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Synthesis, structure and properties of Pd@MOF-808

  • Metals & corrosion
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Abstract

The core–shell structure and penetrated structure of Pd-modified metal organic frameworks MOF-808 series materials (named as Pd@MOF-808) are successfully synthesized using Zr(IV) as centron ion, trimesic acid as ligand and Pd as modifier by simple solution method. The structure control and properties of Pd@MOF-808 are characterized by XRD, FT-IR, TEM, XPS, UV–Vis, specific surface area measurement, thermogravimetric analysis, photocatalytic hydrogen production and hydrogen storage testing. The results show that the synthesized Pd nanoparticles have been successfully introduced into the cavity and channel of MOF-808, and the structure of Pd@MOF-808 series materials could remain stable at 350 °C. Photocatalytic hydrogen production experiments exhibit the highest hydrogen production of Pd@MOF-808-b (236 μmol g−1 h−1). More importantly, the results of the adsorption experiment show that the hydrogen storage capacities of the as-prepared 10 wt% Pd@MOF-808-b could reach 2.61 wt%, 5.04 wt% and 8.20 wt% under 4 MPa at 300 K, 195 K and 77 K, respectively. Furthermore, thermodynamic analysis shows that the maximum hydrogen adsorption enthalpy of Pd@MOF-808-b up to − 1.378 kJ mol−1 indicates excellent potential for hydrogen storage and application.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (No. 21171004), Anhui Province Academic Technology Leader Training Funded Projects, the Key Technologies Research and Development Program of Anhui Province (Nos. 1704a0802134, 1604a0802113), Natural Science Foundation of Anhui (No. 1708085QE120) and Major Projects of Natural Science Research in Colleges and Universities of Anhui (No. KJ20171495).

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Authors and Affiliations

  1. Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, 230601, People’s Republic of China

    Jiong Xu, Jin Liu, Zhen Li, Xianbiao Wang & Zhuo Wang

  2. School of Materials Science and Chemical Engineering, Anhui Jianzhu University, Hefei, 230601, People’s Republic of China

    Jin Liu & Zhen Li

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  1. Jiong Xu
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  2. Jin Liu
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Correspondence to Jin Liu.

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Xu, J., Liu, J., Li, Z. et al. Synthesis, structure and properties of Pd@MOF-808. J Mater Sci 54, 12911–12924 (2019). https://doi.org/10.1007/s10853-019-03786-0

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