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A Facile, Mild, and Environmentally Benign Procedure for the Cleavage of Carbon–Nitrogen Double Bonds Using KMnO4 in the Presence of Montmorillonite K-10 Under Solvent-Free Conditions

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Summary.

An efficient and environmentally benign method for the conversion of oximes, semicarbazones, phenylhydrazones, and azines to their corresponding carbonyl compounds using KMnO4/montmorillonite K-10 as a commercially available, non-toxic, stable, and inexpensive reagent is reported.

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Authors and Affiliations

  1. Department of Chemistry, Isfahan University, Isfahan 81746-73441, Iran, , , , , , IR

    Iraj Mohammadpoor-Baltork

  2. Department of Chemistry, Razi University, Kermanshah 67149, Iran, , , , , , IR

    Mohammad mehdi Khodaei & Esmaeil Aslani

  3. College of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran, , , , , , IR

    Abdol R. Hajipour

Authors
  1. Iraj Mohammadpoor-Baltork
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  2. Mohammad mehdi Khodaei
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  3. Abdol R. Hajipour
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  4. Esmaeil Aslani
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Additional information

Corresponding author. E-mail: Imbaltork@sci.ui.ac.ir

Received August 23, 2002; accepted March 23, 2002

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Mohammadpoor-Baltork, I., Khodaei, M., Hajipour, A. et al. A Facile, Mild, and Environmentally Benign Procedure for the Cleavage of Carbon–Nitrogen Double Bonds Using KMnO4 in the Presence of Montmorillonite K-10 Under Solvent-Free Conditions. Monatshefte für Chemie 134, 539–543 (2003). https://doi.org/10.1007/s00706-002-0556-x

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  • DOI: https://doi.org/10.1007/s00706-002-0556-x

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