Abstract
Glasses with compositions xMgO-(20−x)CaO-10Al2O3-20B2O3-50SiO2 (x = 0, 5, 10, 15 and 20 mol%) were prepared by conventional melting method. X-ray photoelectron spectroscopy (XPS) results indicated that the proportion of non-bridging oxygen increased with increasing MgO content. Nuclear magnetic resonance spectra showed that the fraction of the four-coordinated boron ions N4(B) and aluminum ions N4(Al) decreased with increasing MgO/CaO. Thus, higher field strength cations were expected to weaken the glass network. However, the increase in the glass transition temperature (Tg) indicated that the magnesium ions strengthened the glass network. The decrease in dielectric constant εr and loss tanδ could be attributed to the increase in the rigidity of the glass network as the MgO content increased.
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M.M. Gomaa, H.A. Abo-Mosallam, H. Darwish, J. Mater. Sci. Mater. Electron. 20, 507 (2009)
I. Choi, J.G. Kim, D.G. Lee, I.S. Seo, Compos. Sci. Technol 71, 1632 (2011)
A. Sridhar, D.J. Van Dijk, R. Akkerman, Thin Solid Films 517, 4633 (2009)
J.S. Wu, J.F. Stebbins, J. Non-Cryst. Solids 355, 556 (2009)
A. Abd El-Moneim, I.M. Youssof, L. Abd El-Latif, Acta. Mater. 54, 3811 (2006)
R. Balaji Rao, D. Krishna Rao, N. Veeraiah, Mater. Chem. Phys. 87, 357 (2004)
L. Tichy, H. Ticha, J. Non-Cryst. Solids 189, 141 (1995)
N.H. Ray, J. Non-Cryst. Solids 15, 423 (1974)
A. Aronne, S. Esposito, P. Pernice, Mater. Chem. Phys. 51, 163 (1997)
Agilent 4294A (2002) Precision impedance analyzer operation manual, 6th edn (Agilent Technologies Japan, Ltd. Kobe Instrument Division, Part No. 04294–90050, November 2002)
V. Dimitrov, Phys. Chem. Glasses 44, 357 (2003)
H. Yamanaka, K. Nakahata, R. Terai, J. Non-Cryst. Solids 95–96, 405 (1987)
H.Y. Fan, G.N. Wang, L.L. Hu, Solid State Sci. 11, 2065 (2009)
A. Mekki, D. Holland, C.F. McConville, M. Salim, J. Non-Cryst. Solids 208, 267 (1996)
B.V.R. Chowdari, Z. Rong, Solid State Ionics 86–88, 527 (1996)
B.V.R. Chowdari, Z. Rong, Solid State Ionics 90, 151 (1996)
L.M. Thompson, J.F. Stebbins, J. Non-Cryst. Solids 358, 1783 (2012)
S. Kroeker, J.F. Stebbins, Inorg. Chem. 40, 6239 (2001)
J.F. Stebbins, P.D. Zhao, S. Kroeker, Solid State Nucl. Mag. 16, 9 (2000)
N.M. Bobkova, Z.V. Apanovich, S.A. Gailevich, J. Appl. Spectrosc. 47, 743 (1987)
H. Yamashita, K. Inoue, T. Nakajin, H. Inoue, T. Maekawa, J. Non-Cryst. Solids 331, 128 (2003)
H. Deters, A.S.S. de Camargo, C.N. Santos, C.R. Ferrari, A.C. Hernandes, A. Ibanez, M.T. Rinke, H. Eckert, J. Phys. Chem. C 113, 16216 (2009)
J.C.C. Chan, M. Bertmer, H. Eckert, J. Am. Chem. Soc. 121, 5238 (1999)
B.C. Bunker, R.J. Kirkpatrick, R.K. Brow, G.L. Turner, C. Nelson, J. Am. Ceram. Soc. 74, 1430 (1991)
J.R. Allwardt, J.F. Stebbins, B.C. Schmidt, D.J. Frost, A.C. Withers, M.M. Hirschmann, Am. Miner. 90, 1218 (2005)
G. Lusvardi, G. Malavasi, F. Tarsitano, L. Menabue, M.C. Menziani, A. Pedone, J. Phys. Chem. B 113, 10331 (2009)
N.J. Clayden, S. Esposito, A. Aronne, P. Pernice, J. Non-Cryst. Solids 258, 11 (1999)
K. Singh, Solid State Ionics 93, 147 (1997)
C.H. Lee, K.H. Joo, J.H. Kim, S.G. Woo, H.J. Sohn, T. Kang, Y. Park, J.Y. Oh, Solid State Ionics 149, 59 (2002)
G.D. Chryssikos, E.I. Kamitsos, Y.D. Yiannopoulos, J. Non-Cryst. Solids 196, 244 (1996)
S.M. Salem, E.K. Abdel-Khalek, E.A. Mohamed, M. Farouk, J Alloys Compd. 513, 35 (2012)
B.H. Jung, H.S. Kim, J. Non-Cryst. Solids 336, 96 (2004)
Z.J. Wang, Y.C. Hu, H.K. Lu, F. Yu, J. Non-Cryst. Solids 354, 1128 (2008)
T. Zhang, M.Q. Wu, S.R. Zhang, J.M. Wang, D.H. Zhang, F.M. He, Z.P. Li, J. Alloys Compd. 509, 9279 (2011)
H. Darwish, M.M. Gomaa, J. Mater. Sci. Mater. Electron. 17, 35 (2006)
M.M. Gomaa, H. Darwish, S.M. Salman, J. Mater. Sci. Mater. Electron. 19, 5 (2008)
G. Srinivasarao, N. Veeraiah, J. Solid State Chem. 166, 104 (2002)
G. Srinivasarao, N. Veeraiah, J. Phys. Chem. Solids 63, 705 (2002)
P. Subbalakshmi, N. Veeraiah, Mater. Lett. 56, 880 (2002)
S. Ibrahim, H. Darwish, M.M. Gomaa, J. Mater. Sci. Mater. Electron. 23, 1131 (2012)
H. Darwish, S. Ibrahim, M.M. Gomaa, J. Mater. Sci. Mater. Electron. (2012). doi:10.1007/s10854-012-0873-8
V. Dimitrov, T. Komatsu, J. Solid State Chem. 163, 110 (2002)
V. Sundar, R. Yimnirun, B.G. Aitken, R.E. Newnham, Mater. Res. Bull. 33, 1307 (1998)
F.E. Salman, A. Mekki, J. Non-Cryst. Solids 357, 2658 (2011)
S. Ramesh, A.H. Yahaya, A.K. Arof, Solid State Ionics 152–153, 291 (2002)
Acknowledgments
This work was supported by Natural Science Foundation of Shandong Province (No. ZR2012EMM019), Natural Science Youth Foundation of Shandong Province (No. ZR2011EMQ005) and National Natural Science Foundation (No. 51172093, 51042009).
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Zhang, X., Yue, Y. & Wu, H. Effects of MgO/CaO on the structural, thermal and dielectric properties of aluminoborosilicate glasses. J Mater Sci: Mater Electron 24, 2755–2760 (2013). https://doi.org/10.1007/s10854-013-1166-6
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DOI: https://doi.org/10.1007/s10854-013-1166-6