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Effect of reaction conditions on the catalytic performance of Co9Fe3Bi1Mo12O51 in the oxidative dehydrogenation of n-butene to 1,3-butadiene

  • Catalysis, Reaction Engineering, Industrial Chemistry
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Abstract

Oxidative dehydrogenation of n-butene to 1,3-butadiene over Co9Fe3Bi1Mo12O51 catalyst was conducted in a continuous flow fixed-bed reactor. The effect of reaction conditions (steam/n-butene ratio, reaction temperature, and space velocity) on the catalytic performance of Co9Fe3Bi1Mo12O51 was investigated. Steam played an important role in decreasing contact time, suppressing total oxidation of n-butene, and removing coke during the reaction. Yield for 1,3-butadiene showed a volcano-shaped curve with respect to steam/n-butene ratio. The compensation between thermodynamic effect and kinetic effect led to a volcano-shaped curve of 1,3-butadiene yield with respect to reaction temperature. The Co9Fe3Bi1Mo12O51 catalyst showed the best catalytic performance at a certain value of space velocity. The optimum steam/n-butene ratio, reaction temperature, and gas hourly space velocity were found to be 15, 420 °C, and 675 h−1, respectively.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Gwanak-gu, Seoul, 151-744, Korea

    Ji Chul Jung, Howon Lee, Sunyoung Park & In Kyu Song

  2. SK Energy Corporation, Yuseong-gu, Daejeon, 305-712, Korea

    Young-Min Chung, Tae Jin Kim, Seong Jun Lee, Seung-Hoon Oh & Yong Seung Kim

Authors
  1. Ji Chul Jung
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  2. Howon Lee
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  3. Sunyoung Park
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  4. Young-Min Chung
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  5. Tae Jin Kim
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  6. Seong Jun Lee
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  7. Seung-Hoon Oh
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  8. Yong Seung Kim
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  9. In Kyu Song
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Correspondence to In Kyu Song.

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Jung, J.C., Lee, H., Park, S. et al. Effect of reaction conditions on the catalytic performance of Co9Fe3Bi1Mo12O51 in the oxidative dehydrogenation of n-butene to 1,3-butadiene. Korean J. Chem. Eng. 25, 1316–1321 (2008). https://doi.org/10.1007/s11814-008-0215-y

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  • DOI: https://doi.org/10.1007/s11814-008-0215-y

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