Abstract
The development of efficient, scalable, and economically viable electrode materials with high specific capacitance is of great significance for supercapacitor applications. Herein, α-Fe2O3 nanoparticles, α-Fe2O3/rGO, and α-Fe2O3/SnO2/rGO nanocomposite were synthesized by a one-step hydrothermal method. Different characterization techniques were used to study the physical and chemical properties of the prepared materials. The powder XRD measurement revealed that the formation of the ternary composite without any impurities. As characterized by SEM and TEM techniques, both α-Fe2O3 and SnO2 nanoparticles were embedded on two-dimensional reduced graphene oxide sheets. The electrochemical properties of the prepared electrode materials were studied by cyclic voltammetry and galvanostatic charge/discharge, and impedance spectroscopy techniques in a 6 M KOH electrolyte solution. All the electrode materials exhibit Faradic reaction peaks in CV curves which imply the pseudocapacitive nature of the prepared materials. The ternary α-Fe2O3/SnO2/rGO nanocomposite demonstrated the enhanced specific capacitance of 821 Fg−1 at 1Ag−1 than that of α-Fe2O3 nanoparticles (373 Fg−1 at 1Ag−1), and α-Fe2O3/rGO (517 Fg−1 at 1Ag−1) nanocomposite with excellent cyclic retention (98.7%) after successive 10,000 cycles. This improved electrochemical performance of ternary α-Fe2O3/SnO2/rGOnanocomposite is mainly attributed to the surface properties of nanostructures of metal oxides and an excellent conductive network. Moreover, the asymmetric supercapacitor (ASC) device was fabricated using the ternary α-Fe2O3/SnO2/rGOnanocomposite as the anode material and rGO as the cathode material. The ASC device showed an energy density of 17 Wh Kg−1 at a power density of 3585 W kg−1 and retains 94.52% capacitance after successive 5000 cycles at a current density of 10Ag−1.
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References
J. Libich, J. Máca, J. Vondrák, O. Čech, M. Sedlaříková, Supercapacitors: properties and applications. J. Energy Storage. 17, 224–227 (2018). https://doi.org/10.1016/j.est.2018.03.012
K.K. Sadasivuni, D. Ponnamma, J. Kim, J.J. Cabibihan, M.A. Almaadeed, Composites in Super Capacitor (Elsevier Inc., Amsterdam, 2017). https://doi.org/10.1016/B978-0-12-809261-3/00018-8
Y. Wang, Y. Song, Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016). https://doi.org/10.1039/c5cs00580a
S. Khamlich, Z. Abdullaeva, J.V. Kennedy, M. Maaza, High performance symmetric supercapacitor based on zinc hydroxychloride nanosheets and 3D graphene-nickel foam composite. Appl. Surf. Sci. 405, 329–336 (2017). https://doi.org/10.1016/j.apsusc.2017.02.095
K. Kaviyarasu, E. Manikandan, J. Kennedy, M. Jayachandran, R. Ladchumananandasiivam, U.U. De Gomes, M. Maaza, Synthesis and characterization studies of NiO nanorods for enhancing solar cell efficiency using photon upconversion materials. Ceram. Int. 42, 8385–8394 (2016). https://doi.org/10.1016/j.ceramint.2016.02.054
Q. Jiang, N. Kurra, M. Alhabeb, Y. Gogotsi, H.N. Alshareef, All pseudocapacitive MXene-RuO2 asymmetric supercapacitors. Adv. Energy Mater. 8, 1–10 (2018). https://doi.org/10.1002/aenm.201703043
C. Wu, Y. Xu, L. Ao, K. Jiang, L. Shang, Y. Li, Z. Hu, J. Chu, Robust three-dimensional porous rGO aerogel anchored with ultra-fine α-Fe2O3 nanoparticles exhibit dominated pseudocapacitance behavior for superior lithium storage. J. Alloys Compd. 816, 152627 (2020). https://doi.org/10.1016/j.jallcom.2019.152627
V. Velmurugan, U. Srinivasarao, R. Ramachandran, M. Saranya, A.N. Grace, Synthesis of tin oxide/graphene (SnO2/G) nanocomposite and its electrochemical properties for supercapacitor applications. Mater. Res. Bull. 84, 145–151 (2016). https://doi.org/10.1016/j.materresbull.2016.07.015
X. Yang, C. Cai, Y. Zou, C. Xiang, H. Chu, E. Yan, S. Qiu, L. Sun, F. Xu, X. Hu, Co3O4-doped two-dimensional carbon nanosheet as an electrode material for high-performance asymmetric supercapacitors. Electrochim. Acta 335, 135611 (2020). https://doi.org/10.1016/j.electacta.2020.135611
N. Duraisamy, A. Numan, S.O. Fatin, K. Ramesh, S. Ramesh, Facile sonochemical synthesis of nanostructured NiO with different particle sizes and its electrochemical properties for supercapacitor application. J. Colloid Interface Sci. 471, 136–144 (2016). https://doi.org/10.1016/j.jcis.2016.03.013
X. Wu, F. Yang, H. Dong, J. Sui, Q. Zhang, J. Yu, Q. Zhang, L. Dong, Controllable synthesis of MnO2 with different structures for supercapacitor electrodes. J. Electroanal. Chem. 848, 113332 (2019). https://doi.org/10.1016/j.jelechem.2019.113332
S. Shivakumara, T.R. Penki, N. Munichandraiah, High specific surface area α-Fe2O3 nanostructures as high performance electrode material for supercapacitors. Mater. Lett. 131, 100–103 (2014). https://doi.org/10.1016/j.matlet.2014.05.160
Y. Zeng, M. Yu, Y. Meng, P. Fang, X. Lu, Y. Tong, Iron-based supercapacitor electrodes: advances and challenges. Adv. Energy Mater. 6, 1–17 (2016). https://doi.org/10.1002/aenm.201601053
A.K. Mishra, J. At, Concepts and applications. Mol. Condens. Nano Phys. 5, 159–193 (2018). https://doi.org/10.26713/jamcnp.v5i2.842
H. Zhou, G. Han, One-step fabrication of heterogeneous conducting polymers-coated graphene oxide/carbon nanotubes composite films for high-performance supercapacitors. Electrochim. Acta 192, 448–455 (2016). https://doi.org/10.1016/j.electacta.2016.02.015
B. Saravanakumar, G. Ravi, V. Ganesh, S. Ravichandran, A. Sakunthala, R. Yuvakkumar, Low surface energy and pH Effect on SnO2 nanoparticles formation for supercapacitor applications. J. Nanosci. Nanotechnol. 19, 3429–3436 (2019). https://doi.org/10.1166/jnn.2019.16098
P. Liu, Y. Zhu, X. Gao, Y. Huang, Y. Wang, S. Qin, Y. Zhang, Rational construction of bowl-like MnO2 nanosheets with excellent electrochemical performance for supercapacitor electrodes. Chem. Eng. J. 350, 79–88 (2018). https://doi.org/10.1016/j.cej.2018.05.169
Y. Hu, C. Guan, Q. Ke, Z.F. Yow, C. Cheng, J. Wang, Hybrid Fe2O3 Nanoparticle Clusters/rGO Paper as an Effective Negative Electrode for Flexible Supercapacitors. Chem. Mater. 28, 7296–7303 (2016). https://doi.org/10.1021/acs.chemmater.6b02585
K.P. Gannavarapu, R.B. Dandamudi, Shape engineered three dimensional α-Fe2O3-activated carbon nano composite as enhanced electrochemical supercapacitor electrode material. Int. J. Energy Res. 42, 4687–4696 (2018). https://doi.org/10.1002/er.4211
Z. Yang, L. Tang, J. Ye, D. Shi, S. Liu, M. Chen, Hierarchical nanostructured α-Fe2O3/polyaniline anodes for high performance supercapacitors. Electrochim. Acta 269, 21–29 (2018). https://doi.org/10.1016/j.electacta.2018.02.144
Z.-G. Yang, N.-N. Liu, S. Dong, F.-S. Tian, Y.-P. Gao, Z.-Q. Hou, Supercapacitors based on free-standing reduced graphene oxides/carbon nanotubes hybrid films. SN Appl. Sci. 1, 1–9 (2019). https://doi.org/10.1007/s42452-018-0059-y
S.N. Khatavkar, S.D. Sartale, α-Fe2O3 thin film on stainless steel mesh: a flexible electrode for supercapacitor. Mater. Chem. Phys. 225, 284–291 (2019). https://doi.org/10.1016/j.matchemphys.2018.12.079
A.M. Díez-pascual, C. Sainz-urruela, C. Vallés, S. Vera-lópez, M.P.S. Andrés, Tailorable synthesis of highly oxidized graphene oxides via an environmentally-friendly electrochemical process. Nanomaterials 10, 1–18 (2020). https://doi.org/10.3390/nano10020239
C. Zhao, X. Shao, Y. Zhang, X. Qian, Fe2O3/RGO/Fe3O4 composite in-situ grown on Fe foil for high performance supercapacitors. ACS Appl. Mater. Interfaces 8(44), 30133–30142 (2016)
N. Cao, Y. Zhang, Study of reduced graphene oxide preparation by Hummers’ method and related characterization. J. Nanomater. (2015). https://doi.org/10.1155/2015/168125
N.I. Zaaba, K.L. Foo, U. Hashim, S.J. Tan, W.W. Liu, C.H. Voon, Synthesis of graphene oxide using modified Hummers method: solvent influence. Procedia Eng. 184, 469–477 (2017). https://doi.org/10.1016/j.proeng.2017.04.118
Y. Wang, H. Zhang, R. Hu, J. Liu, T. van Ree, H. Wang, L. Yang, M. Zhu, Fe3O4/SnO2/rGO ternary composite as a high-performance anode material for lithium-ion batteries. J. Alloys Compd. 693, 1174–1179 (2017). https://doi.org/10.1016/j.jallcom.2016.10.082
B. Saravanakumar, C. Radhakrishnan, M. Ramasamy, R. Kaliaperumal, A.J. Britten, M. Mkandawire, Copper oxide/mesoporous carbon nanocomposite synthesis, morphology and electrochemical properties for gel polymer-based asymmetric supercapacitors. J. Electroanal. Chem. 852, 113504 (2019). https://doi.org/10.1016/j.jelechem.2019.113504
X. Pan, X. Chen, Y. Li, Z. Yu, Facile synthesis of Co3O4 nanosheets electrode with ultrahigh specific capacitance for electrochemical supercapacitors. Electrochim. Acta 182, 1101–1106 (2015). https://doi.org/10.1016/j.electacta.2015.10.035
M. Jana, P. Sivakumar, M. Kota, M.G. Jung, H.S. Park, Phase- and interlayer spacing-controlled cobalt hydroxides for high performance asymmetric supercapacitor applications. J. Power Sources 422, 9–17 (2019). https://doi.org/10.1016/j.jpowsour.2019.03.019
H. Wang, H. Yi, X. Chen, X. Wang, Asymmetric supercapacitors based on nano-architectured nickel oxide/graphene foam and hierarchical porous nitrogen-doped carbon nanotubes with ultrahigh-rate performance. J. Mater. Chem. A 2, 3223–3230 (2014). https://doi.org/10.1039/c3ta15046a
J. Ding, S. Zhu, T. Zhu, W. Sun, Q. Li, G. Wei, Z. Su, Hydrothermal synthesis of zinc oxide-reduced graphene oxide nanocomposites for an electrochemical hydrazine sensor. RSC Adv. 5, 22935–22942 (2015). https://doi.org/10.1039/c5ra00884k
N. Duraisamy, K. Kandiah, R. Rajendran, S. Prabhu, R. Ramesh, G. Dhanaraj, Electrochemical and photocatalytic investigation of nickel oxide for energy storage and wastewater treatment. Res. Chem. Intermed. 44, 5653–5667 (2018). https://doi.org/10.1007/s11164-018-3446-5
N. Thangavel, S. Bellamkonda, A.D. Arulraj, G. Ranga Rao, B. Neppolian, Visible light induced efficient hydrogen production through semiconductor-conductor-semiconductor (S-C-S) interfaces formed between g-C3N4 and rGO/Fe2O3 core-shell composites. Catal. Sci. Technol. 8, 5081–5090 (2018). https://doi.org/10.1039/c8cy01248b
S.M. Botsa, G.P. Naidu, M. Ravichandra, S.J. Rani, R.B. Anjaneyulu, C.V. Ramana, Flower like SnO2-Fe2O3-rGO ternary composite as highly efficient visible light induced photocatalyst for the degradation of organic pollutants from contaminated water. J. Mater. Res. Technol. 9, 12461–12472 (2020). https://doi.org/10.1016/j.jmrt.2020.08.087
S. Wang, F. Ma, H. Jiang, Y. Shao, Y. Wu, X. Hao, Band gap-tunable porous borocarbonitride nanosheets for high energy-density supercapacitors. ACS Appl. Mater. Interfaces. 10, 19588–19597 (2018). https://doi.org/10.1021/acsami.8b02317
A. Ali, H. Zafar, M. Zia, I. ul Haq, A.R. Phull, J.S. Ali, A. Hussain, Synthesis, characterization, applications, and challenges of iron oxide nanoparticles. Nanotechnol. Sci. Appl. 9, 49–67 (2016). https://doi.org/10.2147/NSA.S99986
R. Barik, M. Mohapatra, Solvent mediated surface engineering of α-Fe2O3 nanomaterials: Facet sensitive energy storage materials. CrystEngComm 17, 9203–9215 (2015). https://doi.org/10.1039/c5ce01369k
Q. Zhang, P. Liu, C. Miao, Z. Chen, C.M. Lawrence Wu, C.H. Shek, Formation of orthorhombic SnO2 originated from lattice distortion by Mn-doped tetragonal SnO2. RSC Adv. 5, 39285–39290 (2015). https://doi.org/10.1039/c5ra04946f
T. Wang, Y. Li, L. Wang, C. Liu, S. Geng, X. Jia, F. Yang, L. Zhang, L. Liu, B. You, X. Ren, H. Yang, Synthesis of graphene/α-Fe2O3 composites with excellent electromagnetic wave absorption properties. RSC Adv. 5, 60114–60120 (2015). https://doi.org/10.1039/c5ra09715k
K. Wongsaprom, R.A. Bornphotsawatkun, E. Swatsitang, Synthesis and characterization of tin oxide (SnO2) nanocrystalline powders by a simple modified sol–gel route. Appl. Phys. A Mater. Sci. Process. 114, 373–379 (2014). https://doi.org/10.1007/s00339-013-8197-y
B.A. Aragaw, Reduced graphene oxide-intercalated graphene oxide nano-hybrid for enhanced photoelectrochemical water reduction. J. Nanostruct. Chem. 10, 9–18 (2020). https://doi.org/10.1007/s40097-019-00324-x
D.L.A. de Faria, S. Venâncio Silva, M.T. de Oliveira, Raman microspectroscopy of some iron oxides and oxyhydroxides. J. Raman Spectrosc. 28, 873–878 (1997). https://doi.org/10.1002/(sici)1097-4555(199711)28:11<873::aid-jrs177>3.3.co;2-2
J. Kennedy, F. Fang, J. Futter, J. Leveneur, P.P. Murmu, G.N. Panin, T.W. Kang, E. Manikandan, Synthesis and enhanced field emission of zinc oxide incorporated carbon nanotubes. Diam. Relat. Mater. 71, 79–84 (2017). https://doi.org/10.1016/j.diamond.2016.12.007
E. Manikandan, G. Kavitha, J. Kennedy, Epitaxial zinc oxide, graphene oxide composite thin-films by laser technique for micro-Raman and enhanced field emission study. Ceram. Int. 40, 16065–16070 (2014). https://doi.org/10.1016/j.ceramint.2014.07.129
S. Wang, Y. Dong, C. He, Y. Gao, N. Jia, Z. Chen, W. Song, The role of sp2/sp3 hybrid carbon regulation in the nonlinear optical properties of graphene oxide materials. RSC Adv. 7, 53643–53652 (2017). https://doi.org/10.1039/c7ra10505c
M. Zhang, D. Lei, Z. Du, X. Yin, L. Chen, Q. Li, Y. Wang, T. Wang, Fast synthesis of SnO2/graphene composites by reducing graphene oxide with stannous ions. J. Mater. Chem. 21, 1673–1676 (2011). https://doi.org/10.1039/c0jm03410j
I.J. Gomez, B. Arnaiz, M. Cacioppo, F. Arcudi, M. Prato, Nanocrystalline Fe-Fe2O3 particle-deposited N-doped graphene as an activity modulated Pt-free electrocatalyst for oxygen reduction reaction. J. Mater. Chem. B. (2018). https://doi.org/10.1039/x0xx00000x
A. Manuscript, CrystEngComm, (n.d.)
M.G.T.N. D., J.M.B.S.P. Basu, R. Mahesh, S. Harish, S. Joseph, P. Sagayaraj, One-pot hydrothermal preparation of Cu2O-CuO/rGO nanocomposites with enhanced electrochemical performance for supercapacitor applications. Appl. Surf. Sci. 449, 474–484 (2018). https://doi.org/10.1016/j.apsusc.2017.12.199
Z. Shen, H. Xing, Y. Zhu, X. Ji, Z. Liu, L. Wang, Synthesis and enhanced microwave-absorbing properties of SnO2/α-Fe2O3@RGO composites. J. Mater. Sci. Mater. Electron. 28, 13896–13904 (2017). https://doi.org/10.1007/s10854-017-7238-2
F. Paquin, J. Rivnay, A. Salleo, N. Stingelin, C. Silva, Multi-phase semicrystalline microstructures drive exciton dissociation in neat plastic semiconductors. J. Mater. Chem. C. 3, 10715–10722 (2015). https://doi.org/10.1039/b000000x
G. Zhao, T. Wen, C. Chen, X. Wang, Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas. RSC Adv. 2, 9286–9303 (2012). https://doi.org/10.1039/c2ra20990j
W.P.S.L. Wijesinghe, M.M.M.G.P.G. Mantilaka, K.A.A. Ruparathna, R.B.S.D. Rajapakshe, S.A.L. Sameera, M.G.G.S.N. Thilakarathna, Filler Matrix Interfaces of Inorganic/Biopolymer Composites and Their Applications (Elsevier Ltd, Amsterdam, 2019). https://doi.org/10.1016/B978-0-08-102665-6.00004-2
G. Xia, N. Li, D. Li, R. Liu, C. Wang, Q. Li, X. Lü, J.S. Spendelow, J. Zhang, G. Wu, Graphene/Fe2O3/SnO2 ternary nanocomposites as a high-performance anode for lithium ion batteries. ACS Appl. Mater. Interfaces. 5, 8607–8614 (2013). https://doi.org/10.1021/am402124r
T. Li, A. Qin, L. Yang, J. Chen, Q. Wang, D. Zhang, H. Yang, In situ grown Fe2O3 single crystallites on reduced graphene oxide nanosheets as high performance conversion anode for sodium-ion batteries. ACS Appl. Mater. Interfaces. 9, 19900–19907 (2017). https://doi.org/10.1021/acsami.7b04407
L. Chen, D. Liu, P. Yang, Preparation of α-Fe2O3/rGO composites toward supercapacitor applications. RSC Adv. 9, 12793–12800 (2019). https://doi.org/10.1039/c9ra01928f
W. Peng, G. Han, Y. Huang, Y. Cao, S. Song, Insight the effect of crystallinity of natural graphite on the electrochemical performance of reduced graphene oxide. Results Phys. 11, 131–137 (2018). https://doi.org/10.1016/j.rinp.2018.08.055
M.T.T. Tran, B. Tribollet, V. Vivier, M.E. Orazem, On the impedance response of reactions influenced by mass transfer. Russ. J. Electrochem. 53, 932–940 (2017). https://doi.org/10.1134/S1023193517090142
E. Samuel, T.G. Kim, C.W. Park, B. Joshi, M.T. Swihart, S.S. Yoon, Supersonically sprayed Zn2SnO4/SnO2/CNT nanocomposites for high-performance supercapacitor electrodes. ACS Sustain. Chem. Eng. 7, 14031–14040 (2019). https://doi.org/10.1021/acssuschemeng.9b02549
Acknowledgements
The authors would like to acknowledge the Ministry of Science and Technology, Department of Science and Technology (WOS-A) (File No. SR-WOS-A/PM-71/2017), and DST-SERB, India (File No. EMR/2017/001238), for financial support and the authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this study through the Large Research Group Project under grant number R.G.P. 2/139/1442.
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Geerthana, M., Prabhu, S., Harish, S. et al. Design and preparation of ternary α-Fe2O3/SnO2/rGO nanocomposite as an electrode material for supercapacitor. J Mater Sci: Mater Electron 33, 8327–8343 (2022). https://doi.org/10.1007/s10854-021-06128-6
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DOI: https://doi.org/10.1007/s10854-021-06128-6