Abstract
Rainwater quality is of utmost importance as it can be used to predict atmospheric quality which of course governs, to some extent, the health of the ecosystem. In this regard, the research reported here was to study chemical characteristics of precipitation in Kelaniya, Gampaha District, one of the most populated and most urbanized districts in Sri Lanka. This study was conducted during the period from 2012 to 2014, and wet precipitation was analyzed for pH, conductivity, Na+, NH4+, K+, Mg2+, Ca2+, F−, Cl−, NO3−, SO42−, Pb, Cu, Mn, Al, Zn, and Fe for a total of seventy-eight (78) samples. Volume-weighted average concentrations of the major ionic species present in precipitation samples were in the order of Na+ > Ca2+ > Cl− > SO42− > NH4+ > Mg2+ > NO3− > K+ > F−. Neutralization of the acidic species would take place due to the presence of NH4+ and CaCO3. When considering marine contribution, SO42−/Na+, Ca2+/Na+, and Mg2+/Na+ ratios are higher than the reference value suggesting that contribution of sources be possible other than marine. Among metallic constituents, the concentration of Al is the highest while that of Mn is the lowest. Significant correlation is observed among certain ions and elements (Ca2+, SO42−, Mg2+, Al, Cu, Fe, Zn, and H+) which indicates their source of origin and chemical interaction. This study reveals that chemical composition of rain water depends on both anthropogenic activities and natural phenomena.
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References
Akkoyunlu BO, Tayanc M (2003) Analyses of wet and bulk deposition in four different regions of Istanbul, Turkey. Atmos Environ 37(25):3571–3579
Alkhashman O (2005) Study of chemical composition in wet atmospheric precipitation in Eshidiya area, Jordan. Atmos Environ 39(33):6175–6183
Bhaskar VV, Rao PSP (2017) Annual and decadal variation in chemical composition of rain water at all the ten GAW stations in India. J Atmos Chem 74(1):23–53
Bisht DS et al (2017) Chemical characterization of rainwater at a high-altitude site “Nainital” in the central Himalayas, India. Environ Sci Pollut Res 24(4):3959–3969
Cao YZ et al (2009) Chemical characteristics of wet precipitation at an urban site of Guangzhou, South China. Atmos Res 94(3):462–469
Carvalho SCP, de Lima JLMP, de Lima M I P (2014) Rainwater sequential sampler: assessing intra-event water composition variability. J Engi Res Technol 1(1): 1–7.
Chakraborty B, Gupta A (2018) Study and interpretation of chemical composition of rainwater in selected urban and rural locations in India using multivariate analysis. AIP Conference Proceedings, 1952.
Chakraborty A, Gupta T, Tripathi SN (2016) Chemical composition and characteristics of ambient aerosols and rainwater residues during Indian summer monsoon: insight from aerosol mass spectrometry. Atmos Environ 136:144–155
Czerwińska J, Wielgosiński G (2019) Changes in the pollution of Lodz voivodship rainwater as a result of changes in pollutant immissions. Acta Innov 30:31–37
Deusdará KRL et al (2017) Rainwater chemistry and bulk atmospheric deposition in a tropical semiarid ecosystem: the Brazilian Caatinga. J Atmos Chem 74(1):71–85
Huang K et al (2008) The chemistry of the severe acidic precipitation in Shanghai. China Atmos Res 89(1–2):149–160
Huston R et al (2009) Characterisation of atmospheric deposition as a source of contaminants in urban rainwater tanks. Water Res 43(6):1630–1640
Ileperuma O (2015) Model assessment of acid deposition potential by SOx in Sri Lanka. J Nat Sci Found of Sri Lanka 43(3):281
Li YC et al (2016) Chemical characteristics of rainwater in Sichuan basin, a case study of Ya’an. Environ Sci Pollut Res 23(13):13088–13099
Lin X et al (2019) Rainwater in Guangzhou, China: oxidizing properties and physicochemical characteristics. Atmos Pollut Res 10(1):303–312
Liu P et al (2018) Assessment of heavy metal characteristics and health risks associated with PM 2.5 in Xi’an, the largest city in northwestern China. Air Qual Atmos Hlth 11(9):1037–1047. https://doi.org/10.1007/s11869-018-0598-9
Liyandeniya AB, Deeyamulla MP, Priyantha N. (2020) Atmospheric chemical composition of bulk deposition at two geographically distinct locations in Sri Lanka, Environ Monit Asses. 192(7). doi: 10.1007/s10661-020-08412-0.
Martins EH et al (2019) Chemical composition of rainwater in an urban area of the southeast of Brazil. Atmos Pollut Res 10(2):520–530
Mosley L (2005) Water quality of rainwater, SOPAC Miscellaneous Reports, (February) :1–19.
Ouyang W et al (2019) Rainwater characteristics and interaction with atmospheric particle matter transportation analyzed by remote sensing around Beijing. Sci Total Environ 651:532–540
Park SM et al (2015) Chemical composition of water soluble inorganic species in precipitation at Shihwa Basin, Korea. Atmosphere 6(6):732–750
Rao PSP et al (2016) Sources of chemical species in rainwater during monsoon and non-monsoonal periods over two mega cities in India and dominant source region of secondary aerosols. Atmos Environ 146:90–99
Rastegari MM, Keshavarzi B, Sorooshian A (2019) Influence of natural and urban emissions on rainwater chemistry at a southwestern Iran coastal site. Sci Total Environ 668:1213–1221
Romero Orué M, Gaiero D, Kirschbaum A (2019) Seasonal characteristics of the chemical composition of rainwaters from Salta city, NW Argentina. Environ Earth Sci 78(1)
Singh SP et al (2018) Cations chemistry characterization of rainwater of the Varanasi district in the indo-gangetic plains India. Inter J Chem Studies 6(1):1380–1384
Staelens J et al (2005) A comparison of bulk and wet-only deposition at two adjacent sites in Melle (Belgium). Atmos Environ 39(1):7–15
Weerasundara L et al (2017) Microorganisms and heavy metals associated with atmospheric deposition in a congested urban environment of a developing country: Sri Lanka. Sci Total Environ 584–585:803–812
Weerasundara L, Magana-Arachchi DN, Ziyath AM, Goonetilleke A, Vithanage M (2018) Health risk assessment of heavy metals in atmospheric deposition in a congested city environment in a developing country: Kandy City, Sri Lanka. J Environ Manag 220:198–206
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This study was financially supported by the National Research Council of Sri Lanka (Grant No. NRC/11/127).
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Liyandeniya, A.B., Deeyamulla, M.P. & Priyantha, N. Source apportionment of rainwater chemical composition in wet precipitation at Kelaniya in Sri Lanka. Air Qual Atmos Health 13, 1497–1504 (2020). https://doi.org/10.1007/s11869-020-00903-w
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DOI: https://doi.org/10.1007/s11869-020-00903-w