Abstract
This study presented the research work carried out for the investigation of chemical composition of bulk precipitation in two geographically and economically distinct areas, namely Gampaha and Kandy Districts. This study was conducted from 2013 to 2014 at three sampling stations in each District. The bulk precipitation was analyzed for pH, conductivity, Na+, NH4+, K+, Mg2+, Ca2+, F−, Cl−, NO3−, SO42−, Pb, Cu, Mn, Al, Zn and Fe for a total of 375 samples. Only 8% events of acidic precipitation were recorded in Gampaha District when compared with 3% in Kandy District. The volume weighted average concentrations of the major ionic species present in precipitation samples were in the order of Na+ > Ca2+ > Cl− > NH4+ > SO42− > Mg2+ > NO3− > K+ > F− in the Gampaha stations, while the order was NH4+ > Ca2+ > Na+ > Cl− > SO42− > Mg2+ > NO3− > K+ > F− in Kandy District. Neutralization of acidity of precipitation is much more related to CaCO3 than NH3, and high content of Ca2+ ions present in both Districts strongly supports this fact. When considering marine contribution, SO42−/Na+, Ca2+/Na+ and Mg2+/Na+ ratios are higher than the reference value suggesting contribution of sources other than marine. Depositions of both Districts show that the concentration of Al is the highest while that of Mn is the lowest. Principal component analysis suggests that influencing human activities on chemical composition of rain water depends on thermal power plant, oil refinery, heavy traffic and waste incineration in the study area.
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References
Aberatne, V. D. & Ileperuma, O. (2006). 3644-12881-1-PB.pdf. In National Science Foundation Sri Lanka (Vol. 34, Issue 3, pp. 137–141).
Akkoyunlu, B. (2003). Analyses of wet and bulk deposition in four different regions of Istanbul, Turkey. Atmospheric Environment, 37(25), 3571–3579. https://doi.org/10.1016/S1352-2310(03)00349-2.
Alkhashman, O. (2005). Study of chemical composition in wet atmospheric precipitation in Eshidiya area, Jordan. Atmospheric Environment, 39(33), 6175–6183. https://doi.org/10.1016/j.atmosenv.2005.06.056.
Bhaskar, V. V., & Rao, P. S. P. (2017). Annual and decadal variation in chemical composition of rain water at all the ten GAW stations in India. Journal of Atmospheric Chemistry, 74(1), 23–53. https://doi.org/10.1007/s10874-016-9339-3.
Bisht, D. S., Srivastava, A. K., Joshi, H., Ram, K., Singh, N., Naja, M., Srivastava, M. K., & Tiwari, S. (2017). Chemical characterization of rainwater at a high-altitude site “Nainital” in the Central Himalayas, India. Environmental Science and Pollution Research, 24(4), 3959–3969. https://doi.org/10.1007/s11356-016-8093-z.
Carvalho, S. C. P., de Lima, J. L. M. P., & de Lima, M. I. P. (2014). Rainwater sequential sampler: assessing intra-event water composition variability. Journal of Engineering Research and Technology, 1(1), 1–7 http://journal.iugaza.edu.ps/index.php/JERT/article/view/26.
Croisé, L., Ulrich, E., Duplat, P., & Jaquet, O. (2005). Two independent methods for mapping bulk deposition in France. Atmospheric Environment, 39(21), 3923–3941. https://doi.org/10.1016/j.atmosenv.2005.03.021.
Deusdará, K. R. L., Forti, M. C., Borma, L. S., Menezes, R. S. C., Lima, J. R. S., & Ometto, J. P. H. B. (2017). Rainwater chemistry and bulk atmospheric deposition in a tropical semiarid ecosystem: the Brazilian Caatinga. Journal of Atmospheric Chemistry, 74(1), 71–85. https://doi.org/10.1007/s10874-016-9341-9.
Dissanayake, C. B., & Weerasooriya, S. V. R. (1985). The environmental chemistry of rainwater in Sri Lanka. International Journal of Environmental Studies, 26(1–2), 71–86. https://doi.org/10.1080/00207238508710245.
Gao, B., Ouyang, W., Cheng, H., Xu, Y., Lin, C., & Chen, J. (2019). Interactions between rainfall and fine particulate matter investigated by simultaneous chemical composition measurements in downtown Beijing. Atmospheric Environment, 218(September), 1–9. https://doi.org/10.1016/j.atmosenv.2019.117000.
Granat, L., Suksomsankh, K., Simachaya, S., Tabucanon, M., & Rodhe, H. (1996). Regional background acidity and chemical composition of precipitation in Thailand. Atmospheric Environment, 30(10–11), 1589–1596. https://doi.org/10.1016/1352-2310(95)00455-6.
Herrera, J., Rodríguez, S., & Baéz, A. P. (2009). Chemical composition of bulk precipitation in the metropolitan area of Costa Rica, Central America. Atmospheric Research, 94(2), 151–160. https://doi.org/10.1016/j.atmosres.2009.05.004.
Huang, Y., Wang, Y., & Zhang, L. (2008a). Long-term trend of chemical composition of wet atmospheric precipitation during 1986-2006 at Shenzhen City, China. Atmospheric Environment, 42(16), 3740–3750. https://doi.org/10.1016/j.atmosenv.2007.12.063.
Huang, K., Zhuang, G., Xu, C., Wang, Y., & Tang, A. (2008b). The chemistry of the severe acidic precipitation in Shanghai, China. Atmospheric Research, 89(1–2), 149–160. https://doi.org/10.1016/j.atmosres.2008.01.006.
Ileperuma, O. (2015). Model assessment of acid deposition potential by SOx in Sri Lanka. Journal of the National Science Foundation of Sri Lanka, 43(3), 281. https://doi.org/10.4038/jnsfsr.v43i3.7956.
Jain, C. D., Madhavan, B. L., & Ratnam, M. V. (2019). Source apportionment of rainwater chemical composition to investigate the transport of lower atmospheric pollutants to the UTLS region. Environmental Pollution, 248, 166–174. https://doi.org/10.1016/j.envpol.2019.02.007.
Li, Y. C., Zhang, M., Shu, M., Ho, S. S. H., Liu, Z. F., Wang, X. X., & Zhao, X. Q. (2016). Chemical characteristics of rainwater in Sichuan basin, a case study of Ya’an. Environmental Science and Pollution Research, 23(13), 13088–13099. https://doi.org/10.1007/s11356-016-6363-4.
Martins, E. H., Nogarotto, D. C., Mortatti, J., & Pozza, S. A. (2019). Chemical composition of rainwater in an urban area of the southeast of Brazil. Atmospheric Pollution Research, 10(2), 520–530. https://doi.org/10.1016/j.apr.2018.10.003.
Migliavacca, D., Teixeira, E., Wiegand, F., Machado, A., & Sanchez, J. (2005). Atmospheric precipitation and chemical composition of an urban site, Guaba hydrographic basin, Brazil. Atmospheric Environment, 39(10), 1829–1844. https://doi.org/10.1016/j.atmosenv.2004.12.005.
Mimura, A. M. S., Almeida, J. M., Vaz, F. A. S., de Oliveira, M. A. L., Ferreira, C. C. M., & Silva, J. C. J. (2016). Chemical composition monitoring of tropical rainwater during an atypical dry year. Atmospheric Research, 169, 391–399. https://doi.org/10.1016/j.atmosres.2015.11.001.
Park, S. M., Seo, B. K., Lee, G., Kahng, S. H., & Jang, Y. (2015). Chemical composition of water soluble inorganic species in precipitation at Shihwa Basin, Korea. Atmosphere, 6(6), 732–750. https://doi.org/10.3390/atmos6060732.
Paternoster, M., Sinisi, R., Mancusi, C., Pilat, K., Sabia, A., & Mongelli, G. (2014). Natural versus anthropogenic influences on the chemical composition of bulk precipitation in the southern Apennines, Italy: a case study of the town of Potenza. Journal of Geochemical Exploration, 145, 242–249. https://doi.org/10.1016/j.gexplo.2014.07.003.
Pu, W., Quan, W., Ma, Z., Shi, X., Zhao, X., Zhang, L., Wang, Z., & Wang, W. (2017). Long-term trend of chemical composition of atmospheric precipitation at a regional background station in Northern China. Science of the Total Environment, 580, 1340–1350. https://doi.org/10.1016/j.scitotenv.2016.12.097.
Rao, P. S. P., Tiwari, S., Matwale, J. L., Pervez, S., Tunved, P., Safai, P. D., Srivastava, A. K., Bisht, D. S., Singh, S., & Hopke, P. K. (2016). Sources of chemical species in rainwater during monsoon and non-monsoonal periods over two mega cities in India and dominant source region of secondary aerosols. Atmospheric Environment, 146, 90–99. https://doi.org/10.1016/j.atmosenv.2016.06.069.
Rastegari Mehr, M., Keshavarzi, B., & Sorooshian, A. (2019). Influence of natural and urban emissions on rainwater chemistry at a southwestern Iran coastal site. Science of the Total Environment, 668, 1213–1221. https://doi.org/10.1016/j.scitotenv.2019.03.082.
Staelens, J., Deschrijver, A., Vanavermaet, P., Genouw, G., & Verhoest, N. (2005). A comparison of bulk and wet-only deposition at two adjacent sites in Melle (Belgium). Atmospheric Environment, 39(1), 7–15. https://doi.org/10.1016/j.atmosenv.2004.09.055.
Szép, R., Bodor, Z., Miklóssy, I., Niță, I. A., Oprea, O. A., & Keresztesi, Á. (2019). Influence of peat fires on the rainwater chemistry in intra-mountain basins with specific atmospheric circulations (Eastern Carpathians, Romania). Science of the Total Environment, 647, 275–289. https://doi.org/10.1016/j.scitotenv.2018.07.462.
Tennakoon, P. L. K., Hettiarachchi, L. S. K., & Gunaratne, G. K. A. (2006). An assessment of rainwater quality from the tea growing areas of Sri Lanka. Sri Lankan Journal of Tea Science, 71(1), 50–62.
Tripathy, G. R., Mishra, S., Danish, M., & Ram, K. (2019). Elevated barium concentrations in rain water from east-coast of India: role of regional lithology. Journal of Atmospheric Chemistry, 76(1), 59–72. https://doi.org/10.1007/s10874-019-9387-6.
Uchiyama, R., Okochi, H., Katsumi, N., & Ogata, H. (2017). The impact of air pollutants on rainwater chemistry during “urban-induced heavy rainfall” in downtown Tokyo, Japan. Journal of Geophysical Research, 122(12), 6502–6519. https://doi.org/10.1002/2017JD026803.
Venkateshwarlu, P., & Satyanarayana, J. (2014). Chemical composition of rainwater at an urban area during southwest monsoon. International Journal of Modern Chemistry and Applied Science, 1(1), 1–4.
Vieira-Filho, M. S., Lehmann, C., & Fornaro, A. (2015). Influence of local sources and topography on air quality and rainwater composition in Cubatão and São Paulo, Brazil. Atmospheric Environment, 101, 200–208. https://doi.org/10.1016/j.atmosenv.2014.11.025.
Yu, H., He, N., Wang, Q., Zhu, J., Gao, Y., Zhang, Y., Jia, Y., & Yu, G. (2017). Development of atmospheric acid deposition in China from the 1990s to the 2010s. Environmental Pollution, 231(3), 182–190. https://doi.org/10.1016/j.envpol.2017.08.014.
Zeng, Y., & Hopke, P. K. (1989). A study of the sources of acid precipitation in Ontario, Canada. Atmospheric Environment (1967), 23(7), 1499–1509. https://doi.org/10.1016/0004-6981(89)90409-5.
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Authors of this research paper would like to thank financial support from the National Research Council of Sri Lanka (Grant No. NRC/11/127) for providing equipment and other expenses.
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Liyandeniya, A., Deeyamulla, M. & Priyantha, N. Atmospheric chemical composition of bulk deposition at two geographically distinct locations in Sri Lanka. Environ Monit Assess 192, 452 (2020). https://doi.org/10.1007/s10661-020-08412-0
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DOI: https://doi.org/10.1007/s10661-020-08412-0