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An Efficient Route to Phenylselenoethers in the Presence of Ag2O

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Summary.

An efficient protocol for the preparation of phenylselenoethers from unsaturated alcohols using phenylselenenyl halides at room temperature was developed. The procedure employs phenylselenenyl chloride and bromide, some Δ 4- and Δ 5-alkenols and Ag2O, as an additive, to generate the tetrahydropyrans or tetrahydrofurans. This method permits the preparation of cyclic phenylselenoethers in high yields and under extremely mild conditions.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kragujevac, Kragujevac, Serbia

    Zorica M. Bugarčić, Vera M. Divac & Mariana P. Gavrilović

Authors
  1. Zorica M. Bugarčić
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  2. Vera M. Divac
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  3. Mariana P. Gavrilović
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Correspondence to Zorica M. Bugarčić.

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Bugarčić, Z., Divac, V. & Gavrilović, M. An Efficient Route to Phenylselenoethers in the Presence of Ag2O. Monatsh. Chem. 138, 985–988 (2007). https://doi.org/10.1007/s00706-007-0661-y

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  • DOI: https://doi.org/10.1007/s00706-007-0661-y

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