Skip to main content

Advertisement

SpringerLink
Log in

Thermally stable and organo-soluble polyamides containing triazine rings and ether linkages in the main chain: Synthesis and characterization

  • Papers
  • Published:
Chinese Journal of Polymer Science Aims and scope Submit manuscript

Abstract

In order to synthesize new polyamide (PA) 5 and copolyamides (CoPA) 7a-7d, a new-type of dicarboxylic acid containing triazine ring was successfully synthesized from 2,4-dichloro-6-methoxy-s-triazine 1 and 4-aminobenzoic acid. New polyamide 5 containing triazine moiety was prepared from 4,4′-(6-methoxy-1,3,5-triazine-2,4-diyl)bis(azanediyl)dibenzoic acid 3 and 4,4′-diaminodiphenylether by direct polycondensation reaction. Then new series thermally stable copolyamides 7a-7d with high solubility in common organic solvents were synthesized from the direct polycondensation reaction of diacid 3 as a first monomer, aliphatic-aromatic diacids 6a-6d as second diacids and 4,4′-diaminodiphenylether. All of the above polymers were fully characterized by 1H-NMR and FTIR spectroscopy, elemental analysis (CHN), inherent viscosity, solubility tests, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The resulted CoPAs 7a-7d have shown good inherent viscosities, solubility and thermal properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lin, J. and Sherrington, D.C., Adv. Polym. Sci., 1994, 111: 177

    Article  CAS  Google Scholar 

  2. Faghihi, K. and Hajibeygi, M., J. Appl. Polym. Sci., 2004, 92: 3447

    Article  CAS  Google Scholar 

  3. Gutch, P.K., Banerjee, S. and Jaiswal, D.K., J. Appl. Polym. Sci., 2003, 89: 691

    Article  CAS  Google Scholar 

  4. Hale, W.F., Farnham, A.G., Johnson, R.N. and Clendinning, R.A., J. Polym. Sci., Part A: Polym. Chem., 1967, 5: 2399

    Article  CAS  Google Scholar 

  5. Johnson, R.N., Farnham, A.G., Clendinning, R.A., Hale, W.F. and Merriman, C.N., J. Polym. Sci., Part A: Polym. Chem., 1967, 5: 2375

    Article  CAS  Google Scholar 

  6. Hajibeygi, M., Shabanian, M. and Khodaei-Tehrani, M., Des. Monomers Polym., 2011, 14: 617

    CAS  Google Scholar 

  7. Faghihi, K., Nourbakhsh, M. and Hajibeygi, M., Chinese J. Polym. Sci., 2010, 28(6): 941

    Article  CAS  Google Scholar 

  8. Hajibeygi, M., Faghihi, K. and Shabanian, M., J. Appl. Polym. Sci., 2011, 121: 2877

    Article  CAS  Google Scholar 

  9. Faghihi, K., Hajibeygi, M. and Shabanian, M., Polym. Int., 2010, 59: 218

    CAS  Google Scholar 

  10. Faghihi, K. and Hajibeygi, M., Chinese J. Polym. Sci., 2010, 28(4): 517

    Article  CAS  Google Scholar 

  11. Faghihi, K., Shabanian, M., Hajibeygi, M. and Mohammadi, Y., Polym. Sci. Seri B, 2010, 52: 549

    Article  Google Scholar 

  12. Morgan, P.W., Macromolecules, 1970, 3: 536

    Article  CAS  Google Scholar 

  13. Grave, R.B., High performance polymers: their origin and development. New York: Elsevier Science Publishing Co Inc, 1986

    Google Scholar 

  14. Hedrick, J.L. and Twieg, R., Polymer, 1997, 38: 995

    Article  CAS  Google Scholar 

  15. Carter, K.R., Miller, R.D. and Hedrick, J.L., Macromolecules, 1993, 26: 2209

    Article  CAS  Google Scholar 

  16. Verborgt, J. and Marvel, C.S., J. Polym. Sci: Polym. Chem. Ed., 1973, 11: 261

    CAS  Google Scholar 

  17. Anderson, D.R. and John, M.H., J. Polym. Sci., Part A: Polym. Chem., 1966, 4: 1689

    Article  CAS  Google Scholar 

  18. Yu, G., Liu, C., Wang, J., Gu, T. and Jian, X., Polym. Degrad. Stab., 2009, 94: 1053

    Article  CAS  Google Scholar 

  19. Bhimrao, D.S. and Sudhakar, S.M., J. Polym. Sci., Part A: Polym. Chem., 1991, 29: 825

    Google Scholar 

  20. Sagar, A.D., Salunkhe, M.M., Wadgaonkar, P.P., Sarawade, B.D. and Mahajan, S.S., J. Polym. Sci., Part A: Polym. Chem., 1997, 35: 1077

    Article  CAS  Google Scholar 

  21. Yamazaki, N., Matsumoto, M. and Higashi, F., J. Polym. Sci., Part A: Polym. Chem., 1975, 13: 1373

    CAS  Google Scholar 

  22. Shabanian, M. and Basaki, N., Composites: Part B, 2013, 52: 224

    Article  CAS  Google Scholar 

  23. Hajibeygi, M. and Shabanian, M., J. Appl. Polym. Sci., 2012, 126: 280

    Article  CAS  Google Scholar 

  24. Hajibeygi, M. and Shabanian, M., Des. Monomers Polym., 2013, 16: 222

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Kharazmi University, 15719-14911, Tehran, Iran

    Mohsen Hajibeygi

  2. Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran

    Khalil Faghihi & Zeinab Mirzakhanian

  3. Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran

    Majid Khodaei-Tehrani

Authors
  1. Mohsen Hajibeygi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Khalil Faghihi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Majid Khodaei-Tehrani
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zeinab Mirzakhanian
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohsen Hajibeygi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hajibeygi, M., Faghihi, K., Khodaei-Tehrani, M. et al. Thermally stable and organo-soluble polyamides containing triazine rings and ether linkages in the main chain: Synthesis and characterization. Chin J Polym Sci 33, 109–117 (2015). https://doi.org/10.1007/s10118-015-1562-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10118-015-1562-x

Keywords

Search

Navigation