Abstract
Nanothermites (metal oxide/metal) are tremendously exothermic and run with self sustaining oxygen content. Manganese oxide is one of the most effective oxidizers for nanothermite applications. This paper reports on the sustainable fabrication of different nanoscopic forms of colloidal manganese oxides including: MnO2 nanoparticles of 20 nm average particle size and Mn2O3 nanorods of 50 nm diameter and 1 µm length. TEM micrographs demonstrated mono-dispersed particles and rods. XRD diffractograms revealed highly crystalline materials. MnO2 nanoparticles (oxygen content 37 wt%) can offer high oxidizing ability compared with Mn2O3 nanorods (oxygen content 30 wt%). The integration of colloidal particles into energetic matrix can offer enhanced dispersion characteristics; consequently stoichiometric binary mixture of MnO2 and Al nanoparticles were re-dispersed in organic solvent. The integration of developed colloidal nanothermite particles into tri-nitro toluene offered enhanced shock wave strength by 35% using ballistic mortar test. Thanks to nanotechnology which offered sustainable manufacture and subsequent integration of one of the most effective nanothermite particles into highly energetic system.
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References
V.E. Zarko, A.A. Gromov (eds.), Energetic Nanomaterials Synthesis, Characterization, and Application (Elsevier, Amsterdam, 2016)
J. Conkling, C. Mocella (eds.), Chemistry of Pyrotechnics Basic Principles and Theory, 2nd edn. (CRC, London, 2012)
S. Elbasuney et al., Stabilized super-thermite colloids: a new generation of advanced highly energetic materials. Appl. Surf. Sci. 419, 328–336 (2017)
P.P. Vadhe et al., Cast aluminized explosives (review). Combust. Explosion Shock Waves 44(4), 461–477 (2008)
D.G. Piercey, T.M. Klapötke, Nanoscale aluminum-metal oxide (thermite) reactions for application in energetic materials. Central Eur. J. Energ. Mater. 7(2), 15 (2010)
N.H. Yen, L.Y. Wang, Reactive metals in explosives. Propellants Explos. Pyrotech. 37(2), 143–155 (2012)
M.L. Chan et al., Castable Thermobaric Explosive Formulations (The United State of America Repredented by The Secretary of The Navy, Washington, DC, 2005) p. 5
T.M. Klapِtke (ed.), Chemistry of High-Energy Materials. 3rd edn. (De Gruyter, Munich, 2015)
W.A. Trzciński, L. Maiz, Thermobaric and enhanced blast explosives—properties and testing methods. Propellants Explos. Pyrotech. 40(5), 632–634 (2015)
H. Sui, S. Atashin, J.Z. Wen, Thermo-chemical and energetic properties of layered nano-thermite composites. Thermochim. Acta 642, 17–24 (2016)
M. Comet et al., Phosphorus-based nanothermites: a new generation of energetic materials. J. Phys. Chem. Solids 71(2), 64–68 (2010)
G. Jian et al., Nanothermite reactions: is gas phase oxygen generation from the oxygen carrier an essential prerequisite to ignition? Combust. Flame 160(2), 432–437 (2013)
L. Glavier et al., Nanoenergetics as pressure generator for nontoxic impact primers: comparison of Al/Bi2O3, Al/CuO, Al/MoO3 nanothermites and Al/PTFE. Combust. Flame 162(5), 1813–1820 (2015)
E. Nixon et al., Effect of a superhydrophobic coating on the combustion of aluminium and iron oxide nanothermites. Surf. Coat. Technol. 205(21–22), 5103–5108 (2011)
E. Collins et al., Comparison of engineered nanocoatings on the combustion of aluminum and copper oxide nanothermites. Surf. Coat. Technol. 215, 476–484 (2013)
A.K. Mohamed, H.E. Mostafa, S. Elbasuney, Nanoscopic fuel-rich thermobaric formulations: chemical composition optimization and sustained secondary combustion shock wave modulation. J. Hazard. Mater. 301, 492–503 (2016)
P. Brousseau, C.J. Anderson, Nanometric aluminum in explosives. Propellants Explos. Pyrotech. 27(5), 300–306 (2002)
V.W. Manner et al., The role of aluminum in the detonation and post-detonation expansion of selected cast HMX-based explosives. Propellants Explos. Pyrotech. 37(2), 198–206 (2012)
X.L. Xing et al., Discussions on thermobaric explosives (TBXs). Propellants Explos. Pyrotech. 39(1), 14–17 2014
J. Shin et al., Numerical modeling of close-in detonations of high explosives. Eng. Struct. 81, 88–97 (2014)
H.J. Krier, J.M. Peuker, N. Glumac, Aluminum Combustion in Aluminized Explosives: Aerobic and Anaerobic Reaction (49th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition, Orlando, 2011)
K.L. McNesby et al., Afterburn ignition delay and shock augmentation in fuel rich solid explosives. Propellants Explos. Pyrotech. 35(1), 57–65 (2010)
M.B. Talawar et al., Emerging trends in advanced high energy materials. Combust. Explosion Shock Waves 43(1), 62–72 (2007)
A.S. Mukasyan, A.S. Rogachev, S.T. Aruna, Combustion synthesis in nanostructured reactive systems. Adv. Powder Technol. 26(3), 954–976 (2015)
K. Monogarov et al., Сombustion of micro- and nanothermites under elevating pressure. Phys. Procedia 72, 362–365 (2015)
B.Q. Lin, et al., Experimental investigation on explosion characteristics of nano-aluminum powder—air mixtures. Combust. Explosion Shock Waves 46(6), 678–682 (2010)
K.M. Dimpe et al., Synthesis, modification, characterization and application of AC@Fe2O3@MnO2 composite for ultrasound assisted dispersive solid phase microextraction of refractory metals in environmental samples. Chem. Eng. J. 308, 169–176 (2017)
W.-J. Liu, Y.-M. Dai, J.-M. Jehng, Synthesis, characterization and electrochemical properties of Fe/MnO2 nanoparticles prepared by using sol–gel reaction. J. Taiwan Inst. Chem. Eng. 45(2), 475–480 (2014)
W. Wang et al., Synthesis of MnO2 nanoparticles with different morphologies and application for improving the fire safety of epoxy. Compos. Part A 95, 173–182 (2017)
Y. Xiong et al., Synthesis of honeycomb MnO2 nanospheres/carbon nanoparticles/graphene composites as electrode materials for supercapacitors. Appl. Surf. Sci. 357, 1024–1030 (2015)
A.G.M. da Silva et al., MnO2 nanowires decorated with Au ultrasmall nanoparticles for the green oxidation of silanes and hydrogen production under ultralow loadings. Appl. Catal. B 184, 35–43 (2016)
E. Pargoletti et al., High-performance of bare and Ti-doped α-MnO2 nanoparticles in catalyzing the oxygen reduction reaction. J. Power Sources 325, 116–128 (2016)
M. Qiao et al., Facile synthesis and enhanced electromagnetic microwave absorption performance for porous core-shell Fe3O4@MnO2 composite microspheres with lightweight feature. J. Alloy. Compd. 693, 432–439 (2017)
D. Moradkhani, M. Malekzadeh, E. Ahmadi, Nanostructured MnO2 synthesized via methane gas reduction of manganese ore and hydrothermal precipitation methods. Trans. Nonferrous Met. Soc. China 23(1), 134–139 (2013)
L. Kang et al., Urea-assisted hydrothermal synthesis of manganese dioxides with various morphologies for hybrid supercapacitors. J. Alloy. Compd. 648, 190–194 (2015)
S. Elbasuney, Dispersion characteristics of dry and colloidal nano-titania into epoxy resin. Powder Technol. 268(0), 158–164 (2014)
E.L. Dreizin, Metal-based reactive nanomaterials. Prog. Energy Combust. Sci. 35(2), 141–167 (2009)
S. Elbasuney, Surface engineering of layered double hydroxide (LDH) nanoparticles for polymer flame retardancy. Powder Technol. 277, 63–73 (2015)
S. Elbasuney, Sustainable steric stabilization of colloidal titania nanoparticles. Appl. Surf. Sci. 409, 438–447 (2017)
K. Byrappa, S. Ohara, T. Adschiri, Nanoparticles synthesis using supercritical fluid technology – towards biomedical applications. Adv. Drug Deliv. Rev. 60(3), 299–327 (2008)
S. Elbasuney, S.F. Mostafa, Continuous flow formulation and functionalization of magnesium di-hydroxide nanorods as a clean nano-fire extinguisher. Powder Technol. 278, 72–83 (2015)
M.A. Elsayed, M. Gobara, S. Elbasuney, Instant synthesis of bespoke nanoscopic photocatalysts with enhanced surface area and photocatalytic activity for wastewater treatment. J. Photochem. Photobiol. A 344, 121–133 (2017)
S. Elbasuney, H.E. Mostafa, Synthesis and surface modification of nanophosphorous-based flame retardant agent by continuous flow hydrothermal synthesis. Particuology 22, 82–88 (2015)
K. Byrappa, M. Yoshimura (eds.), Handbook of Hydrothermal Technology (William Andrew, Norwich, 2001)
J. Li, Engineering Nanoparticles in Near-Critical and Supercritical Water (University of Nottingham, Nottingham, 2008)
P. Savage et al., Reactions at supercritical conditions: applications and fundamentals. Am. Inst. Chem. Eng. J. 41(7), 1723–1778 (1995)
K.S. Morley et al., Clean preparation on nanoparticulate metals in porous supports: a supercritical route. J. Chem. Mater. 12, 1898–1905 (2002)
H. Hobbs, Biocatalysis in ‘Green Solvents’, in Chemistry (University of Nottingham, Notttingham, 2006)
J.A. Darr, M. Poliakoff, New directions in inorganic and metal-organic coordination chemistry in supercritical fluids. Chem. Rev. 99(2), 495–541 (1999)
T. Adschiri, Y. Hakuta, K. Arai, Hydrothermal synthesis of metal oxide fine particles at supercritical conditions. Ind. Eng. Chem. Res. 39(12), 4901–4907 (2000)
T. Adschiri, K. Kanazawa, K. Arai, Rapid and continuous hydrothermal synthesis of boehmite particles in subcritical and supercritical water. J. Am. Ceram. Soc. 75(9), 2615–2618 (1992)
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Military technical college is acknowledged for funding the research project entitled “Nanoscopic Cast Metalized Explosive Formulations”.
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Elbasuney, S. Novel Colloidal Nanothermite Particles (MnO2/Al) for Advanced Highly Energetic Systems. J Inorg Organomet Polym 28, 1793–1800 (2018). https://doi.org/10.1007/s10904-018-0823-x
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DOI: https://doi.org/10.1007/s10904-018-0823-x