No. 20207003, No. 20704019, No. 51603093), Innovative and Entrepreneurial Building Team Project of Jiangsu Province (No. 2015026), Zhejiang South Taihu Lake Elite Program Leading Innovation Team Project (202001).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 212013, Jiangsu, China

    Yuan Qin, Chunyu Xu, Zhenguo Hu, Yimiao Zhang, Yufei Jia, Songjun Li & Xinhua Yuan

  2. Hangmo New Materials Group Co., Ltd., Huzhou, 313310, Zhejiang, China

    Fuliang Meng & Xinhua Yuan

  3. Research School of Polymeric Materials, Jiangsu University, Zhenjiang, 212013, Jiangsu, China

    Songjun Li & Xinhua Yuan

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  1. Yuan Qin
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Contributions

Yuan Qin and Chunyu Xu wrote the main manuscript text. Zhenguo Hu, Yimiao Zhang and Yufei Jia participated in a part of the experimental works. Fuliang Meng, Songjun Li and Xinhua Yuan guided the design work of the scientific research program. All authors reviewed the manuscript.

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Correspondence to Fuliang Meng, Songjun Li or Xinhua Yuan.

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Qin, Y., Meng, F., Xu, C. et al. Preparation and Performance of Novel Flavonoid Phenols-Based Biomass-Modified Phenol Formaldehyde Resins. J Inorg Organomet Polym 33, 1817–1829 (2023). https://doi.org/10.1007/s10904-023-02619-7

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