Skip to main content
SpringerLink
Log in

Synthesis and characterization of polyamides derived from (4-(4-(2, 6-diphenylpyridin-4yl)phenoxy)phenyl)-3, 5-diaminobezamide

  • Published:
Chinese Journal of Polymer Science Aims and scope Submit manuscript

Abstract

New types of polyamides containing pendent triaryl pyridine groups were successfully synthesized by direct polycondensation of a symmetry diamine, (4-(4-(2,6-diphenylpyridin-4yl)phenoxy)phenyl)-3,5-diaminobezamide (DPDAB), and various aromatic and aliphatic dicarboxylic diacids in NMP using triphenyl phosphate (TPP) and pyridine as catalyst. The diamine and all the prepared polyamides were fully characterized by using FT-IR, 1H-NMR, UV-Vis spectroscopy, fluorimetry and elemental analysis. The inherent viscosity of polyamides ranged from 0.45 dL/g to 0.68 dL/g. All the polymers exhibited solubility in common polar aprotic solvents such as NMP, DMAc, DMF, DMSO, pyridine, HMPA, and even in less polar solvents such as THF and m-cresol at room temperature. Thermal properties of polyamides were evaluated by means of DSC, DMTA and TGA. These polymers showed glass transition temperatures (Tg) in the range of 138–210°C. Their initial decomposition temperature (Ti) varied from 265°C to 310°C under N2. The dilute solution (0.2 g/dL) of polyamides in DMF exhibited fluorescence emission with λmax in the range of 470–550 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yang, H.H., “Aromatic high-strength fibers”, Wiley, New York, 1989, p. 10

    Google Scholar 

  2. Cassidy, P.E., “Thermally stable polymers”, Marcel Dekker, New York Inc, 1980, p. 27

  3. Frazer, A.H., “High temperature resistant polymers”, Wiley, New York, 1968, p. 17

    Google Scholar 

  4. Culbertson, B.M. and Pittman, C.U., “New Monomers and Polymers”, Plenum Press, New York, 1984, p. 22

    Book  Google Scholar 

  5. Patil, P.S., Pal, R.R., Salunkhe, M.M., Maldar, N.N. and Wadgaonkar, P.P., Eur. Polym. J., 2007, 43: 5047

    Article  CAS  Google Scholar 

  6. Shao, Y., Li, Y., Zhao, X., Ma, T., Gong C. and Yang, F., Eur. Polym. J. 2007, 43: 4389

    Article  CAS  Google Scholar 

  7. Liaw, D.J., Wang, K.L., Pundlik Pujari, S., Huang, Y.C., Tao, B.C., Chen, M.H., Lee, K.R. and Lai, J.Y., Dyes Pigments, 2009, 82: 109

    Article  CAS  Google Scholar 

  8. Ghaemy, M. and Alizadeh, R., Eur. Polym. J., 2009, 45: 1681

    Article  CAS  Google Scholar 

  9. Ebadi, H. and Mehdipour-Ataei, S., Chinese J. Polym. Sci., 2010, 28(1): 29

    Article  CAS  Google Scholar 

  10. Imai, Y., Malder, N.N. and Kakimoto, M., J. Polym. Sci. Part A: 1984, 22: 2189

    CAS  Google Scholar 

  11. Bruma, M., Mercer, F., Fitch, J. and Cassidy, P., J. Appl. Polym. Sci., 1995, 56: 527

    Article  CAS  Google Scholar 

  12. Eastmond, G.C., Gibas, M. and Paprotny, J., Eur. Polym. J., 1999, 35: 2097

    Article  CAS  Google Scholar 

  13. Hsiao, S.H. and Dai, L.R., J. Polym. Sci. Part A: 1999, 37: 665

    Article  CAS  Google Scholar 

  14. Faghihi, K., Shabanian, M. and Izadkhah, A., Chinese J. Polym. Sci., 2010, 28(4): 589

    Article  CAS  Google Scholar 

  15. Mallakpour, S. and Khani, M., Chinese J. Polym. Sci., 2010, 28(6): 859

    Article  CAS  Google Scholar 

  16. Mallakpour, S., and Dinari, M., Chinese J. Polym. Sci., 2010, 28(5): 685

    Article  CAS  Google Scholar 

  17. Kusama, M., Mastsumoto, T. and Kurosaki, T., Macromolecules, 1994, 27: 1117

    Article  CAS  Google Scholar 

  18. Liaw, D.J., Chen, W.H., Hu, C.K., Lee, K.R. and Lai, J.Y., Polymer, 2007, 48: 6571

    Article  CAS  Google Scholar 

  19. Liou, G.S., Fang, Y.K. and Yen, H.J., J. Polym. Res., 2007, 14: 147

    Article  CAS  Google Scholar 

  20. Ghaemy, M. and Barghamadi, M., J. Appl. Polym. Sci., 2009, 114: 3464

    Article  CAS  Google Scholar 

  21. Li, F., Fang, S, Ge, J.J., Honigfort, P.S., Chen, J.C., Harris, F.W. and Cheng, S.Z.D., Polymer, 1999, 40: 4571

    Article  CAS  Google Scholar 

  22. Liaw, D.J., Chang, F.C., Leung, M.K., Chou, M.Y. and Muellen, K., Macromolecules, 2005, 38: 4024

    Article  CAS  Google Scholar 

  23. Mallakpour, S. and Kolahdoozan, M., React. Funct Polymers, 2008, 68: 91

    Article  CAS  Google Scholar 

  24. Liaw, D.J. and Liaw, B.Y., Polymer, 2001, 42: 839

    Article  CAS  Google Scholar 

  25. Ghaemy, M. and Barghamadi, M., J. Appl. Polym. Sci., 2009, 111: 1588

    Article  CAS  Google Scholar 

  26. Myung, B.Y., Ahn, C.J. and Yoon, T.H., Polymer, 2004, 45: 3185

    Article  CAS  Google Scholar 

  27. Yamazaki, N., Matsumoto, M. and Higashi, F., J. Polym. Sci. Part A, 1975, 13: 1373

    CAS  Google Scholar 

  28. Ghaemy, M. and Alizadeh, R., Eur. Polym. J., 2009, 45: 3108

    Article  CAS  Google Scholar 

  29. Ghaemy, M., Behmadi, H. and Alizadeh, R., Chinese Chem. Lett., 2009, 20: 961

    Article  CAS  Google Scholar 

  30. Mighani, H. and Ghaemy, M., Chinese J. Polym. Sci., 2010, 28(2): 147

    Article  CAS  Google Scholar 

  31. Liaw, D.J., Liaw, B.Y. and Jeng, M.Q., Polymer, 1998, 39: 1597

    Article  CAS  Google Scholar 

  32. Mallakpour, S. and Taghavi, M., Polymer, 2008, 49: 3239

    Article  CAS  Google Scholar 

  33. Yagci, H. and Mathias, L.J., Polymer, 1998, 39: 3779

    Article  CAS  Google Scholar 

  34. San-José, N., Gómez-Valdemoro, A., Estevez, P., García, F.C., Serna, F. and José Miguel García J. M. Eur. Polym. J., 2008, 44: 3578

    Article  Google Scholar 

  35. Liou, G.S. and Chang, C.W., Macromolecules, 2008, 41: 1667

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

    Mousa Ghaemy & Soheila Khajeh

Authors
  1. Mousa Ghaemy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Soheila Khajeh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mousa Ghaemy.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ghaemy, M., Khajeh, S. Synthesis and characterization of polyamides derived from (4-(4-(2, 6-diphenylpyridin-4yl)phenoxy)phenyl)-3, 5-diaminobezamide. Chin J Polym Sci 30, 82–92 (2012). https://doi.org/10.1007/s10118-012-1105-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10118-012-1105-7

Keywords

Search

Navigation