Abstract
Poly(butylene terephthalate)-block-poly(tetramethylene glycol) (PBT-PTMG)-based thermoplastic elastomer (TPE) was filled with nano TiO2 particles by direct melt blending. The particle content in matrix was varied from 1.3 to 4.9 vol.%. The samples were characterized using SEM, μCT, DSC, TGA, DMTA and tensile test. SEM examination shows strong interfacial interactions between TPE matrix and TiO2 particles due to formation of chemical bonds. The incorporation of TiO2 particles increases overall the thermal properties of soft and hard segments such as the glass transition temperature, the melting temperature, and the thermal stability of material. The tensile properties of TPE are also significantly improved indicated by increased tensile strength and modulus. Increasing particle content leads to increased mechanical properties and thermal stability of composites.
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References
Gabrielse W, Soliman M, Dijkstra K (2001) Macromolecule 34:1685
Miller JA, Mckenna JM, Pruckmayr G, Epperson JE, Cooper SL (1985) Macromolecules 18:1727
Veenstra H, Hoogvliet RM, Norder B, Posthuma de Boer AJ (1998) Polym Sci B 36:1795
Holden G, Legge NR, Quirk RP, Schroeder HE (1996) Thermoplastic elastomers: a comprehensive review, 2nd edn. Hanser, Munich
Bhowmick AK, Stephens HL (eds) (2001) Handbook of elastomers, 2nd edn. Marcel Dekker Inc., New York
Coleman D (1954) J Polym Sci 14:15
Zhu LL, Wegner G (1981) Makromol Chem 182:3625
Cella RJJ (1973) Polym Sci Symp 42:727
Phillips RA, Mckenna JM, Cooper SL (1994) J Polym Sci B 32:791
Schmalz H, van Guldener V, Gabrielse W, Lange R, Abetz V (2002) Macromolecules 35:5491
Stevenson JS, Cooper SL (1988) Macromolecules 21:1309
Seymour RW, Overton JR, Corley LS (1975) Macromolecules 8:331
El Fray M, Slonecki J (1998) Macromol Sci Phys B 37:143
Hagashiyama A, Yamamoto Y, Chujo R, Wu M (1992) Polymer 24:1345
Slonecki J (1992) Polimery 37:19
Khaled SM, Sui RH, Charpentier PA, Rizkalla AS (2007) Langmuir 23:3988
Weng YX, Li L, Liu L, Wang L, Yang GZ (2003) J Phys Chem B 107:4356
Paul SA, Sinturel C, Joseph K, Gem Mathew GD, Pothan LA, Thomas S (2010) Polym Eng Sci 50:384
Ezquerra T (2005) In: Fakirov S (ed) Handbook of condensation thermoplastic elastomer. Wiley, Weinheim
Acknowledgements
The authors gratefully acknowledge German Research Foundation (DFG) for the fellowship in the framework of the graduate school GRK 814. They also thank Mr. Dieter Krüger from Allod Werkstoff GmbH (Germany) for kindly providing the TPE-E materials.
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Zhou, RJ., Burkhart, T. Thermal and mechanical properties of poly(ether ester)-based thermoplastic elastomer composites filled with TiO2 nanoparticles. J Mater Sci 46, 2281–2287 (2011). https://doi.org/10.1007/s10853-010-5068-1
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DOI: https://doi.org/10.1007/s10853-010-5068-1