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Effect of Calcination Temperature on the Catalytic Performance of γ-Bi2MoO6 in the Oxidative Dehydrogenation of n-Butene to 1,3-Butadiene

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Abstract

γ-Bi2MoO6 catalysts prepared by a co-precipitation method were calcined at various temperatures (425–675 °C), and were applied to the oxidative dehydrogenation of n-butene to 1,3-butadiene in a continuous flow fixed-bed reactor. Conversion of n-butene and yield for 1,3-butadiene were high at low calcination temperature (425–475 °C), but were decreased with increasing calcination temperature (525–675 °C). Temperature-programmed reoxidation (TPRO) measurements revealed that the catalytic performance of γ-Bi2MoO6 was well correlated with the oxygen mobility of the catalyst. Yield for 1,3-butadiene was increased with increasing oxygen mobility of γ-Bi2MoO6 catalyst. Among the catalysts tested, γ-Bi2MoO6 catalyst calcined at 475 °C showed the best catalytic performance due to its facile oxygen mobility.

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Acknowledgements

This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST) (No. 2009-0078115).

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul, 151-744, South Korea

    Ji Chul Jung, Howon Lee, Dong Ryul Park, Jeong Gil Seo & In Kyu Song

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  1. Ji Chul Jung
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  2. Howon Lee
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  3. Dong Ryul Park
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  5. In Kyu Song
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Correspondence to In Kyu Song.

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Jung, J.C., Lee, H., Park, D.R. et al. Effect of Calcination Temperature on the Catalytic Performance of γ-Bi2MoO6 in the Oxidative Dehydrogenation of n-Butene to 1,3-Butadiene. Catal Lett 131, 401–405 (2009). https://doi.org/10.1007/s10562-009-0091-z

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