Abstract
The thermal and optical properties in the formation of gold nanoshells on SiO2 were studied by thermal lens (TL) and absorption spectroscopy. The formation of SiO2@Au particles was realized in four stages: First, SiO2 spheres were synthesized using the Stöber method. Later the attachment of amino groups and the adsorption of hydroxide gold nanoparticles on surface of silicon dioxide were realized. Finally, the growth of gold shell was obtained. The UV–Vis spectrum of SiO2@Au nanostructures showed an absorption band in the near-infrared region around of 740 nm associated with the presence of a gold shell on the dielectric platform. Transmission electron microscopy and scanning electron microscopy confirmed the formation of well-defined gold nanoshell on SiO2 spheres. Silicon dioxide nanospheres with an average size of 293 nm and Au-nanoshell with thicknesses of ~ 14 nm were obtained. The high crystalline quality of Au-nanoshell was demonstrated by X-ray diffraction. The thermal diffusivity during the different steps of formation of the gold nanoshell was studied using absorption spectroscopy and the mode-mismatched TL. A redshift of absorption band optic was observed by UV–Vis, and a very significant increase in the thermal diffusivity as the Au shell was completed.
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S.J. Oldenburg, R.D. Averitt, S.L. Westcott, N.J. Halas, Nanoengineering of optical resonances. Chem. Phys. Lett. 288, 243–247 (1998). https://doi.org/10.1016/S0009-2614(98)00277-2
R. Weissleder, A clearer vision for in vivo imaging. Nature 19, 316–317 (2001). https://doi.org/10.1038/86684
L. Tang, L. Liu, H.B. Elwing, Complement activation and inflammation triggered by model biomaterial surfaces. J. Biomed. Mater. Res. 41, 333–340 (1998). https://doi.org/10.1002/(SICI)1097-4636(199808)41:2%3c333:AID-JBM19%3e3.0.CO;2-L
T. Ji, V.G. Lirtsman, Y. Avny, D. Davidov, Preparation, characterization, and application of au-shell/polystyrene beads and Au-Shell/magnetic beads. Adv. Mater. 13, 1253–1256 (2001). https://doi.org/10.1002/1521-4095(200108)13:16%3c1253:aid-adma1253%3e3.0.co;2-t
W. Wu, C. Yu, M. Chu, A gold nanoshell with silica inner shell synthesized using liposome templates for doxorubicin loading and near-infrared photothermal therapy. Int. J. Nanomed. 6, 807–813 (2011). https://doi.org/10.2147/IJN.S16701
I. Grabowska-Jadach, D. Kalinowska, M. Drozd, M. Pietrzak, Synthesis, characterization and application of plasmonic hollow gold nanoshells in a photothermal therapy New particles for theranostics. Biomed. Farmacother. 111, 1147–1155 (2019). https://doi.org/10.1016/j.biopha.2019.01.037
K. Wang, Y. Wang, C. Wang, X. Jia, J. Li, R. Xiao, S. Wang, Facile synthesis of high-performance SiO2@Au core–shell nanoparticles with high SERS activity. RSC Adv. 8, 30825–30831 (2018). https://doi.org/10.1039/c8ra05213a
D. Kandpal, S. Kalele, S. Kulkarni, Synthesis and characterization of silica–gold core-shell (SiO2@Au) nanoparticles. Pramana J. Phys. 69, 277–283 (2007). https://doi.org/10.1007/s12043-007-0128-z
J. Choma, A. Dziura, D. Jamiola, P. Nyga, M. Jaroniec, Preparation and properties of silica-gold core-shell particles. Colloids Surf. A 373, 167–171 (2011). https://doi.org/10.1016/j.colsurfa.2010.10.046
J.C.Y. Kah, N. Phonthammachai, R.C.Y. Wang, J. Song, T. White, S. Mhaisalkar, I. Ahmadb, C. Shepparda, M. Olivo, Synthesis of gold nanoshells based on the deposition-precipitation process. Gold Bull. 41, 23–36 (2008). https://doi.org/10.1007/BF03215620
V.A. Khanadeev, B.N. Khlebtsov, N.G. Khlebtsov, Optical properties of gold nanoshells on monodisperse silica cores: experiment and simulations. J. Quant. Spectrosc. Radiat. Transf. 187, 1–9 (2017). https://doi.org/10.1016/j.jqsrt.2016.09.004
M.D. English, E.R. Waclawik, A novel method for the synthesis of monodisperse gold-coated silica nanoparticles. J. Nanopart. Res. 14, 1–10 (2012). https://doi.org/10.1007/s11051-011-0650-2
S. Soltaninejad, M.S. Husin, A.R. Sadrolhosseini, R. Zamiri, A. Zakaria, M.M. Moksin, E. Gharibshahi, Thermal diffusivity measurement of Au nanofluids of very low concentration by using photoflash technique. Measurements 46, 4321–4327 (2013). https://doi.org/10.1016/j.measurement.2013.07.043
A. Netzahual-Lopantzi, J.F. Sánchez-Ramírez, J.L. Jiménez-Pérez, D. Cornejo-Monroy, G. López-Gamboa, Z.N. Correa-Pacheco, Study of the thermal diffusivity of nanofluids containing SiO2 decorated with Au nanoparticles by thermal lens spectroscopy. Appl. Phys. A 125, 588 (2019). https://doi.org/10.1007/s00339-019-2891-3
J.L. Luna-Sánchez, J.L. Jiménez-Pérez, R. Carbajal-Valdez, G. López-Gamboa, M. Perez-Gonzalez, Z.N. Correa-Pacheco, Green synthesis of silver nanoparticles using Jalapeno Chili extract and thermal lens study of acrylic resin nanocomposites. Thermochim. Acta 678, 178314 (2019). https://doi.org/10.1016/j.tca.2019.178314
J. Shen, R. Lowe, R.D. Snook, A model for cw laser induced mode-mismatched dual-beam thermal lens spectrometry. Chem. Phys. 165, 385–396 (1992). https://doi.org/10.1016/0301-0104(92)87053-C
W. Stöber, A. Fink, Controlled Growth of monodisperse Silica Spheres in the Micron Size Range. J. Colloid Interface Sci. 26, 62–69 (1968). https://doi.org/10.1016/0021-9797(68)90272-5
Q. Guo, D. Huang, X. Kou, W. Cao, L. Li, L. Ge, L. Jiangong, Synthesis of disperse amorphous SiO2 nanoparticles via sol-gel. Ceram. Int. 43, 92–196 (2017). https://doi.org/10.1016/j.ceramint.2016.09.133
Y. An, G. Zhu, W. Bi, L. Lu, C. Feng, Z. Xu, W. Zhang, Highly sensitive electrochemical immunoassay integrated with polymeric nanocomposites and enhanced SiO2@Au core-shell nanobioprobes for SirT1 determination. Anal. Chim. Acta 966, 54–61 (2017). https://doi.org/10.1016/j.aca.2017.02.011
L. Sun, L. Jiang, S. Peng, Y. Zheng, X. Sun, H. Su, C. Qi, Preparation of Au catalysis supported on core-shell SiO2/polypyrrole composites with high catalytic performances in the reduction of 4-nitrophenol. Synth. Met. 248, 20–26 (2019). https://doi.org/10.1016/j.synthmet.2018.12.024
R. Zhang, Structural and optical properties of grey and porous SiO2 nanoparticles. Physica B 533, 23–25 (2019). https://doi.org/10.1016/j.physb.2018.10.027
G. Xu, X. Shen, Fabrication of SiO2 nanoparticles incorporated coating onto titanium substrates by the micro arc oxidation to improve the wear resistance. Surf. Coat. Technol. 364, 180–186 (2019). https://doi.org/10.1016/j.surfcoat.2019.01.069
I.A. Rhaman, P. Vejayakumaran, C.S. Sipaut, J. Ismail, M.A. Bakar, R.K.C. Adnan, An optimized sol-gel synthesis of stable primary equivalent silica particles. Colloids Surf. A 294, 102–110 (2007). https://doi.org/10.1016/j.colsurfa.2006.08.001
E. Vega-López, U. Morales-Muñoz, El Proceso Stöber: Principios y Actualidad 1ª Parte 9, 19–30 (2016). http://quimica.ugto.mx/index.php/nyt/article/view/Nyt%209-3
J.L. Jiménez-Pérez, J.F. Sánchez-Ramírez, D. Cornejo-Monroy, R. Gutiérrez-Fuentes, J.A. Pescador-Rojas, A. Cruz-Orea, C. Jacinto, Photothermal study of two different nanofluids containing SiO2 and TiO2 semiconductor nanoparticles. Int. J. Thermophys. 33, 69–79 (2012). https://doi.org/10.1007/s10765-011-1139-z
E. Wondu, Z. Lule, J. Kim, Thermal Conductivity and Mechanical Properties of Thermoplastic Polyurethane-/Silane-Modified Al2O3 Composite Fabricated via Melt Compounding. Polymers 11, 1–12 (2019). https://doi.org/10.3390/polym11071103
D.S. Muratov, D.V. Kuznetsov, I.A. Il’inykh, I.N. Burmistrov, I.N. Mazov, Thermal conductivity of polypropylene composites filled with silane-modified hexagonal BN. Compos. Sci. Technol. 111, 40–43 (2015). https://doi.org/10.1016/j.compscitech.2015.03.003
S. Ivanova, V. Pitchon, C. Petit, H. Herschbach, A.V. Dorsselaer, E. Leize, Preparation of alumina supported gold catalysts: gold complexes genesis, identification and speciation by mass spectrometry. Appl. Catal. A 26, 203–210 (2006). https://doi.org/10.1016/j.apcata.2005.10.018
M. Hari, S.A. Joseph, S. Mathew, B. Nithyaja, V.P.N. Nampoori, P. Radhakrishnan, Thermal diffusivity of nanofluids composed of rod-shaped silver nanoparticles. Int. J. Therm. Sci. 64, 188–194 (2013). https://doi.org/10.1016/j.ijthermalsci.2012.08.011
R. Carbajal-Valdez, A. Rodríguez-Juárez, J.L. Jiménez-Pérez, J.F. Sánchez-Ramírez, A. Cruz-Orea, Z.N. Correa-Pacheco, M. Macías, J.L. Luna-Sánchez, Experimental investigation on thermal properties of Ag nanowire nanofluids at low concentrations. Thermochim. Acta 671, 83–88 (2019). https://doi.org/10.1016/j.tca.2018.11.015
A. Netzahual-Lopantzi, J.F. Sánchez-Ramírez, J.L. Jiménez-Pérez, Comparative study of the thermal diffusivity of SiO2–Au nanoparticles in water base. Appl. Phys. A 126, 588 (2020). https://doi.org/10.1007/s00339-020-3346-6
X. Huang, M.A. El-Sayed, Gold nanoparticles: optical properties and implementations in cancer diagnosis and photothermal therapy. J Adv Res 1, 13–28 (2010). https://doi.org/10.1016/j.jare.2010.02.002
W. Huang, Q. Qian, M.A. El-Sayed, Y. Ding, Z.L. Wang, Effect of the lattice crystallinity on the electron-phonon relaxation rates in gold nanoparticles. J. Phys. Chem. C 111, 10751–10757 (2007). https://doi.org/10.1021/jp0738917
F.M. Ali, W.M. Yunus, Study of the effect of volume fraction concentration and particle materials on thermal conductivity and thermal diffusivity of nanofluids. Jpn. J. Appl. Phys. 50, 085201 (2011). https://doi.org/10.1143/JJAP.50.085201
R. Gutierrez Fuentes, J.A. Pescador Rojas, J.L. Jimenez-Perez, J.L. Sánchez-Ramírez, A. Cruz-Orea, J.G. Mendoza-Alvarez, Study of thermal diffusivity of nanofluids with bimetallic nanoparticles with Au(core)/Ag(shell) structure. Appl. Surf. Sci. 255, 781–783 (2008). https://doi.org/10.1016/j.apsusc.2008.07.023
M. Nikbankht, Radiative heat transfer between core-shell nanoparticles. J. Quant. Spectrosc. Radiat. Transf. 221, 164–171 (2018). https://doi.org/10.1016/j.jqsrt.2018.10.005
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This work was supported by CONACYT (Mexico) under scholarship No. 308327.
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Netzahual-Lopantzi, A., Sánchez-Ramírez, J.F., Saab-Rincón, G. et al. Thermal diffusivity monitoring during the stages of formation of core–shell structures of SiO2@Au. Appl. Phys. A 126, 392 (2020). https://doi.org/10.1007/s00339-020-03586-3
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DOI: https://doi.org/10.1007/s00339-020-03586-3