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Synthesis, Characterization, and Catalytic Property of a Hybrid Nanoscale Polyoxoniobate

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Abstract

A nanoscale polyoxoniobate based on trivalent nickel complex and Lindqvist-type cluster, [Ni(en)3]2[H2Nb6O19]·8H2O (abbreviated as NEN) (en = ethylenediamine, C2H8N2) has been synthesized and structurally characterized by elemental analyses, IR spectrum, UV–visible spectra, X-ray photoelectron spectrum (XPS), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Structural analysis shows that NEN is an ionic compound, in which the cations are two trivalent nickel complexes [Ni(en)3]3+ and the anion is a Lindqvist-type polyoxoniobate [Nb6O19]8− cluster. Notably, NEN can catalyze the production of reactive oxygen species efficiently in aqueous solution system.

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Acknowledgments

This work was supported by the Natural Science Foundation of China (Grants 21573056), Shanxi Province Science Foundation for Youths (Grants 201901D211453), the Research Foundation for Advanced Talents of Shanxi Province (1800008001), the Research Foundation of Taiyuan Institute of Technology (03000352), and the Research Foundation of the Chinese State Key Laboratory of Coordination Chemistry (SKLCC1912).

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Authors and Affiliations

  1. Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, 030008, People’s Republic of China

    Xiang Ma, Yujian Bian, Yingjie Zhou, Qiang Zhao, Yong Tian & Jiai Hua

  2. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, People’s Republic of China

    Pengtao Ma

  3. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, People’s Republic of China

    Jiai Hua

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  1. Xiang Ma
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Appendix A. Supplementary material

Appendix A. Supplementary material

Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Center, CCDC reference number: 1980676 for NEN. This data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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Ma, X., Bian, Y., Zhou, Y. et al. Synthesis, Characterization, and Catalytic Property of a Hybrid Nanoscale Polyoxoniobate. J Clust Sci 32, 613–620 (2021). https://doi.org/10.1007/s10876-020-01820-9

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