Abstract
The moisture sorption behavior of white and naturally colored cotton fibers is studied by dynamic vapor sorption. Dark brown and brown fibers show a higher sorption capacity compared to beige and white fibers. The differences in sorption capacity are found to be related to the maturity and crystallinity index of the fibers. All fibers exhibited sorption hysteresis to varying degrees throughout the full relative humidity range. The variations in hysteresis behavior are mainly attributed to the differences in crystallinity index of the fibers. In addition the monolayer and polylayer moisture content is analyzed using the Hailwood Horrobin model. Monolayer sorption is most closely related to the crystallinity index and, to a lower extent, maturity of the fibers. For beige and white fibers monolayer sorption remains almost constant, whereas for darker fibers it shows a substantial increase with increasing color difference. In contrast, polylayer sorption shows a general increasing trend over the whole studied color spectrum. Also a noticeable relationship was found between the total hysteresis and the monolayer sorption. Yet such relation was less evident for polylayer sorption. This study contributes to the better understanding of the dynamic moisture sorption behavior of white and naturally colored cotton fibers. This improved understanding is important for optimal application of naturally colored cotton fibers in novel materials.
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Abidi N, Hequet E, Ethridge D (2007) Thermogravimetric analysis of cotton fibers: relationships with maturity and fineness. J Appl Polym Sci 103(6):3476–3482. doi:10.1002/app.24465
Al-Muhtaseb AH, McMinn WAM, Magee TRA (2004) Water sorption isotherms of starch powders: part 1: mathematical description of experimental data. J Food Eng 61(3):297–307. doi:10.1016/S0260-8774(03)00133-X
Barrer RM (1947) The solubility of gases in elastomers. Trans Faraday Soc 43:3. doi:10.1039/tf9474300003
Bradbury JH (1963) Sorption of liquids by wool part III accessibility of wool to sorbates. J Appl Polym Sci 7(2):557–568. doi:10.1002/app.1963.070070213
Bredereck K, Hermanutz F (2005) Man–made cellulosics. Rev Prog Col Rel Topics 35(1):59–75. doi:10.1111/j.1478-4408.2005.tb00160.x
Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60(2):309–319. doi:10.1021/ja01269a023
Ceylan Ö, Van Landuyt L, Meulewaeter F, De Clerck K (2012) Moisture sorption in developing cotton fibers. Cellulose 19(5):1517–1526. doi:10.1007/s10570-012-9737-x
Corradini E, Teixeira EM, Paladin PD, Agnelli JA, Silva ORRF, Mattoso LHC (2009) Thermal stability and degradation kinetic study of white and colored cotton fibers by thermogravimetric analysis. J Therm Anal Calorim 97(2):415–419. doi:10.1007/s10973-008-9693-8
Dickerson DK, Lane EF, Rodriguez DF (1999) Naturally colored cotton: resistance to changes in color and durability when refurbished with selected laundry aids. California Agricultural Technology Institute, California State University, Fresno
Dutt Y, Wang XD, Zhu YG, Li YY (2004) Breeding for high yield and fibre quality in coloured cotton. Plant Breed 123(2):145–151. doi:10.1046/j.1439-0523.2003.00938.x
El Mogahzy YE, Broughton RM (1992) “Regressional” observations of HVI fiber properties, yarn quality, and processing performance of medium staple cotton part I: HVI fiber parameters. Text Res J 62(4):218–226. doi:10.1177/004051759206200406
Gehlen MH (2010) Kinetics of autocatalytic acid hydrolysis of cellulose with crystalline and amorphous fractions. Cellulose 17(2):245–252. doi:10.1007/s10570-009-9385-y
Hailwood AJ, Horrobin S (1946) Absorption of water by polymers: analysis in terms of a Simple model. Trans Faraday Soc 42:B084. doi:10.1039/tf946420b084
Hill TL (1950) Statistical mechanics of adsorption. X. Thermodynamics of adsorption on an elastic adsorbent. J Chem Phys 18:791. doi:10.1063/1.1747777
Hill CAS, Norton A, Newman G (2009) The water vapor sorption behavior of natural fibres. J Appl Polym Sci 112(3):1524–1537. doi:10.1002/app.29725
Hill CAS, Norton AJ, Newman G (2010) The water vapor sorption properties of sitka spruce determined using a dynamic vapor sorption apparatus. Wood Sci Technol 44(3):497–514. doi:10.1007/s00226-010-0305-y
Joly C, Gauthier R, Escoubes M (1996) Partial masking of cellulosic fiber hydrophilicity for composite applications. Water sorption by chemically modified fibers. J Appl Polym Sci 61(1):57–69. doi:10.1002/(SICI)1097-4628(19960705)61:1<57:AID-APP7>3.0.CO;2-T
Kachrimanis K, Noisternig MF, Griesser UJ, Malamataris S (2006) Dynamic moisture sorption and desorption of standard and silicified microcrystalline cellulose. Eur J Pharm Biopharm 64(3):307–315. doi:10.1016/j.ejpb.2006.05.019
Kohler R, Ausperger B (2003) A numeric model for the kinetics of water vapor sorption on cellulosic reinforcement fibers. Compos Interfaces 10:255–276. doi:10.1163/156855403765826900
Kohler R, Alex R, Brielmann R, Ausperger B (2006a) A new kinetic model for water sorption isotherms of cellulosic materials. Macromol Symp 244:89–96. doi:10.1002/masy.200651208
Kohler R, Alex R, Brielmann R, Ausperger B (2006b) A new kinetic model for water sorption isotherms of cellulosic materials. Macromol Symp 244(1):89–96. doi:10.1002/masy.200651208
Kongdee A, Bechtold T, Burtscher E, Scheinecker M (2004) The influence of wet/dry treatment on pore structure-the correlation of pore parameters, water retention and moisture regain values. Carbohydr Polym 57(1):39–44. doi:10.1016/j.carbpol.2004.03.025
Krakhmalev VA, Paiziev AA (2006) Spiral structures of cotton fiber. Cellulose 13(1):45–52. doi:10.1007/s10570-005-9023-2
Lord E, Heap SA (1988) The origin and assessment of cotton fibre maturity. Internatinal Institute for Cotton, Technical Research Division, Manchester
Lu Y, Pignatello JJ (2002) Demonstration of the ‘conditioning effect’ in soil organic matter in support of a pore deformation mechanism for sorption hysteresis. Environ Sci Technol 36(21):4553–4561. doi:10.1021/es020554x
Lu Y, Pignatello JJ (2004) History-dependent sorption in humic acids and a lignite in the context of a polymer model for natural organic matter. Environ Sci Technol 38(22):5853–5862. doi:10.1021/es049774w
Markova N, Sparr E, Wadsö L (2001) On application of an isothermal sorption microcalorimeter. Thermochim Acta 374(2):93–104. doi:10.1016/S0040-6031(01)00476-2
Mihranyan A, Llagostera AP, Karmhag R, Strømme M, Ragnar E (2004) Moisture sorption by cellulose powders of varying crystallinity. Int J Pharm 269(2):433–442. doi:10.1016/j.ijpharm.2003.09.030
Morais Teixeira E, Corrêa AC, Manzoli A, Leite FL, Oliveira CR, Mattoso LHC (2010) Cellulose nanofibers from white and naturally colored cotton fibers. Cellulose 17(3):595–606. doi:10.1007/s10570-010-9403-0
Okubayashi S, Griesser UJ, Bechtold T (2004) A kinetic study of moisture sorption and desorption on lyocell fibers. Carbohydr Polym 58(3):293–299. doi:10.1016/j.carbpol.2004.07.004
Pan Z, Sun D, Sun J, Zhou Z, Jia Y, Pang B, Ma Z, Du X (2010) Effects of fiber wax and cellulose content on colored cotton fiber quality. Euphytica 173(2):141–149
Parmar MS, Chakraborty M (2001) Thermal and burning behavior of naturally colored cotton. Text Res J 71(12):1099–1102. doi:10.1177/004051750107101211
Paudel DR, Hequet EF, Abidi N (2013) Evaluation of cotton fiber maturity measurements. Ind Crop Prod 45:435–441
Rodgers J, Montalvo J, Davidonis G, VonHoven T (2010) Near infrared measurement of cotton fiber micronaire, maturity and fineness—a comparative investigation. Text Res J 80(9):780–793
Sangwichien C, Aranovich GL, Donohue MD (2002) Density functional theory predictions of adsorption isotherms with hysteresis loops. Colloids Surf A Physicochem Eng Asp 206(1–3):313–320. doi:10.1016/S0927-7757(02)00048-1
Siau JF (1983) A proposed theory for nonisothermal unsteady-state transport of moisture in wood. Wood Sci Technol 17:75–77. doi:10.1007/BF00351834
Siroka B, Noisternig M, Griesser UJ, Bechtold T (2008) Characterization of cellulosic fibers and fabrics by sorption/desorption. Carbohydr Res 343(12):2194–2199. doi:10.1016/j.carres.2008.01.037
Skaar C (1972) Water in wood, 1st edn. Syracuse University Press, Syracuse
Taylor JB (1954) Sorption of water by soda boiled cotton at low humidities and some comparison with viscose rayon. J Text Inst 45:642–645
Wangaard FF, Granados LA (1967) The effect of extractives on water-vapor sorption by wood. Wood Sci Technol 1:253–277. doi:10.1007/BF00349758
Watt IC, D’Arcy RL (1976) Hydration of biopolymers. J Polym Sci Polym Symposia 55(1):155–166. doi:10.1002/polc.5070550117
Xie Y, Hill CAS, Xiao Z, Jalaludin Z, Militz H, Mai C (2010a) Water vapor sorption kinetics of wood modified with glutaraldehyde. J Appl Polym Sci 117(3):1674–1682. doi:10.1002/app.32054
Xie Y, Hill CAS, Jalaludin Z, Curling SF, Anandjiwala RD, Norton AJ, Newman G (2010b) The dynamic water vapor sorption behaviour of natural fibres and kinetic analysis using the parallel exponential kinetics model. J Mater Sci 46(2):479–489. doi:10.1007/s10853-010-4935-0
Xie Y, Hill CAS, Jalaludin Z, Sun D (2011) The water vapor sorption behaviour of three celluloses: analysis using parallel exponential kinetics and interpretation using the kelvin-voigt viscoelastic model. Cellulose 18(3):517–530. doi:10.1007/s10570-011-9512-4
Yasuda R, Minato K, Norimoto M (1994) Chemical modification of wood by non-formaldehyde cross-linking reagents. Wood Sci Technol 28:209–218. doi:10.1007/BF00193329
Young JH, Nelson GH (1967) Theory of hysteresis between sorption and desorption isotherms in biological materials. Trans Am Soc Agric Eng 10:260–263
Zaihan J, Hill CAS, Curling S, Hashim WS, Hamdan H (2009) Moisture adsorption isotherms of Acacia Mangium and Endospermum Malaccense using dynamic vapor sorption. J Trop For Sci 21(3):277–285
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This work was supported by the Institute for the Promotion of Innovation by Science and Technology in Flanders (IWT) [project number IWT090505].
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Ceylan, Ö., Goubet, F. & De Clerck, K. Dynamic moisture sorption behavior of cotton fibers with natural brown pigments. Cellulose 21, 1149–1161 (2014). https://doi.org/10.1007/s10570-014-0206-6
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DOI: https://doi.org/10.1007/s10570-014-0206-6