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New Colorimetric and Fluorometric Fluoride Ion Probe Based on Anthra[1,9-cd]pyrazol-6(2H)-one

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Abstract

New colorimetric and fluorometric fluoride ion probe, anthra[1,9-cd]pyrazol- 6(2H)-one (1), was synthesized by one-step condensation. The probe 1 shows F−-selective color change from colorless to pink and appearance of red fluorescence. The fluorescence quantum yield of free probe 1 in DMSO was calculated to be 0.03. After addition of 15 equiv. of F−, its fluorescence quantum yield can be increased to 0.37. The analytical detection limit for F− was 2.8 × 10− 7 M. 1H NMR analysis and DFT calculation show that the F−-induced colorimetric and fluorometric responses of 1 are driven by deprotonation process.

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Acknowledgements

This study was supported by the Science Foundation for Creative Research Groups of HBNU (No. T201501) and Foundation for Hubei Key Laboratory of Pollutant Analysis and Reuse Technology (No. PA150204).

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Authors and Affiliations

  1. Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Collaborative Innovation Center for Rare Metal Chemistry, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, 435002, People’s Republic of China

    Yang Hu, Yan-Yan Liu, Qiao Li, Jing-Yu Sun & Sheng-Li Hu

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  1. Yang Hu
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Correspondence to Sheng-Li Hu.

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Hu, Y., Liu, YY., Li, Q. et al. New Colorimetric and Fluorometric Fluoride Ion Probe Based on Anthra[1,9-cd]pyrazol-6(2H)-one. J Fluoresc 27, 2287–2294 (2017). https://doi.org/10.1007/s10895-017-2170-7

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