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Self-Assembled Hydrogen-Bonding Chains of Copper(II) 2-Nitrobenzoate with Nicotinamide

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Abstract

The synthesis, spectral characterization and crystal structure of two new nitrobenzoatocopper(II) complexes, namely, [Cu2(2-O2Nbz)4(nia)2]·ACN (1) and [Cu2(2-O2Nbz)4(ACN)2] (2) (where 2-O2Nbz = 2-nitrobenzoate, nia = nicotinamide and ACN = acetonitrile) are reported. The complexes 1 and 2 form dinuclear units of the paddle-wheel type around the crystallographic inversion centers. The copper ions are bridged by four 2-nitrobenzoate anions and the neutral N-donor ligands, viz. nicotinamide in 1 and acetonitrile in 2, are coordinated at apical positions. Selected geometric parameters of both complexes are compared with values for related tetra-2-nitrobenzoate complexes of copper(II) as well as the other dimeric copper(II) carboxylates with apical nicotinamide and acetonitrile ligands. The molecules of 1 are linked with N–H···O and C–H···O hydrogen bonds. The π–π stacking interactions in 1 are observed between benzene rings of 2-nitrobenzoate anions and pyridine rings of nicotinamide and also between acetonitrile molecules and benzene rings of 2-nitrobenzoate anions. The C–H···O hydrogen-bonds and CH/π interactions are observed in crystal structure of 2.

Graphical Abstract

The synthesis, spectral characterization and crystal structure of two new nitrobenzoatocopper(II) complexes, namely, [Cu2(2-O2Nbz)4(nia)2]·ACN and [Cu2(2-O2Nbz)4(ACN)2] (where 2-O2Nbz = 2-nitrobenzoate, nia = nicotinamide and ACN = acetonitrile) are reported. The both complexes form dinuclear units of the paddle-wheel type around the crystallographic inversion centers.

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Acknowledgments

We thank the Scientific Grant Agency of the Ministry of Education of Slovak Republic and the Slovak Academy of Sciences for financial support (1/0575/08 and 1/4454/07).

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Slovak Technical University, 812 37, Bratislava, Slovakia

    Jan Moncol, Zuzana Vasková, Petra Stachová, Jozef Svorec & Dušan Valigura

  2. Department of Chemistry, University of Jyväskylä, 40351, Jyväskylä, Finland

    Reijo Sillanpää

  3. Department of Physical Chemistry, Slovak Technical University, 812 37, Bratislava, Slovakia

    Milan Mazúr

Authors
  1. Jan Moncol
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  2. Zuzana Vasková
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  3. Petra Stachová
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  4. Jozef Svorec
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  5. Reijo Sillanpää
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  6. Milan Mazúr
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  7. Dušan Valigura
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Correspondence to Jan Moncol.

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Moncol, J., Vasková, Z., Stachová, P. et al. Self-Assembled Hydrogen-Bonding Chains of Copper(II) 2-Nitrobenzoate with Nicotinamide. J Chem Crystallogr 40, 179–184 (2010). https://doi.org/10.1007/s10870-009-9631-z

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  • DOI: https://doi.org/10.1007/s10870-009-9631-z

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