Abstract
An analytical model for dissolution kinetics of secondary phase particles upon isothermal annealing has been proposed. Considering the interactions of solute diffusion fields in front of the secondary phase/matrix interface upon dissolution, a Johnson–Mehl–Avrami type equation, subjected to necessary modification, was derived, in combination with a classic dissolution model for single-particle system. Compared with the semiempirical dissolution models, which are used to fit the experimental results and phase-field method simulation, the current model follows an analogous form, but with the time-dependent kinetic parameters. Distinct from the model fitting work published recently, the current model is derived from the diffusion-controlled transformation theory, while the modeling quality is guaranteed by the physically realistic model parameters. On this basis, the current model calculation leads to a clear relationship between the secondary phase volume fraction and the time. Accordingly, model predictions for isothermal θ′ dissolution in Al–3.0wt%–Cu alloy and silicon dissolution in Al–0.8wt%–Si alloy were performed; good agreement with the published experimental data has been achieved.
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Abbreviations
- C m :
-
Initial solute concentration in the matrix
- C α :
-
Solute concentration at the interface
- C β :
-
Solute concentration in the secondary phase
- D :
-
Diffusion coefficient of solute atoms
- D 0 :
-
Preexponential factor for diffusion
- f :
-
Volume fraction of the secondary phase
- f 0 :
-
Initial volume fraction of the secondary phase
- f eq :
-
Equilibrium volume fraction of the secondary phase
- f t :
-
Transformed fraction (transformation degree)
- k :
-
Dimensionless parameter related to solute concentrations, C β , C α , and C m
- K 0 :
-
Rate constant
- m :
-
Modified proportional factor
- n :
-
Transformed exponent
- Q :
-
Activation energy for dissolution
- Q D :
-
Activation energy for diffusion
- r d :
-
Decrement of the dissolving particle radius
- R :
-
Radius of the dissolving particle
- R 0 :
-
Initial radius of the dissolving particle
- t e :
-
The total transformation time needed for dissolution
- V e :
-
Extended transformed volume of the secondary phase
- x e :
-
Extended transformed fraction
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Acknowledgements
The authors are grateful to the Natural Science Foundation of China (Nos. 51134011, 51101122, and 51071127), the National Basic Research Program of China (973 Program, No. 2011CB610403), China National Funds for Distinguished Young Scientists (No. 51125002), the Fundamental Research Fund (Nos. JC20120223), and the 111 Project (No. B08040) of Northwestern Polytechnical University.
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Appendix
Appendix
Analogous to a mathematical treatment in Ref. [47], the extended transformed fraction is reformulated proceeding as follows.
For the two parts x e1 and x e2 in Eq. (34), two corresponding parameters b 1 and b 2 can be chosen in such a way that x e is due to only the first part,
Or that x e is due to only the second part,
With x e1′ = x e2′ = x e. Then, the total extended transformed fraction can be written as,
And
During dissolution, it can be seen that both x e1 and x e2 are positive and smaller than x e. Always two integers, a 1 and a 2, can be found to satisfy Eq. (35). Moreover, for integers, a 1 and a 2, it holds that \( a_{1} x_{{{\text{e}}1'}} = \sum\nolimits_{i = 1}^{{a_{1} }} {x_{{{\text{e}}1}} (i)} \) if x e1(1) = x e1(2) = …··· = x e1(a 1) = x e1′; and \( a_{2} x_{{{\text{e}}2{\prime }}} = \sum\nolimits_{i = 1}^{{a_{2} }} {x_{{{\text{e}}2}} (i)} \) if x e2(1) = x e2(2) = …··· = x e2(a 2) = x e2′. Then, taking both x e1(i) and x e2(i) equal to x e, Eq. (A.3) can be rewritten as,
Note that all fraction terms in Eq. (A.5) are equal. Substituting all x e1(i) and x e2(i) combined with Eqs. (A.1), (A.2) and (A.4), Eq. (A.5) becomes,
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Zuo, Q., Liu, F., Wang, L. et al. An analytical model for secondary phase dissolution kinetics. J Mater Sci 49, 3066–3079 (2014). https://doi.org/10.1007/s10853-013-8009-y
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DOI: https://doi.org/10.1007/s10853-013-8009-y