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Synthesis and characterization of organosoluble polyamides from quinoxaline based diamine

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Abstract

Aromatic/aliphatic polyamides were synthesized from a diamine monomer, 2,3-bis-p-aminophenylquinoxaline (IV), based on quinoxaline and various dicarboxylic acids of aliphatic, aromatic and heterocyclic. The diamine and polyamides were characterized by elemental analysis, FTIR and 1H-NMR. The solubility of the polyamides was affected by the quinoxaline and heterocyclic groups in the polymer chain. They were all soluble in common organic solvents such as dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF) and N-methylpyrolidone (NMP). The polyamides showed inherent viscosity in the range of 0.25–0.3 dL/g in DMSO at 25°C and good thermal stability with the char yields in the range of 65%–82% at 600°C in nitrogen.

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Authors and Affiliations

  1. Department of Chemistry, University of Golestan, Gorgan, P.O. Box 155, Iran

    Hossein Mighani

  2. Department of Chemistry, University of Mazandaran, Babolsar, P.O. Box 453, Iran

    Hossein Mighani & Mousa Ghaemy

Authors
  1. Hossein Mighani
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  2. Mousa Ghaemy
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Correspondence to Hossein Mighani.

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Mighani, H., Ghaemy, M. Synthesis and characterization of organosoluble polyamides from quinoxaline based diamine. Chin J Polym Sci 28, 147–155 (2010). https://doi.org/10.1007/s10118-010-8231-x

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  • DOI: https://doi.org/10.1007/s10118-010-8231-x

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