Abstract
Niobate ceramics such as NaNbO3 and KNbO3 have been studied as promising Pb-free piezoelectric ceramics, but their sintering densification is fairly difficult. In the present study, highly dense Na0.5K0.5NbO3 ceramics with submicron grains were prepared using SPS, whose density was raised to 4.47 g/cm3 (>99% of the theoretical density) at 920 °C. Reasonably good ferroelectric and piezoelectric properties were obtained in the SPSed Na0.5K0.5NbO3 ceramics after annealing in air. The effect of annealing time on the electrical properties was investigated to determine optimal processing condition. The piezoelectric parameter (d 33) of the Na0.5K0.5NbO3 ceramics annealed properly reached 148 pC/N.
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References
L. Egreton, D.M. Dillon, J. Am. Ceram. Soc. 42, 438 (1959)
R.E. Jaeger, L. Egreton, J. Am. Ceram. Soc. 45, 209 (1962)
B.T. Matthias, J. Remeika, Phys. Verh. 82, 727 (1951)
T. Wada, K. Tsuji, T. Saito, Y. Matsuo, Jpn. J. Appl. Phys. 42, 6110 (2003)
Y. Guo, K. Kakimoto, H. Ohsato, Appl. Phys. Lett. 85, 4121 (2004).
R. Wang, R. Xie, T. Sekiya, Y. Shimojo, Mater. Res. Bull. 39, 1709–1715 (2004)
M. Matsubara, K. Kikuta, S. Hirano, J. Appl. Phys. 97, 114105 (2005)
B.-P. Zhang, L.-M. Zhang, J.-F. Li, H.-L. Zhang, S.-Z. Jin, The Fifth Pacific Rim International Conference On Advanced Materials And Processing, Pts 1-5 Materials Science Forum, 475–479 (2005)
J.-F. Li, K. Wang, B.-P. Zhang and L.-M. Zhang, J. Am. Ceram. Soc., (2005) (accepted)
Y. Saito, H. Takao, I. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Nature 432, 84–87 (2004)
K. Takagi, S. Kikuchi, J.-F. Li, H. Okamura, R. Watanabe, A. Kawasaki, J. Am. Ceram. Soc., 87, 8 (2004)
Acknowledgments
The authors wish to thank Toyota Motor Corporation for their support to Tsinghua-Toyota collaborative research on lead-free piezoelectric ceramics. This work was also partly supported by the National Natural Science Foundation of China (Grant No. 50325207) and the Ministry of Science and Technology (Grant No. 2002CB613306).
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Wang, K., Zhang, BP., Li, JF. et al. Lead-free Na0.5K0.5NbO3 piezoelectric ceramics fabricated by spark plasma sintering: Annealing effect on electrical properties. J Electroceram 21, 251–254 (2008). https://doi.org/10.1007/s10832-007-9137-z
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DOI: https://doi.org/10.1007/s10832-007-9137-z