Abstract
The fundamental mechanisms of solid lubrication are reviewed with examples from well-known solid lubricants like the transition metal dichalcogenides and diamond-like carbon families of coatings. Solid lubricants are applied either as surface coatings or as fillers in self-lubricating composites. Tribological (friction and wear) contacts with solid lubricant coatings typically result in transfer of a thin layer of material from the surface of the coating to the counterface, commonly known as a transfer film or tribofilm. The wear surfaces can exhibit different chemistry, microstructure, and crystallographic texture from those of the bulk coating due to surface chemical reactions with the surrounding environment. As a result, solid lubricant coatings that give extremely low friction and long wear life in one environment can fail to do so in a different environment. Most solid lubricants exhibit non-Amontonian friction behavior with friction coefficients decreasing with increasing contact stress. The main mechanism responsible for low friction is typically governed by interfacial sliding between the worn coating and the transfer film. Strategies are discussed for the design of novel coating architectures to adapt to varying environments.
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References
Tabor D (1981) J Lubr Tech 103:169
Rabinowicz E (1995) Friction and wear of materials, 3rd edn. Wiley, New York, p 34
Rabinowicz E (1971) ASLE Trans 14:198
Gao GT, Mikulski PT, Harrison JA (2002) J Am Chem Soc 124:7202
Heo S-J, Sinnott SB, Brenner DW, Harrison JA (2005) In: Bhushan B (ed) Nanotribology and nanomechanics: an introduction. Springer, Heidelberg, p 623
Szlufarska I, Chandross M, Carpick RW (2008) J Phys D Appl Phys 41:123001
Pastewka L, Moser S, Moseler M (2010) Tribol Lett 39:49
Liang T, Sawyer WG, Perry SS, Sinnott SB, Phillpot SR (2008) Phys Rev B 77:104105
Liang T, Phillpot SR, Sinnott SB (2009) Phys Rev B 79:245110
Jang I, Burris DL, Dickrell PL, Barry PR, Santos C, Perry SS, Phillpot SR, Sinnott SB, Sawyer WG (2007) J Appl Phys 102:123509
Barry PR, Chiu PY, Perry SS, Sawyer WG, Phillpot SR, Sinnott SB (2011) Langmuir 27:9910
Prasad SV, Michael JR, Christenson TR (2003) Scripta Mater 48:255
Jungk JM, Michael JR, Prasad SV (2008) Acta Mater 56:1956
Johnson KL (1985) Contact mechanics. Cambridge University Press, Cambridge
Larsen-Basse J (1992) ASM handbook, vol 18: friction, lubrication, and wear technology, p. 30
Greenwood JA, Williamson JBP (1966) Proc R Soc (Lond) A 295:300
Whitehouse DJ, Archard JF (1970) Proc R Soc (Lond) A316:97
Bower AF, Johnson KL (1989) J Mech Phys Solids 34:471
Bowden FP, Tabor D (1986) The friction and lubrication of solids. Clarendon Press, Oxford, pp 112–120
Stoyanov P, Chromik RR, Goldbaum D, Lince JR, Zhang X (2010) Tribol Lett 40:199
Stoyanov P, Strauss HW, Chromik RR (2012) Wear 274–275:149
Chromik RR, Wahl KJ (2005) World Tribology Congress III. American Society of Mechanical Engineers, New York, pp 829–830
Singer IL, Dvorak SD, Wahl KJ, Scharf TW (2003) J Vac Sci Technol A 21:S232
Wahl KJ, Sawyer WG (2008) MRS Bull 33:1159
Strauss HW, Chromik RR, Hassani S, Klemberg-Sapieha JE (2011) Wear 272:133
Schmellenmeier H (1953) Exp Tech Phys 1:49
Eisenberg S, Chabot R (1971) J Appl Phys 42:2953
Braithwaite ER (1964) Solid lubricants and surfaces. Clarendon Press, Oxford, p 139
Deacon RF, Goodman JF (1958) Proc R Soc Lond A 243:464
Roselman IC, Tabor D (1976) J Phys D 9:2517
Buckley DH (1981) Surface effects in adhesion, friction, wear and lubrication. Elsevier, Amsterdam
Skinner J, Gane N, Tabor D (1971) Nature 232:195
Savage RH (1948) J Appl Phys 19:1
Ramadanoff D, Glass SW (1944) Trans Am Inst Electr Eng 63:825
Yen BK, Schwickert BE, Toney MF (2004) Appl Phys Lett 84:4702
Robertson J (1986) Adv Phys 35:317
Tallant DR, Parmeter JE, Siegal MP, Simpson RL (1995) Diam Relat Mater 4:191
Erdemir A, Donnet C (eds) (2008) Tribology of diamond-like carbon films: fundamentals and applications. Springer, New York
Robertson J (2002) Mater Sci Eng R 37:129
Erdemir A, Donnet C (2006) J Phys D Appl Phys 39:R311
Koidl P, Wagner C, Dischler B, Wagner J, Ramsteiner M (1990) Mater Sci Forum 52:41
Tamor MA, Vassell WC, Carduner KR (1991) App Phys Lett 58:592
Donnet C, Fontaine J, Lefevre F, Grill A, Patel V, Jahnes C (1999) J App Phys 85:3264
Weiler M, Sattel S, Giessen T, Jung K, Ehrhardt H, Veerasamy VS, Robertson J (1996) Phys Rev B 53:1594
Erdemir A, Eryilmaz OL, Fenske G (2000) J Vac Sci Tech A 18:1987
Erdemir A (2002) Proc Inst Mech Eng J 216:387
Scharf TW, Ohlhausen JA, Tallant DR, Prasad SV (2007) J Appl Phys 101:0635211
Grill A (1993) Wear 168:143
Donnet C (1998) Surf Coat Technol 100–101:180
Scharf TW, Singer IL (2003) Tribol Lett 14:137
Kester DJ, Brodbeck CL, Singer IL, Kyriakopoulos A (1999) Surf Coat Technol 113:268
Scharf TW, Singer IL (2002) Tribol Trans 45:363
Prasad SV, Dugger MT, Christenson TR, Tallant DR (2004) J Manuf Process 6:107
Scharf TW, Singer IL (2009) Tribol Lett 36:43
Sánchez-López JC, Erdemir A, Donnet C, Rojas TC (2003) Surf Coat Technol 163–164:444
Chromik RR, Strauss HW, Scharf TW (2012) J Manag 64:35
Fontaine J, Le Mogne T, Loubet JL, Belin M (2005) Thin Solid Films 482:99
Fontaine J, Belin M, Le Mogne T, Grill A (2004) Tribol Int 37:869
Erdemir A, Fontaine J, Donnet C (2008) In: Donnet C, Erdemir A (eds) Tribology of diamond-like carbon films: fundamentals and applications. Springer, New York, p 237
Erdemir A, Halter M, Fenske GR, Zuiker C, Csencsits R, Krauss AR, Gruen DM (1997) Trib Trans 40:667
Erdemir A, Fenske GR, Krauss AR, Gruen DM, McCauley T, Csencsits RT (1999) Surf Coat Technol 121:565
Konicek AR, Grierson DS, Gilbert PUPA, Sawyer WG, Sumant AV, Carpick RW (2008) Phys Rev Lett 100:235502–235505
Grierson DS, Sumant AV, Konicek AR, Abrecht M, Birrell J, Auciello O, Carlisle JA, Scharf TW, Dugger MT, Gilbert PUPA, Carpick RW (2007) J Vac Sci Tech B 25:1700
Prasad SV, Zabinski JS (1997) Nature 387:761
Singer IL (1992) In: Singer IL, Pollock HM (eds) Fundamentals of friction: macroscopic and microscopic processes. Kluwer, Dordrecht, p 237
Brainard WA (1969) NASA TN D5141
Sliney HE (1982) Tribol Int 15:303
Prasad SV, Zabinski JS (1993) J Mater Sci Lett 12:1413
Prasad SV, Zabinski JS, McDevitt NT (1995) Tribol Trans 38:57
Zabinski JS, Donley MS, Prasad SV, McDevitt NK (1994) J Mater Sci 29:4834. doi:10.1007/BF00356530
Muratore C, Bultman JE, Aouadi SM, Voevodin AA (2011) Wear 270:140
Wahl KJ, Dunn DN, Singer IL (1999) Wear 230:175
Scharf TW, Kotula PG, Prasad SV (2010) Acta Mater 58:4100
Hu JJ, Wheeler R, Zabinski JS, Shade PA, Shiveley A, Voevodin AA (2008) Tribol Lett 32:49
Muratore C, Voevodin AA (2009) Ann Rev Mater Res 39:297
Hilton R, Fleischauer PD (1992) Surf Coat Technol 54–55:435
Zabinski JS, Donley MS, Walck SD, Schneider TR, McDevitt NT (1995) Tribol Trans 38:894
Teer DG (2001) Wear 251:1068
Fox VC, Renevier N, Teer DG, Hampshire J, Rigato V (1999) Surf Coat Technol 116–119:492
Scharf TW, Prasad SV, Dugger MT, Kotula PG, Goeke RS, Grubbs RK (2006) Acta Mater 54:4731
Scharf TW, Diercks DR, Gorman BP, Prasad SV, Dugger MT (2009) Tribol Trans 52:284
Briscoe BJ, Tabor D (1975) Wear 34:29
Bahadur S, Tabor D (1984) Wear 98:1
Burris DL, Boesl B, Bourne GR, Sawyer WG (2007) Macro Mater Eng 292:387
Dellacorte C, Sliney HE (1992) Lubric Eng 48:877
Dellacorte C, Edmonds BJ, Benoy PA (2001) NASA TM-210944
Prasad SV, Zabinski JS (1997) Wear 203:498
Prasad SV, Walck SD, Zabinski JS (2000) Thin Solid Films 360:107
Zabinski JS, Sanders JH, Nainaparampil J, Prasad SV (2000) Tribol Lett 8:103
Goto M, Kasahara A, Tosa M (2011) Tribol Lett 43:155
Mohseni H, Scharf TW (2012) J Vac Sci Technol A 30:01A149-1
Rebholz C, Ziegele H, Leyland A, Matthews A (1998) J Vac Sci Technol A 16:2851
Saito T, Honda F (2000) Wear 237:253
Koskilinna JO, Linnolahti M, Pakkanen TA (2006) Tribol Lett 24:37
Erdemir A, Fenske GR, Erck RA (1990) Surf Coat Technol 44:588
Erdemir A, Erck RA, Robles J (1991) Surf Coat Technol 49:435
Dvorak SD, Wahl KJ, Singer IL (2002) Tribol Trans 45:354
Lovell M, Deshmukh P, Sawyer WG, Mobley A (2006) Wear 260:1295
Doll GL, Mensah BA, Mohseni H, Scharf TW (2010) J Therm Spray Technol 19:510
Prasad SV, Scharf TW, Kotula PG, Michael JR, Christenson TR (2009) J Microelectromech Syst 18:695
Erdemir A, In Bhushan B (eds) (2001) Handbook of modern tribology. CRC Press, Boca Raton, FL, p 787
Acknowledgements
Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy’s National Nuclear Security Administration under Contract DE-AC04-94AL85000. The authors thank Joe Michael, Michael Rye, Paul Kotula, Dick Grant, and Bonnie McKenzie for their assistance in electron microscopy, and Jill Glass and Robert Grubbs for their critical reviews. TWS would also like to acknowledge partial support of this work from The National Science Foundation (Grant Numbers: CMMI-0700828 and CMMI-1100648).
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T. W. Scharf—On sabbatical from the Department of Materials Science and Engineering, The University of North Texas, Denton, TX 76203-5310 USA.
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Scharf, T.W., Prasad, S.V. Solid lubricants: a review. J Mater Sci 48, 511–531 (2013). https://doi.org/10.1007/s10853-012-7038-2
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DOI: https://doi.org/10.1007/s10853-012-7038-2