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RETRACTED ARTICLE: Effect of the support on the mechanism of partial oxidation of methane on platinum catalysts

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This article was retracted on 31 July 2020

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The partial oxidation of methane was studied on Pt/Al2O3, Pt/ZrO2, Pt/CeO2 and Pt/Y2O3 catalysts. For Pt/Al2O3, Pt/ZrO2 and Pt/CeO2, temperature programmed surface reaction (TPSR) studies showed partial oxidation of methane comprehends two steps: combustion of methane followed by CO2, and steam reforming of unreacted methane, while for Pt/Y2O3 a direct mechanism was observed. Oxygen Storage Capacity (OSC) evaluated the reducibility and oxygen transfer capacity of the catalysts. Pt/CeO2 catalyst showed the highest stability on partial oxidation. The results were explained by the higher reducibility and oxygen storage/release capacity which allowed a continuous removal of carbonaceous deposits from the active sites, favoring the stability of the catalyst, For Pt/Al2O3 and Pt/ZrO2 catalysts the increase of carbon deposits around or near the metal particle inhibits the CO2 dissociation on CO2 reforming of methane. Pt/Y2O3 was active and stable for partial oxidation of methane, and its behavior was explained by a change in the reaction mechanism.

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Change history

  • 31 July 2020

    The Publisher has retracted this article by Passos et al. [1]. Owing to a technical error Passos et al. (2006) [2] was republished in the same journal creating a duplicate publication [1]. The Publisher apologises to the authors and to readers for this error. All authors agree with this retraction.

References

  1. J.H. Lunsford (2000) Catal. Today 63 165 Occurrence Handle1:CAS:528:DC%2BD3cXotlKnur4%3D Occurrence Handle10.1016/S0920-5861(00)00456-9

    Article  CAS  Google Scholar 

  2. J.R. Rostrup-Nielsen J. Sehested (2002) Adv. Catal. 47 65 Occurrence Handle1:CAS:528:DC%2BD3sXhtVyhtb4%3D

    CAS  Google Scholar 

  3. S. Freni G. Calogero S. Cavallaro (2000) J. Power Sources 87 28 Occurrence Handle1:CAS:528:DC%2BD3cXitFyqtbo%3D Occurrence Handle10.1016/S0378-7753(99)00357-2

    Article  CAS  Google Scholar 

  4. P.D.F. Vernon M.L.H. Green A.K. Cheetham A.T. Ashcroft (1990) Catal. Lett. 6 181 Occurrence Handle1:CAS:528:DyaK3MXktlWmsLw%3D Occurrence Handle10.1007/BF00774718

    Article  CAS  Google Scholar 

  5. P.M. Torniainen X. Chu L.D. Schmidt (1994) J.Catal. 146 1 Occurrence Handle1:CAS:528:DyaK2cXit1ajs7g%3D Occurrence Handle10.1016/0021-9517(94)90002-7

    Article  CAS  Google Scholar 

  6. Y. Boucouvalas Z. Zhang X.E. Verykios (1996) Catal. Lett. 40 189 Occurrence Handle1:CAS:528:DyaK28Xlt1KgtrY%3D Occurrence Handle10.1007/BF00815281

    Article  CAS  Google Scholar 

  7. A.A. Lemonidou A.E. Stambouli G.J. Tjatjopoulos I.A. Vasalos (1997) Catal. Lett. 43 235 Occurrence Handle1:CAS:528:DyaK2sXht1Cktro%3D Occurrence Handle10.1023/A:1018975630498

    Article  CAS  Google Scholar 

  8. A.G. Steghuis J.G. Ommen ParticleVan J.A. Lercher (1998) Catal. Today 46 91 Occurrence Handle1:CAS:528:DyaK1cXmvVyrsbw%3D Occurrence Handle10.1016/S0920-5861(98)00330-7

    Article  CAS  Google Scholar 

  9. L.V. Mattos E.R. Oliveira Particlede P.D. Resende F.B. Noronha F.B. Passos (2002) Catal. Today 77 245 Occurrence Handle1:CAS:528:DC%2BD38Xpt1eqt7c%3D Occurrence Handle10.1016/S0920-5861(02)00250-X

    Article  CAS  Google Scholar 

  10. L.V. Mattos E. Rodino D.E. Resasco F.B. Passos F.B. Noronha (2003) Fuel Process. Technol. 1677 1

    Google Scholar 

  11. C.E. Hori H. Permana K.Y.S. Ng A. Brenner K. More K.M. Rahmoeller D. Belton (1998) Appl. Catal. Envir. B. 16 105 Occurrence Handle1:CAS:528:DyaK1cXhvVyhur0%3D Occurrence Handle10.1016/S0926-3373(97)00060-X

    Article  CAS  Google Scholar 

  12. F.B. Passos M. Schmal R. Frety (1992) Catal. Lett. 14 57 Occurrence Handle1:CAS:528:DyaK38Xltlymtrc%3D Occurrence Handle10.1007/BF00764219

    Article  CAS  Google Scholar 

  13. E. Rogemond N. Essayem R. Frety V. Perrichon M. Primet F. Mathis (1997) J. Catal. 166 229 Occurrence Handle1:CAS:528:DyaK2sXhs1Gntrg%3D Occurrence Handle10.1006/jcat.1997.1493

    Article  CAS  Google Scholar 

  14. M. Pettre Ch. Eichner M. Perrin (1946) Trans. Faraday Soc. 43 335 Occurrence Handle10.1039/tf946420335b

    Article  Google Scholar 

  15. D. Dissanayake M.P. Rosynek K.C.C. Kharas J.H. Lunsford (1991) J. Catal. 132 117 Occurrence Handle1:CAS:528:DyaK3MXmtFWmurw%3D Occurrence Handle10.1016/0021-9517(91)90252-Y

    Article  CAS  Google Scholar 

  16. M.E.S. Hegarty A.M. O’Connor J.R.H. Ross (1998) Catal. Today 42 225 Occurrence Handle1:CAS:528:DyaK1cXkt1eltbs%3D Occurrence Handle10.1016/S0920-5861(98)00096-0

    Article  CAS  Google Scholar 

  17. M.M.V.M. Souza M. Schmal (2005) Appl. Catal. A: Gen. 281 19 Occurrence Handle1:CAS:528:DC%2BD2MXhsFSitrs%3D Occurrence Handle10.1016/j.apcata.2004.11.007

    Article  CAS  Google Scholar 

  18. W.J.M. Vermeiren E. Blomsma P.A. Jacobs (1992) Catal. Today 13 421 Occurrence Handle10.1016/0920-5861(92)80168-M

    Article  Google Scholar 

  19. E.P.J. Mallens J.H.B.J. Hoebink C.B. Marin (1995) Catal. Lett. 33 291 Occurrence Handle1:CAS:528:DyaK2MXnt1Grt7s%3D Occurrence Handle10.1007/BF00814232

    Article  CAS  Google Scholar 

  20. Y.H. Hu E. Ruckenstein (1998) J. Phys. Chem. A. 102 10568 Occurrence Handle1:CAS:528:DyaK1cXnsF2ns7c%3D Occurrence Handle10.1021/jp9837535

    Article  CAS  Google Scholar 

  21. W.Z. Wheng M.S. Chen Q.G. Yan T.H. Wu Z.S. Chao Y.Y. Liao H.L. Wan (2000) Catal. Today 63 317 Occurrence Handle10.1016/S0920-5861(00)00475-2

    Article  Google Scholar 

  22. D. Wang O. Dewaele A.M. Groote Particlede G.F. Froment (1996) J.Catal 159 418 Occurrence Handle1:CAS:528:DyaK28XivFCgtLg%3D Occurrence Handle10.1006/jcat.1996.0105

    Article  CAS  Google Scholar 

  23. L.V. Mattos E.R. Oliveira P.D. Resende F.B. Noronha F.B. Passos (2005) Catal. Today 101 23 Occurrence Handle10.1016/j.cattod.2004.12.006

    Article  Google Scholar 

  24. E. Ruckenstein H. Wang (2000) J. Catal. 190 32 Occurrence Handle1:CAS:528:DC%2BD3cXnsVertA%3D%3D Occurrence Handle10.1006/jcat.1999.2736

    Article  CAS  Google Scholar 

  25. H. Nishimoto K. Nakagawa N. Ikenaga T. Suzuki (2002) Catal. Lett. 82 161 Occurrence Handle1:CAS:528:DC%2BD38Xns1Cmtbk%3D Occurrence Handle10.1023/A:1020554309639

    Article  CAS  Google Scholar 

  26. J. Wei E.J. Iglesia (2004) J. Phys. Chem. B 108 4094 Occurrence Handle1:CAS:528:DC%2BD2cXhvFWiur4%3D Occurrence Handle10.1021/jp036985z

    Article  CAS  Google Scholar 

  27. M.H. Yao R.J. Baird F.W. Kunz T.E. Hoost (1997) J. Catal. 166 67 Occurrence Handle1:CAS:528:DyaK2sXhtVKgsrk%3D Occurrence Handle10.1006/jcat.1997.1504

    Article  CAS  Google Scholar 

  28. J. Kaspar P. Fornasiero M. Graziani (1999) Catal. Today 50 285 Occurrence Handle1:CAS:528:DyaK1MXitVKgu7s%3D Occurrence Handle10.1016/S0920-5861(98)00510-0

    Article  CAS  Google Scholar 

  29. D.L. Trimm (1999) Catal. Today 49 3 Occurrence Handle1:CAS:528:DyaK1MXps1Khsw%3D%3D Occurrence Handle10.1016/S0920-5861(98)00401-5

    Article  CAS  Google Scholar 

  30. J.R. Rostrup- Nielsen I. Alstrup (1999) Catal. Today 53 311 Occurrence Handle1:CAS:528:DyaK1MXnsFeqsLs%3D Occurrence Handle10.1016/S0920-5861(99)00125-X

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Universidade Federal Fluminense, Rua Passo da Pátria, CEP 24210-240, 156, Niterói, RJ, Brazil

    Fabio B. Passos & Elaine R. Oliveira

  2. Instituto Nacional de Tecnologia, Av. Venezuela, CEP 20081-312, 82, Rio de Janeiro, RJ, Brazil

    Lisiane V. Mattos & Fabio B. Noronhe

Authors
  1. Fabio B. Passos
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  2. Elaine R. Oliveira
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  3. Lisiane V. Mattos
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  4. Fabio B. Noronhe
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Correspondence to Fabio B. Passos.

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Passos, F.B., Oliveira, E.R., Mattos, L.V. et al. RETRACTED ARTICLE: Effect of the support on the mechanism of partial oxidation of methane on platinum catalysts. Catal Lett 110, 261–267 (2006). https://doi.org/10.1007/s10562-006-0119-6

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  • DOI: https://doi.org/10.1007/s10562-006-0119-6

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