Abstract
In this study, fluorescent dye benzo 2,1,3 thiadiazole has been dispersed into the pure nematic liquid crystal (NLC) 2020, which is composed of fluorinated 4′-alkylphenyl-4-isothiocyanatotolanes, in three different concentrations. Electro-optical and dielectric parameters have been investigated in the present work. Birefringence has been calculated by transmittance technique for pure and dye-dispersed system, and found to be increased for dispersed system. This is the key finding of the present investigation. In this work, response time has also been calculated by optical switching method and found to be decreased after the dispersion of fluorescent dye into the pure NLC 2020. Contrast ratio has also been measured here and found to be increased for the dispersed system. Relative permittivity has been found to be decreased after the dispersion of dye. Dielectric anisotropy has also been calculated for pure NLC and dye–NLC dispersed system, and found to be decreased for dispersed system. The present investigation may be helpful in the improvement of response time of liquid crystal-based devices.
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R. Muenster, M. Jarasch, X. Zhuang, Y.R. Shen, Dye-induced enhancement of optical nonlinearity in liquids and liquid crystals. Appl. Phys. Lett. 78, 42–46 (1997)
B.Ya.. Zel’dovich, N.F. Pilipetskii, A.V. Sukhov, N.V. Tabiryan, Sov. Phys. JETP Lett. 31, 263 (1980)
S.D. Durbin, S.M. Arakelian, Y.R. Shen, Phys. Rev. Lett. 47, 1411 (1981)
L. Marrucci, Y.R. Shen, in The Optics of Thermotropic Liquid Crystals, ed. by R. Sambles, S. Elston (Taylor & Francis, London, 1998)
A.S. Zolot’ko, V.F. Kitaeva, N. Kroo, N.I. Sobolev, L. Csillag, Sov. Phys. JETP Lett. 32, 158 (1980)
S. Varghese, S. Narayanankutty, C.W.M. Bastiaansen, G.P. Crawford, D.J. Broer, Patterned alignment of liquid crystals by m-rubbing. Adv. Mater. 16, 1600–1605 (2004)
V.A. Konovalov, V.G. Chigrinov, H.S. Kwok, H. Takada, H. Takadsu, Photoaligned vertical aligned nematic mode in liquid crystals. Jpn. J. Appl. Phys. 43, 261–266 (2004)
S.P. Yadav, K.K. Pandey, A.K. Misra, R. Manohar, Electro-optical behaviour of dye doped nematic liquid crystal. Acta Phys. Pol. A 199, 824–829 (2011)
P.G. de Gennes, J. Prost, The Physics of Liquid Crystals (Oxford University Press, UK, 1993)
M. Pande, P.K. Tripathi, A.K. .Misra, S. Manohar, R. Manohar, S. Singh, Dielectric and electro-optical properties of polymer-stabilized liquid crystal system. Appl. Phys. A. 122, 217–226 (2016)
I.C. Khoo, Liquid Crystals: Physical Properties and Nonlinear Optical Phenomena (Wiley, New York, 1995)
P. Klysubun, Nonlinear optical studies of dye-doped nematic liquid crystals. Ph.D. Dissertation, Virginia Polytechnic Institute and State University, Virginia (2002)
S. Yilmaz, A. Bozkurt, Spectroscopic measurement of liquid crystal anisotropy in the ultraviolet/visible region. Mater. Chem. Phys. 107, 410–412 (2008)
L. Marrucci, Y.R. Shen, The Optics of Thermotropic Liquid Crystals, ed. by R. Sambles, S. Elston (Taylor and Francis, London, 1997)
I. J´anossy, L. Csillag, A.D. Lloyd, Temperature dependence of the optical Fréedericksz transition in dyed nematic liquid crystals. Phys. Rev. A 44, 8410–8416 (1991)
I. J´anossy, Molecular interpretation of the absorption-induced optical reorientation of nematic liquid crystals. Phys. Rev. E. 49, 2957–2962 (1994)
S. Marino, M. Castriota, V. Bruno, E. Cazzanelli, G. Strangi, C. Versace, N. Scaramuzza, Changes of the electro-optic response of nematic liquid crystal cells due to inserted titania–vanadia films. Appl. Phys. 97, 013523–013529 (2005)
C. Motoc, G. Iacobescu, Birefringence of azo-dye doped nematic liquid crystals. J. Optoelectron. Adv. Mater. 8, 295–298 (2006)
S. Shoarinejad, M.S. Zakerhamidi, Ordering behavior and linear dichroism of pure and doped liquid crystals. Mol. Cryst. Liq. Cryst. 613, 149–155 (2015)
P. Klysubun, G. Indebetouw, Transient and steady state photorefractive responses in dye doped nematic liquid crystal cells. J. Appl. Phys. 91, 897 (2002)
S. Ghosh, G.O. Carlisle, Carbon nanotube enhanced diffraction efficiency in dye-doped liquid crystal. J. Mat. Sci. Mat. Elect. 16, 753 (2005)
M.T. Sims, R.J. Mandle, J.W. Mandle, J.W. Goodby, M.B. Nielson, Guest–host systems containing anthraquinone dyes with multiple visible transitions giving positive and negative dichroic order parameters: an assessment of principal molecular axes and computational methods. Liq. Cryst. 44, 2029–2045 (2017)
M. Petersen, Jevric, R.J. Mandle, T. Mark, J.N. Sims, S.J. Moore, J.W. Cowling, J.W. Goodby, B. Nielsen, Photoswitching of dihydroazulene derivatives in liquid crystalline host systems. Chem. Eur. J. 23, 5090–5103 (2017)
J. Stephen, C. Cowling, Ellis, J.W. Goodby, Anthraquinone liquid crystal dichroic dyes—a new form of chromonic dye? Liq. Cryst. 38, 1683–1698 (2011)
D.J. Gardiner, H.J. Coles, Organosiloxane liquid crystals for fast-switching bistable scattering devices. J. Phys. D Appl. Phys. 39, 4948–4955 (2006)
R.J. Mandle, E.A. Davis, C.-C.J. Voll, D.J. Lewis, S.J. Cowling, J.W. Goodby. Self-organisation through size-exclusion in soft materials. J. Mater. Chem. C 3, 2380–2388 (2015)
A.K. Misra, P.K. Tripathi, R. Manohar, Fluorescence, UV absorbance and dielectric studies of fluorescent dye doped ferroelectric liquid crystal. J. Non Cryst. Solids 412, 1–4 (2015)
G. Pathak, S. Pandey, R. Katiyar, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar, Analysis of photoluminescence, UV absorbance, optical band gap and threshold voltage of TiO2 nanoparticles dispersed in high birefringence nematic liquid crystal towards its application in display and photovoltaic devices. J. Lumin. 192, 33–39 (2017)
G. Pathak, R. Katiyar, K. Agrahari, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar, Analysis of birefringence property of three different nematic liquid crystals dispersed with TiO2 nanoparticles. Opto Electron. Rev. 26, 11–18 (2017)
J. Dziaduszek, R. D˛abrowski, S. Urban, K. Garbat, A. Glushchenko, K. Czupryński, Selected fluorosubstituted phenyltolanes with a terminal group: NCS, CN, F, OCF3 and their mesogenic and dielectric properties and use for the formulation of high birefringence nematic mixtures to GHz and THz applications. Liq. Cryst. 44, 1277–1292 (2017)
A.K. Misra, P.K. Tripathi, R. Manohar, Reduction of optical response time for fluorescent dye doped ferroelectric liquid crystal. J. Mol. Liq. 175, 67–71 (2012)
T. Vimal, S. Pandey, S.K. Gupta, D.P. Singh, K. Agrahari, G. Pathak, S. Kumar, P.K. Tripathi, R. Manohar, Manifestation of strong magneto-electric dipolar coupling in ferromagnetic nanoparticles–FLC composite: evaluation of time-dependent memory effect. Liq. Cryst. 45, 687–697 (2017)
P.K. Tripathi, M. Pande, S. Singh, Dielectric and electro-optical properties of polymer-stabilized liquid crystal. II. Polymer PiBMA dispersed in MBBA. Appl. Phys. A. 122, 847–853 (2016)
S. Pandey, T. Vimal, D.P. Singh, S.K. Gupta, G. Pathak, R. Katiyar, R. Manohar, Core/shell quantum dots in ferroelectric liquid crystals matrix: effect of spontaneous polarisation coupling with dopant. Liq. Cryst. 43, 980–993 (2016)
R. Manohar, K.K. Pandey, S.P. Yadav, A.K. Srivastava, A.K. Misra, Surface anchoring effect on guest–host ferroelectric liquid crystal response time—an electro-optical investigation. Philos. Mag. 90(34), 4529–4539 (2010)
D.M. Potukuchi, A.K. George, C. Carboni, S.H. Al-Harthi, J. Naciri, Frequency dielectric relaxation, spontaneous polarization, optical tilt angle and response time investigations in a fluorinated ferroelectric liquid crystal, N125F2(R*). Ferroelectrics 300, 79–93 (2004)
L.M. Blinov, V.G. Chigrinov, Electrooptic Effects in Liquid Crystal Materials (Springer, New York, 1996)
V.S. Chandel, S. Manohar, J.P. Shukla, R. Manohar, Optical studies of a pure and dye doped nematic liquid crystal E-24. Trans. Electr. Electron. Mater. 13, 221–224 (2012)
W. Haase, O. Trinquet, U. Quotschalla, J.K. Foitzik, Properties of guest–host systems with higher concentrations of pleochroic dyes. Mol. Cryst. Liq. Cryst. 148(1), 15–27 (1987)
A.K. Misra, A.K. Srivastava, J.P. Shukla, R. Manohar, Dielectric and electro optical parameters of two ferroelectric liquid crystals: a comparative study. Phys. Scr. 78, 065602 (2008)
Acknowledgements
The authors are thankful to DST for grant of Indo-Polish Project and UPCST for grant of project. We are also thankful to Dr. Swadesh Kumar Gupta, working at Hong Kong University of Science and Technology and Dr. Satya Prakash Yadav, working at Banaras Hindu University, for informative discussion about experiments.
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Pathak, G., Agrahari, K., Yadav, G. et al. Tuning of birefringence, response time, and dielectric anisotropy by the dispersion of fluorescent dye into the nematic liquid crystal. Appl. Phys. A 124, 463 (2018). https://doi.org/10.1007/s00339-018-1878-9
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DOI: https://doi.org/10.1007/s00339-018-1878-9