Abstract
The intercalation of xylenol orange, morin and Calmaigite into NiaY zeolite were studied by XRD, TGA, and BET and diffuse reflectance. These dye incorporated into NaY zeolite by ion exchange in aqueous phase. Results show that xylenol orange can be intercalating better into zeolite. The dye molecules are strongly retained in the channels of zeolites. The prepared intercalated dye/zeolite, for the first time, was used as the modifier for carbon past electrode. The dye/zeolite modified carbon paste electrode was developed for the voltammetric determination of Cu(II). Copper(II) was selectively preconcentrated. Results shows the peak current intensity increased in order of calmagite > xylenol orange > morin dyes intercalated in zeolite. The results agree with complex formation of those dyes as chelating agents with Copper(II).
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References
Schulz-Ekloff, G.: Stud. Surf. Sci. Catal. 85, 145 (1994)
Schulz-Ekloff, G., Wohrle, D., van Duffel, B., Schoonheydt, R.A.: Chromophores in porous silicas and minerals: preparation and optical properties. Micropor. Mesopor. Mat. 51, 91–138 (2002)
De Vos, D.E., Jacobs, P.A.: Stud. Surf. Sci. Catal. 137, 957 (2001)
Wohrle, D., Schulz-Ekloff, G.: Molecular sieve encapsulated organic dyes and metal chelates. Adv. Mater. 6, 875–880 (1994)
Bedioui, F.: Zeolite-encapsulated and clayintercalated metal porphyrin, phthalocyanine and Schiff-base complexes as models for biomimetic oxidation catalysts: an overview. Coord. Chem. Rev. 144, 39–68 (1995)
Zanjanchi, M.A., Sohrabnejad, Sh.: Intercalation of methylene blue into mordenites: role of zeolite acidity. J. Incl. Phenom. Macro. 46, 43–49 (2003)
Walcarius, A.: Zeolite-modified electrodes: analytical applications and prospects. Electroanalysis 8, 971–986 (1996)
Walcarius, A.: Zeolite-modified electrodes in electroanalytical chemistry. Anal. Chim. Acta. 384, 1–16 (1999)
Kilinic, S., Yuksel, U., Akcay, H.: Development of a novel carbon paste electrode containing a natural zeolite for the voltammetric determination of copper. Electrochem. Commun. 7, 130–134 (2005)
Arvand, M., Sohrabnejad, Sh., Mousavi, M.F., Shamsipuor, M., Zanjanchi, M.A.: Electrochemical study of methylene blue incorporated into mordenite type zeolite and its application for amperometric determination of ascorbic acid in real samples. Anal. Chim. Acta. 491, 193–201 (2003)
Breck, D.W., TonaWanda, N.Y., assigned to Union Carbid. Pat .No.3130007, Patented April, 21, 1964
Xie, Y.C., Tang, Y.Q.: Spontaneous monolayer dispersion of oxides and salts onto surfaces of supports: application to heterogeneous catalysis. Adv. Catal. 37, 1 (1990)
Bergmann, K., Okonski, C.T.: A spectroscopic study of methylene blue monomer, dimer, and complexes with montmorillonite. J. Phys. Chem. 67, 2169–2177 (1963)
Cenens, J., Schoonheydt, K.A.: Visible spectroscopy of methylene blue on hectorite, laponite B, and barasym in aqueous suspension. Clay Clay Miner. 36, 214–224 (1988)
Hulanicki, A., Ackermann S.G.: Compleximetric indicators: characteristics and applications. Pure Appl. Chem. 55(7), 1137–1230 (1983)
Hajian, R., Shams, E.: Application of adsorptive stripping voltammetry to the determination of bismuth and copper in the presence of morin. Anal. Chim. Acta. 491, 63–69 (2003)
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Zendehdel, M., Babaei, A. & Alami, S. Intercalation of xylenol orange, morin and calmagite into NaY zeolite and their application in dye/zeolite modified electrode. J Incl Phenom Macrocycl Chem 59, 345–349 (2007). https://doi.org/10.1007/s10847-007-9334-z
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DOI: https://doi.org/10.1007/s10847-007-9334-z