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Transport of silver ion through bulk liquid membrane using macrocyclic and acyclic ligands as carriers in organic solvents

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Abstract

The bulk liquid membrane transport of silver (I) ion was studied by dibenzopyridino-18-crown-6(DBPY18C6), 4-nitrobenzo-15-crown-5(NB15C5), 2-aminothiaphenol and a new synthesized ligand, 1,4-dioxa-7,10-dithiacyclododecane-2,3-dione as carriers in nitrobenzene (NB). The effects of pH on the source phase and receiving phase, the nature and concentration of stripping agents in the receiving phase and the picrate concentration as counter ion in source phase were investigated. The results show that the efficiency of transport of the Ag+ ion through membranes, changes with the nature of the ligand. The efficiency transport increases for the ligands with donating nitrogen and sulfur atoms with respect to oxygen donor atoms. Maximum transport efficiency was observed for silver (I) ion in the presence of thiosulfate ion ( \( {\text{S}}_{{\text{2}}} {\text{O}}^{{2-}}_{{\text{3}}} \)) as a suitable stripping agent. The results show that the sequence of transport efficiency for Ag+ ion using DBPY18C6, NB15C5, 2-aminothiaphenol and 1,4-dioxa-7,10-dithiacyclododecane-2,3-dione as carriers in organic solvents is: nitrobenzene > dichloromethane > 1,2- dichloroethane > chloroform.

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References

  1. Kolthoff, M., Elving, P.J. (ed): Treatise on Analytical Chemistry. Interscience, New York (1996)

  2. Rener, H.: Ulmanns Encyklopädie der Technischen Chemie, vol. 21, 4th Verlag Chemie, Weinheim (1982)

  3. Saito, T.: Selective transport of alkali and alkaline earth metallic ions through a supported liquid membrane containing tripentyl phosphates ace a carrier. Separ. Sci. Technol. 28, 1629–1640 (1993)

    Article  CAS  Google Scholar 

  4. Hiratani, K., Takahashi, T., Sugihara, H., Kasuga, K., Fujiwara, K., Hayashita, T., Bartsch, R.A.: Selective liquid membrane transport of lead (II) by a aceyclic polyether dicarboxylic acid ionophore. Anal. Chem. 69, 3002–3007 (1997)

    Article  CAS  Google Scholar 

  5. Safavi, A., Rastegaezadeh, S.: Selective and efficient uphill transport of Cu(II) through liquid membrane. Talanta 42, 2039–2042 (1995)

    Article  CAS  Google Scholar 

  6. Akhond, M., Shamsipu, M.: Specific uphill transport of zinc havezn (SNA) 42-ion using Na+. Dicyclohexyl-18-crown-6 have carrier J. Chin. Chem. Soc. 43, 225–229 (1996)

    CAS  Google Scholar 

  7. Akhond, M., Shamsipur, M.: Specific uphill transport of Cd2+ ion by a cooperative carrier composed of aza-18-crown-6 and palmitic acid. J. Membr. Sci. 117, 221–226 (1996)

    Article  CAS  Google Scholar 

  8. Hancock, R.D.: Macrocycles and their selectivity for metal ions on the basis of size. Pure. Appl. Chem. 58, 1445–1452 (1986)

    Article  CAS  Google Scholar 

  9. Araki, T., Tsukube, H.: Liquid Membranes. Ends, CRC press, Boca Ratoon, FL (1990)

  10. Damu, K.V., Shaikjee, M.S., Michael, J.P., Howard, A.S., Hancock, R.D.: Control of metal ion selectivity in ligands containing neutral oxygen and pyridyl groups. Inorg. Chem. 25, 3879–3883 (1986)

    Article  CAS  Google Scholar 

  11. Rounaghi, G.H., Popov, A.I.: Complexing ability of some mixed sulfur-oxygen crown ethers in nonaqueous solvents. J. Inorg. Nucl. Chem. 43, 911–915 (1981)

    Article  CAS  Google Scholar 

  12. Lindoy, L.F.: Transition metal complexes of synthetic macrocyclic ligands. Chem. Soc. Rev. 4, 421–441 (1975)

    Article  CAS  Google Scholar 

  13. Sayedi, S.M., Sadeghian, A., Sadeghian, H., Hazrathoseyni, A., Sadeghian, M.: Synthesis and biological evaluation of some new thioether-ester crown ethers. Phosphorus Sulfur Silica. 182, 265–272 (2007)

    Article  CAS  Google Scholar 

  14. Chia, P.S.K., Lindoy, L.F., Walker, G.W., Everett, G.W.: Supramolecular transport of metal amine complexes through liquid membranes by the ionophore lasalocid A. Pure Appl. Chem. 65, 521–526 (1993)

    Article  CAS  Google Scholar 

  15. Kazemi, S.Y., Shamsipur, M.: Membrane transport of Cu (II) with a cooperative carrier composed of dibenzodiaza-15-crown-4 and oleic acid. Sep. Purif. Technol. 17, 181–187 (1999)

    Article  CAS  Google Scholar 

  16. Rounaghi, G.H., Kazemi, M.S.: Study of bulk membrane transport of some heavy metal cations using three macrocyclic ligands containing oxygen and nitrogen heteroatom. J. Incl. Phenom. Macro. 55, 347–352 (2006)

    Article  CAS  Google Scholar 

  17. Kadidas, C., Heftor, G., Marcus, Y.: Gibbs energies of transfer of cations from water to mixed aqueous organic solvent. Chem. Rev. 100, 828–830 (2002)

    Google Scholar 

  18. Izatt, R.M., Bradshaw, J.S., Nielsen, S.A., Lamb, J.D., Christensen, J.J., Sen, D.: Thermodynamic and kinetic data for cation- macrocycle interaction. Chem. Rev. 85, 271–339 (1985)

    Article  CAS  Google Scholar 

  19. Izutzu, K.: Electrochemistry in Non-aqueous Solutions, pp. 85, Wiley-VCH (2002)

  20. Yu-Hwang, W., Shong Shih, J.: Conformational features of 2.3-peptides. J. Chin. Chem. Soc. 47, 1215 (2000)

    Google Scholar 

  21. Shamsipur, M., Azimi, G., Mashhadizadeh, M.H., Madaeni, S.S.: Selective transport of silver ion through a supported liquid membrane using hexathia-18-crown-6 as carrier. Anal. Sci. 17, 491–496 (2001)

    Article  CAS  Google Scholar 

  22. Akhond, M., Tashkhourian, J.: Highly selective transport of Ag+ ion through a liquid membrane containing 2- Mercaptobenzothiazole as carrier. Bull. Korean. Chem. Soc. 24, 489–493 (2003)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

    G. H. Rounaghi & H. Sadeghian

  2. Department of Chemistry, Faculty of Sciences, Islamic Azad University of Bojnord, Bojnord, Iran

    M. S. Kazemi

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  1. G. H. Rounaghi
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  2. M. S. Kazemi
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  3. H. Sadeghian
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Correspondence to G. H. Rounaghi.

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Rounaghi, G.H., Kazemi, M.S. & Sadeghian, H. Transport of silver ion through bulk liquid membrane using macrocyclic and acyclic ligands as carriers in organic solvents. J Incl Phenom Macrocycl Chem 60, 79–83 (2008). https://doi.org/10.1007/s10847-007-9355-7

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  • DOI: https://doi.org/10.1007/s10847-007-9355-7

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