Abstract
A novel high-nuclearity copper(I) cluster formulated as [Cu14(tBuC≡C)10(CH3COO)4] (1) was synthesized through comproportionation reaction under stirring condition. The tetradecanuclear copper(I) cluster was identified by single-crystal X-ray diffraction and characterized using UV–Vis, IR, thermogravimetric analysis, powder X-ray diffraction and elemental analyses. Interestingly, powder sample of 1 exhibits remarkable yellow luminescence at room temperature.
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Acknowledgements
This work was financially supported by the NSFC (Grant No. 21571115), the Natural Science Foundation of Shandong Province (Nos. JQ201803 and ZR2017MB061), the Qilu Youth Scholar Funding of Shandong University and the Fundamental Research Funds of Shandong University (104.205.2.5).
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Zhuo, HY., Hu, AY., Feng, L. et al. A Tetradecanuclear Organometallic Copper(I)-Alkynide Cluster: Synthesis, Crystal Structure, and Luminescent Property. J Clust Sci 29, 1017–1022 (2018). https://doi.org/10.1007/s10876-018-1413-3
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DOI: https://doi.org/10.1007/s10876-018-1413-3