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High Performance Removal of Anionic and Cationic Dye Pollutants with Co3O4 Modified Nanoclinoptilolite: Kinetics and Adsorption Equilibrium Studies

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Abstract

In this paper Co3O4 doped nanoclinoptilolite was synthesized and characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), field emission scanning electron microscopy (FESEM) and energy-dispersive X-ray spectroscopy (EDX) techniques. The adsorption efficiency for removing of methylene blue was about 95% in 10 min. The effect of some factors such as adsorbent dose, concentration of analyte and pH was investigated for enhancing the removing efficiency. Moreover Freundlich and Langmuir patterns were plotted for this new nanocomposite. Maximum of adsorption capacity was obtained from slope of Langmuir and was about 25 mg/g. The kinetic study for methylene blue shows a second order kinetic with rate constant about 0.02 g/mg/min. The prepared nanocomposite was successfully applied for removing some color compounds such as methylene blue, methyl green, and methyl red and also binary dye mixtures.

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References

  1. R. Kant, Nat. Sci. 4, 22 (2012)

    CAS  Google Scholar 

  2. P.A. Carneiro, R.F. Pupo Nogueira, M.V.B. Zanoni, Dyes Pigments 74, 127 (2007)

    Article  CAS  Google Scholar 

  3. R. Mohammadzadeh Kakhki, R. Tayebee, M. Mohammadpour, F. Ahsani, J. Incl. Phenom. Macrocycl. Chem. https://doi.org/10.1007/s10847-018-0803-3 (2018)

    Article  Google Scholar 

  4. R. Mohammadzadeh Kakhki, F. Ahsani, J. Mater. Sci. Mater. Electron. 29, 3767 (2018)

    Article  CAS  Google Scholar 

  5. R. Mohammadzadeh Kakhki, R. Tayebee, F. Ahsani, J. Mater. Sci. Mater. Electron. 28, 5941 (2017)

    Article  CAS  Google Scholar 

  6. R. Mohammadzadeh Kakhki, A. Khorrampoor, M. Rabbani, F. Ahsani, J. Mater. Sci. Mater. Electron. 28, 4095 (2017)

    Article  CAS  Google Scholar 

  7. R. Mohammadzadeh Kakhki, F. Ahsani, N. Mir, J. Mater. Sci. Mater. Electron. 27, 11509 (2016)

    Article  CAS  Google Scholar 

  8. A. Nezamzadeh-Ejhieh, Z. Banan, Desalination 284, 157 (2012)

    Article  CAS  Google Scholar 

  9. M. Bahrami, A. Nezamzadeh-Ejhieh, Mater. Sci. Semicond. Process. 30, 275 (2015)

    Article  CAS  Google Scholar 

  10. A. Bagheri Ghomi, V. Ashayeri Iranian, J. Catal. 2, 135 (2012)

    Google Scholar 

  11. A. Buthiyappan, A.R. Abdul Aziz, W.M. Ashri, W. Daud, Rev. Chem. Eng. 32, 1 (2016)

    Article  CAS  Google Scholar 

  12. M. Karimi-Shamsabadi, A. Nezamzadeh-Ejhieh, J. Mol. Catal. A 418, 103 (2016)

    Article  Google Scholar 

  13. Z. Shams-Ghahfarokhi, A. Nezamzadeh-Ejhieh, Mater. Sci. Semicond. Process. 39, 265 (2015)

    Article  CAS  Google Scholar 

  14. D. Ghosk, K.G. Bhattacharyya, Appl. Clay Sci. 20, 295 (2002)

    Article  Google Scholar 

  15. F.D. Mai, C.C. Chen, J.L. Chen, S.C. Liu, J. Chromatogr. A 1189, 355 (2008)

    Article  CAS  Google Scholar 

  16. B.B. Hayes, S. Azadi, R.R. Sullivan, B.J. Meade, J. Allergy Clin. Immunol. 113, S57 (2004)

    Article  Google Scholar 

  17. R. Mohammadzadeh Kakhki, GhH. Rounaghi, J. Chem. Eng. Data. https://doi.org/10.1021/je200220d (2011)

    Article  Google Scholar 

  18. Y.S. Ho, W.T. Chiu, C.C. Wang, Bioresour. Technol. 96, 1285 (2005)

    Article  CAS  Google Scholar 

  19. R. Mohammadzadeh Kakhki, R. Tayebee, S. Hedayat, J. Appl. Organomet. Chem. https://doi.org/10.1002/aoc.4033 (2017)

    Article  Google Scholar 

  20. D.A. Fungaro, C.P. Magdalena, Int. J. Chem. Environ. Eng. Sci. 3, 74 (2012)

    Google Scholar 

  21. F. Akarslan, Ö Altinay, Acta Phys. Pol. A 128, B405 (2015)

    Article  CAS  Google Scholar 

  22. S. Thussing, P. Gazdzicki, P. Jakob, Surf. Sci. 623, 29 (2014)

    Article  CAS  Google Scholar 

  23. M. Nosuhi, A. Nezamzadeh-Ejhieh, Electrochim. Acta 223, 47 (2017)

    Article  CAS  Google Scholar 

  24. A. Nezamzadeh-Ejhieh, M. Shahanshahi, J. Ind. Eng. Chem. 19, 2026 (2013)

    Article  CAS  Google Scholar 

  25. Q. Tang, Q. Zhang, P. Wang, Y. Wang, H. Wan, Chem. Mater. 16, 1967 (2004)

    Article  CAS  Google Scholar 

  26. Y. Nozue, T. Kodaira, T. Goto, Phys. Rev. Lett. 68, 3789 (1992)

    Article  CAS  Google Scholar 

  27. M. Wark, A. Brückner, T. Liese, W. Grünert, Chem. Tech. 49, 1 (1997)

    Google Scholar 

  28. J. Singh, J. Im, J.E. Whitten, J.W. Soares, D.M. Steeves, Langmuir 25, 9947 (2009)

    Article  CAS  Google Scholar 

  29. B. Bardakci, S. Bahseli, Indian J. Pure Appl. Phys. 48, 615 (2010)

    CAS  Google Scholar 

  30. C.G. Wu, T. Bein, Science 266, 1013 (1994)

    Article  CAS  Google Scholar 

  31. R.F. Howe, Appl. Organomet. Chem. 1, 188 (1987)

    Google Scholar 

  32. G. Horvath, K. Kawazoe, J. Chem. Eng. Jpn. 16, 470 (1983)

    Article  CAS  Google Scholar 

  33. F. Meneau, G. Sankar, N. Morgante, S. Cristol, C.R.A. Catlow, J.M. Thomas, G.N. Greaves, Nucl. Instrum. Methods Phys. Res. B 199, 499 (2003)

    Article  CAS  Google Scholar 

  34. M.A. Khalilzadeh, A. Hosseini, A. Pilevar, Eur. J. Org. Chem. 8, 1587 (2011)

    Article  Google Scholar 

  35. M.A. Khalilzadeh, H. Keipour, A. Hosseini, D. Zareyee, New J. Chem. 38, 42 (2014)

    Article  CAS  Google Scholar 

  36. S. Salmanpour, M.A. Khalilzadeh, A. Hosseini, Comb. Chem. High Throughput Screen 16, 339 (2013)

    Article  CAS  Google Scholar 

  37. H. Keipour, A. Hosseini, M.A. Khalilzadeh, T. Ollevier, Lett. Org. Chem. 12, 645 (2015)

    Article  CAS  Google Scholar 

  38. S. Hallajian, M.A. Khalilzadeh, M. Tajbakhsh, E. Alipour, Z. Safaei, Comb. Chem. High Throughput Screen 18, 486 (2015)

    Article  CAS  Google Scholar 

  39. H. Keipour, A. Hosseini, A. Afsari, R. Oladee, M.A. Khalilzadeh, T. Ollevier, Can. J. Chem. 94, 95 (2016)

    Article  CAS  Google Scholar 

  40. J. Balou, M.A. Khalilzadeh, D. Zareyee, Catal. Lett. 147, 2612 (2017)

    Article  CAS  Google Scholar 

  41. P. Kowalczyk, M. Sprynskyy, A.P. Terzyk, M. Lebedynets, J. Namies´nik, B. Buszewski, J. Colloid Interface Sci. 297, 77 (2006)

    Article  CAS  Google Scholar 

  42. Y.F. Wang, F. Lin, W.Q. Pang, J. Hazard. Mater. 142, 160 (2007)

    Article  CAS  Google Scholar 

  43. Y.E. Benkli, M.F. Can, M. Turan, M.S. Celik, Water Res. 39, 487 (2005)

    Article  CAS  Google Scholar 

  44. S.O. Saheed, S.J. Modise, A.M. Sipalma, Adv. Mater. Res. 781–784, 2249 (2013)

    Article  Google Scholar 

  45. M.A. Khakizadeh, H. Keipour, A. Hosseini, D. Zareyee, New J. Chem. 38, 42 (2014)

    Article  Google Scholar 

  46. H. Jahangirian, Dig. J. Nanomater. Biostruct. 8, 1405 (2013)

    Google Scholar 

  47. K. Dastafkan, M. Sadeghi, A. Obeydavi, Int. J. Environ. Sci. Technol. https://doi.org/10.1007/s13762-014-0701-1 (2014)

    Article  Google Scholar 

  48. Y. Huang, W. Wang, Q. Feng, F. Dong, J. Saudi Chem. Soc. 09, 1 (2013)

    Google Scholar 

  49. D. Bae, K. Seff, Microporous Mesoporous Mater. 33, 265 (1999)

    Article  CAS  Google Scholar 

  50. A. Dryer, An Introduction to Zeolite Molecular Sieves (Wiley, Chichester, 1988)

    Google Scholar 

  51. H.Y. Jeong, D.C. Koh, K.S. Lee, H.H. Lee, Appl. Catal. B 127, 68 (2012)

    Article  CAS  Google Scholar 

  52. F. Mohandes, F. Davar, M. Salavati-Niasari, J. Magn. Magn. Mater. 322, 872 (2009)

    Article  Google Scholar 

  53. M. Suzuki, K. Tsutsumi, H. Takahashi, Y. Saito, Zeolite 8, 381 (1988)

    Article  CAS  Google Scholar 

  54. J.S. Chung, H.G. Yun, D.J. Koh, Y.G. Kim, J. Mol. Catal. 79, 199 (1993)

    Article  CAS  Google Scholar 

  55. V.F. Puntes, K.M. Krishnan, A.P. Alivisatos, Science 291, 2115 (2001)

    Article  CAS  Google Scholar 

  56. S.T. Homeyer, W.M.H. Sachtler, J. Catal. 117, 91 (1989)

    Article  CAS  Google Scholar 

  57. P. Kowalczyk, M. Sprynskyy, A.P. Terzyk, M. Lebedynets,, B. Buszewski, J. Namiesnik, J. Colloid Interface Sci. 297, 77 (2006)

    Article  CAS  Google Scholar 

  58. B.A. Holmberg, H. Wang, Y. Yan, Microporous Mesoporous Mater. 74, 189 (2004)

    Article  CAS  Google Scholar 

  59. M. Salavati-Niasari, Polyhedron 28, 2321 (2009)

    Article  CAS  Google Scholar 

  60. J. Graaf, A.J. van Dillen, K.P. Jong, D.C. Koningsberger, J. Catal. 203, 307 (2001)

    Article  Google Scholar 

  61. A. Nezamzadeh-Ejhieh, A. Shirzadi, Chemosphere 107, 136 (2014)

    Article  CAS  Google Scholar 

  62. A. Nezamzadeh-Ejhieh, E. Afshari, Microporous Mesoporous Mater. 153, 267 (2012)

    Article  CAS  Google Scholar 

  63. M. Anari-Anaraki, A. Nezamzadeh-Ejhieh, J. Colloid Interface Sci. 440, 272 (2015)

    Article  CAS  Google Scholar 

  64. A. Nezamzadeh-Ejhieh, M. Kabiri-Samani, J. Hazard. Mater. 260, 339 (2013)

    Article  CAS  Google Scholar 

  65. S. Zhang, W. Xu, M. Zeng, J. Li, J. Li, J. Xu, X. Wang, J. Mater. Chem. A 1, 11691 (2013)

    Article  CAS  Google Scholar 

  66. A. Nezamzadeh-Ejhieh, H. Zabihi-Mobarakeh, J. Ind. Eng. Chem. 20, 1421 (2014)

    Article  CAS  Google Scholar 

  67. A. Nezamzadeh-Ejhieha, M. Karimi-Shamsabadi, Chem. Eng. J. 228, 631 (2013)

    Article  Google Scholar 

  68. C. Pirovano, S. Trasatti, J. Electroanal. Chem. 180(s 1–2), 171 (1984)

    Article  CAS  Google Scholar 

  69. L. Wang, J. Li, Y. Wang, L. Zhao, Q. Jiang, Chem. Eng. J. 181–182, 72 (2012)

    Article  Google Scholar 

  70. M. Heidari-Chaleshtori, A. Nezamzadeh-Ejhieh, New J. Chem. 39, 9396 (2015)

    Article  CAS  Google Scholar 

  71. Y. Ho, W. Chiu, C. Wang, Bioresour. Technol. 96, 1285 (2005)

    Article  CAS  Google Scholar 

  72. P.S. Kumar, S. Ramalingam, C. Senthamarai, M. Niranjanaa, P. Vijayalakshmi, S. Sivanesan, Desalination 261, 52 (2010)

    Article  Google Scholar 

  73. S. Fakari, A. Nezamzadeh-Ejhieh, New J. Chem. 41, 3811 (2017)

    Article  CAS  Google Scholar 

  74. X. Jin, M. Jiang, X. Shan, Z. Pei, Z. Chen, J. Colloid Interface Sci. 328, 243 (2008)

    Article  CAS  Google Scholar 

  75. D. Ghosh, K.G. Bhattacharyya, Appl. Clay Sci. 20, 295 (2002)

    Article  CAS  Google Scholar 

  76. R. Ansari, Z. Mosayebzadeh, J. Iran. Chem. Soc. 7, 339 (2010)

    Article  CAS  Google Scholar 

  77. M. Banimahd Keivani, K. Zare, H. Aghaie, R. Ansari, J. Phys. Theor. Chem. 6, 63 (2009)

    Google Scholar 

  78. M. Dogan, M. Alkan, A. Türkyilmaz, Y. Özdemir, J. Hazard. Mater. 109, 141 (2004)

    Article  CAS  Google Scholar 

  79. M. Soni, A.K. Sharma, J.K. Srivastava, S. Yadav, Int. J. Chem. Sci. Appl. 3, 338 (2012)

    CAS  Google Scholar 

  80. K.V. Kumar, V. Ramamurthi, S. Sivanesan, J. Colloid Interface Sci. 284, 14 (2005)

    Article  CAS  Google Scholar 

  81. C.D. Woolard, J. Strong, C.R. Erasmus, Appl. Geochem. 17, 1159 (2002)

    Article  CAS  Google Scholar 

  82. T. Shen, J. Luo, S. Zhang, X. Luo, J. Environ. Chem. Eng. 3, 1372 (2015)

    Article  CAS  Google Scholar 

  83. J. Sheng, Y. Xie, Y. Zhou, Appl. Clay Sci. 46, 422 (2009)

    Article  CAS  Google Scholar 

  84. R. Han, J. Zhang, P. Han. Chem. Eng. J. 145, 496 (2009)

    Article  CAS  Google Scholar 

  85. O. Yavuz, C. Saka, Appl. Clay Sci. 85, 96 (2013)

    Article  CAS  Google Scholar 

  86. B. Acemioglu, Chem. Eng. J. 106, 73 (2005)

    Article  CAS  Google Scholar 

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  1. Department of Chemistry, Faculty of Sciences, University of Gonabad, Gonabad, Iran

    Roya Mohammadzadeh Kakhki, Samira Hedayat & Fatemeh Ahsani

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  1. Roya Mohammadzadeh Kakhki
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  2. Samira Hedayat
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  3. Fatemeh Ahsani
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Correspondence to Roya Mohammadzadeh Kakhki.

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Mohammadzadeh Kakhki, R., Hedayat, S. & Ahsani, F. High Performance Removal of Anionic and Cationic Dye Pollutants with Co3O4 Modified Nanoclinoptilolite: Kinetics and Adsorption Equilibrium Studies. J Inorg Organomet Polym 28, 2264–2274 (2018). https://doi.org/10.1007/s10904-018-0937-1

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