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Development Trends in Selective Hydrogenation Upgrading of 5-Hydroxymethylfurfural Catalyzed by Heterogeneous Metal Catalysts

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Abstract

5-Hydroxymethylfurfural (HMF) is a crucial platform molecule derived from biomass, with the potential for conversion into a wide array of products, intermediates, or monomers through various transformations including hydrogenation, oxidation, reductive amination, etherification, and decarbonylation due to its diverse functional groups (hydroxy, aldehyde, furan ring). Particularly, diverse products can be derived from the hydrogenation of C=O, C=C, and C–OH, posing a significant challenge in developing active and highly selective catalysts. This minireview addresses recent developments in heterogeneous catalysts and their application to HMF hydrogenation. Emphasis is placed on hydrogenation pathways and the construction of catalytic systems. The aim is to provide researchers with a comprehensive understanding of hydrogenation, hydrogenolysis, and dehydrogenation reactions applicable to biomass conversion. Additionally, current challenges and future opportunities are outlined to guide further studies towards more efficient and scalable processes.

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Fig. 1

Reproduced with permission from Ref. [42]. Copyright 2023, Elsevier

Fig. 2

Reproduced with permission from Ref. [20]. Copyright 2023, American Chemical Society

Fig. 3

Reproduced with permission from Ref. [29]. Copyright 2021, American Chemical Society

Fig. 4

Reproduced with permission from Ref. [25]. Copyright 2021, American Chemical Society

Fig. 5

Reproduced with permission from Ref. [30]. Copyright 2021, American Chemical Society

Fig. 6

Reproduced with permission from Ref. [44]. Copyright 2021, Nature

Fig. 7

Adapted with permission from Ref. [56]. Copyright 2014, Wiley–VCH

Fig. 8

Adapted with permission from Ref. [57]. Copyright 2011, Wiley–VCH

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Data availability

The primary data that support the plots within this paper and other finding of this study are available from the corresponding author on reasonable request.

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Acknowledgements

This work was financial supported by the Science, Education and Industry Integration of Basic Research Projects of Qilu University of Technology (Shandong Academy of Sciences) (Grant No. 2023PX015), Talent research projects of Qilu University of Technology (Shandong Academy of Sciences) (Grant No. 2023RCKY094).

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  1. Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-Scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, People’s Republic of China

    Shulin Liu & Guowei Zhou

  2. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China

    Huizhen Liu & Buxing Han

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Liu, S., Zhou, G., Liu, H. et al. Development Trends in Selective Hydrogenation Upgrading of 5-Hydroxymethylfurfural Catalyzed by Heterogeneous Metal Catalysts. Top Catal (2024). https://doi.org/10.1007/s11244-024-01951-7

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