Skip to main content
SpringerLink
Log in

On the complexation of some univalent cations with beauvericin in nitrobenzene saturated with water

  • Original Article
  • Published:
Journal of Inclusion Phenomena and Macrocyclic Chemistry Aims and scope Submit manuscript

Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq) + 1·Cs+(nb) ⇆ 1·M+(nb) + Cs+(aq) taking place in the two-phase water–nitrobenzene system (M+ = Li+, Na+, K+, Rb+, H3O+, NH4 +, Tl+; 1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) were determined. Moreover, the stability constants of the 1·M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Rb+ < Na+, H3O+ < Tl+ < NH + 4 < K+ < Li+.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2

Similar content being viewed by others

References

  1. Hamill, R.L., Higgens, C.E., Boaz, H.E., Gorman, M.: The structure of beauvericin: a new depsipeptide antibiotic toxic to artemia salina. Tetrahedron Lett. 49, 4255–4258 (1969)

    Article  CAS  Google Scholar 

  2. Logrieco, A., Moretti, A., Castella, G., Kostecki, M., Golinski, P., Ritieni, A., Chelkowski, J.: Beauvericin production by Fusarium species. Appl. Environ. Microbiol. 64, 3084–3088 (1998)

    CAS  Google Scholar 

  3. Logrieco, A., Rizzo, A., Ferracane, R., Ritieni, A.: Occurrence of beauvericin and enniatins in wheat affected by Fusarium avenaceum head blight. Appl. Environ. Microbiol. 68, 82–85 (2002)

    Article  CAS  Google Scholar 

  4. Jestoi, M., Rokka, M., Yli-Mattila, T., Parikka, P., Rizzo, A., Peltonen, K.: Presence and concentrations of the Fusarium-related mycotoxins beauvericin, enniatins and moniliformin in finnish grain samples. Food Addit. Contam. 21, 794–802 (2004)

    Article  CAS  Google Scholar 

  5. Makrlík, E., Vaňura, P.: Applications of the dicarbollylcobaltate(III) anion in the water/nitrobenzene extraction system. Talanta 32, 423–429 (1985)

    Article  Google Scholar 

  6. Makrlík, E., Vaňura, P., Selucký, P.: Stability constants of some univalent cation complexes of 2,3-naphtho-15-crown-5 in nitrobenzene saturated with water. J. Solut. Chem. 38, 1129–1138 (2009)

    Article  Google Scholar 

  7. Makrlík, E., Vaňura, P., Selucký, P.: Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dibutyl diethylcarbamoylmethylene phosphonate. J. Solut. Chem. 39, 692–700 (2010)

    Article  Google Scholar 

  8. Makrlík, E., Vaňura, P., Selucký, P.: Solvent extraction of microamounts of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of “classical” CMPO. Acta Chim. Slov. 55, 223–227 (2008)

    Google Scholar 

  9. Makrlík, E., Vaňura, P., Selucký, P., Babain, V.A., Smirnov, I.V.: Extraction properties of synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide in the water-nitrobenzene system with regard to Eu3+and Am3+. Acta Chim. Slov. 56, 718–722 (2009)

    Google Scholar 

  10. Makrlík, E., Vaňura, P., Selucký, P.: Solvent extraction of barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of Slovafol 909. Acta Chim. Slov. 57, 922–926 (2010)

    Google Scholar 

  11. Makrlík, E., Vaňura, P.: Extraction of K+, Rb+ and Tl+ from water into nitrobenzene by using cesium dicarbollylcobaltate in the presence of hexaethyl calix[6]arene hexaacetate. Z. Phys. Chem. 223, 247–252 (2009)

    Article  Google Scholar 

  12. Makrlík, E., Vaňura, P., Selucký, P.: Extraction of microamounts of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of “classical” CMPO. Z. Phys. Chem. 223, 253–261 (2009)

    Article  Google Scholar 

  13. Toman, P., Makrlík, E., Vaňura, P., Kašička, V.: Protonation of benzo-18-crown-6: extraction and DFT study. Z. Phys. Chem. 225, 265–270 (2011)

    Article  CAS  Google Scholar 

  14. Makrlík, E., Vaňura, P., Sedláková, Z.: Solvent extraction of microamounts of strontium and barium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 600. J. Radioanal. Nucl. Chem. 280, 607–611 (2009)

    Article  Google Scholar 

  15. Makrlík, E., Vaňura, P., Selucký, P.: Solvent extraction of europium and americium into phenyltrifluoromethyl sulfone by using synergistic mixture of hydrogen dicarbollylcobaltate and “classical” CMPO. J. Radioanal. Nucl. Chem. 283, 571–575 (2010)

    Article  Google Scholar 

  16. Makrlík, E., Vaňura, P., Selucký, P.: Solvent extraction of strontium and barium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and dibenzo-24-crown-8. J. Radioanal. Nucl. Chem. 284, 137–142 (2010)

    Article  Google Scholar 

  17. Romanovskiy, V.N., Smirnov, I.V., Babain, V.A., Todd, T.A., Herbst, R.S., Law, J.D., Brewer, K.N.: The universal solvent extraction (UNEX) process. I. Development of the UNEX process solvent for the separation of cesium, strontium and the actinides from acidic radioactive waste. Solvent Extr. Ion Exch. 19, 1–21 (2001)

    Article  CAS  Google Scholar 

  18. Law, J.D., Herbst, R.S., Todd, T.A., Romanovskiy, V.N., Babain, V.A., Esimantovskiy, V.M., Smirnov, I.V., Zaitsev, B.N.: The universal solvent extraction (UNEX) process. II. Flowsheet development and demonstration of the UNEX process for the separation of cesium, strontium and actinides from actual acidic radioactive waste. Solvent Extr. Ion Exch. 19, 23–36 (2001)

    Article  CAS  Google Scholar 

  19. Hawthorne, M.F., Young, D.C., Andrews, T.D., Howe, D.V., Pilling, R.L., Pitts, A.D., Reintjes, M., Warren Jr, L.F., Wegner, P.A.: π-Dicarbollyl derivatives of the transition metals. Metallocene analogs. J. Am. Chem. Soc. 90, 879–896 (1968)

    Article  CAS  Google Scholar 

  20. Rais, J.: Individual extraction constants of univalent ions in the system water-nitrobenzene. Collect. Czech. Chem. Commun. 36, 3253–3262 (1971)

    CAS  Google Scholar 

  21. Makrlík, E., Božek, F.: Individual extraction constants of some univalent cations in the water–nitrobenzene system. Polish J. Chem. 72, 949–952 (1998)

    Google Scholar 

  22. Makrlík, E., Hálová, J., Kyrš, M.: Contribution to the thermodynamics of complexes of alkali metal cations with dibenzo-18-crown-6 in water-nitrobenzene extraction system. Collect. Czech. Chem. Commun. 49, 39–44 (1984)

    Article  Google Scholar 

  23. Makrlík, E., Vaňura, P.: Stability of complex of Cs+ with valinomycin in nitrobenzene saturated with water. J. Radioanal. Nucl. Chem. 214, 339–346 (1996)

    Article  Google Scholar 

  24. Daňková, M., Makrlík, E., Vaňura, P.: Stability of the valinomycin– rubidium complex in water saturated nitrobenzene. J. Radioanal. Nucl. Chem. 221, 251–253 (1997)

    Article  Google Scholar 

  25. Makrlík, E., Vaňura, P.: Extraction of sodium picrate into nitrobenzene in the presence of valinomycin. ACH Models Chem. 135, 213–218 (1998)

    Google Scholar 

  26. Makrlík, E., Vaňura, P.: Experimental evidence for a valinomycin–proton complex. Monatsh. Chem. 137, 157–161 (2006)

    Article  Google Scholar 

  27. Makrlík, E., Dybal, J., Vaňura, P.: A combined experimental and theoretical study on the complexation of Li+ with valinomycin. Monatsh. Chem. 140, 251–254 (2009)

    Article  Google Scholar 

  28. Makrlík, E., Dybal, J., Vaňura, P.: A combined extraction and DFT study on the complexation of K+ with valinomycin. Monatsh. Chem. 140, 1289–1292 (2009)

    Article  Google Scholar 

  29. Makrlík, E., Dybal, J., Vaňura, P.: A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin. Monatsh. Chem. 141, 1191–1194 (2010)

    Article  Google Scholar 

  30. Makrlík, E., Vaňura, P.: Stability of valinomycin–thallium complex in nitrobenzene saturated with water. Polish J. Chem. 72, 650–653 (1998)

    Google Scholar 

  31. Makrlík, E., Selucký, P., Vaňura, P.: Unpublished results

  32. Pedersen, C.J.: Cyclic polyethers and their complexes with metal salts. J. Am. Chem. Soc. 89, 2495–2496 (1967)

    Article  CAS  Google Scholar 

  33. Pedersen, C.J.: Cyclic polyethers and their complexes with metal salts. J. Am. Chem. Soc. 89, 7017–7036 (1967)

    Article  CAS  Google Scholar 

  34. Kolthoff, I.M.: Application of macrocyclic compounds in chemical analysis. Anal. Chem. 51, 1R–22R (1979)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, project No. 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, by the Czech Ministry of Education, Youth, and Sports (project MSM 6046137307), and by the Czech Science Foundation (project P205/10/2280).

Author information

Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic

    Emanuel Makrlík

  2. Nuclear Research Institute, 250 68, Řež, Czech Republic

    Pavel Selucký

  3. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    Petr Vaňura

  4. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovského sq. 2, 162 06, Prague 6, Czech Republic

    Petr Toman

Authors
  1. Emanuel Makrlík
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pavel Selucký
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Petr Vaňura
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Petr Toman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emanuel Makrlík.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makrlík, E., Selucký, P., Vaňura, P. et al. On the complexation of some univalent cations with beauvericin in nitrobenzene saturated with water. J Incl Phenom Macrocycl Chem 73, 329–333 (2012). https://doi.org/10.1007/s10847-011-0060-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10847-011-0060-1

Keywords

Search

Navigation