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Tuning of birefringence, response time, and dielectric anisotropy by the dispersion of fluorescent dye into the nematic liquid crystal

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Abstract

In this study, fluorescent dye benzo 2,1,3 thiadiazole has been dispersed into the pure nematic liquid crystal (NLC) 2020, which is composed of fluorinated 4′-alkylphenyl-4-isothiocyanatotolanes, in three different concentrations. Electro-optical and dielectric parameters have been investigated in the present work. Birefringence has been calculated by transmittance technique for pure and dye-dispersed system, and found to be increased for dispersed system. This is the key finding of the present investigation. In this work, response time has also been calculated by optical switching method and found to be decreased after the dispersion of fluorescent dye into the pure NLC 2020. Contrast ratio has also been measured here and found to be increased for the dispersed system. Relative permittivity has been found to be decreased after the dispersion of dye. Dielectric anisotropy has also been calculated for pure NLC and dye–NLC dispersed system, and found to be decreased for dispersed system. The present investigation may be helpful in the improvement of response time of liquid crystal-based devices.

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References

  1. R. Muenster, M. Jarasch, X. Zhuang, Y.R. Shen, Dye-induced enhancement of optical nonlinearity in liquids and liquid crystals. Appl. Phys. Lett. 78, 42–46 (1997)

    Article  Google Scholar 

  2. B.Ya.. Zel’dovich, N.F. Pilipetskii, A.V. Sukhov, N.V. Tabiryan, Sov. Phys. JETP Lett. 31, 263 (1980)

    ADS  Google Scholar 

  3. S.D. Durbin, S.M. Arakelian, Y.R. Shen, Phys. Rev. Lett. 47, 1411 (1981)

    Article  ADS  Google Scholar 

  4. L. Marrucci, Y.R. Shen, in The Optics of Thermotropic Liquid Crystals, ed. by R. Sambles, S. Elston (Taylor & Francis, London, 1998)

    Google Scholar 

  5. A.S. Zolot’ko, V.F. Kitaeva, N. Kroo, N.I. Sobolev, L. Csillag, Sov. Phys. JETP Lett. 32, 158 (1980)

    ADS  Google Scholar 

  6. S. Varghese, S. Narayanankutty, C.W.M. Bastiaansen, G.P. Crawford, D.J. Broer, Patterned alignment of liquid crystals by m-rubbing. Adv. Mater. 16, 1600–1605 (2004)

    Article  Google Scholar 

  7. V.A. Konovalov, V.G. Chigrinov, H.S. Kwok, H. Takada, H. Takadsu, Photoaligned vertical aligned nematic mode in liquid crystals. Jpn. J. Appl. Phys. 43, 261–266 (2004)

    Article  ADS  Google Scholar 

  8. S.P. Yadav, K.K. Pandey, A.K. Misra, R. Manohar, Electro-optical behaviour of dye doped nematic liquid crystal. Acta Phys. Pol. A 199, 824–829 (2011)

    Article  Google Scholar 

  9. P.G. de Gennes, J. Prost, The Physics of Liquid Crystals (Oxford University Press, UK, 1993)

    Google Scholar 

  10. M. Pande, P.K. Tripathi, A.K. .Misra, S. Manohar, R. Manohar, S. Singh, Dielectric and electro-optical properties of polymer-stabilized liquid crystal system. Appl. Phys. A. 122, 217–226 (2016)

    Article  ADS  Google Scholar 

  11. I.C. Khoo, Liquid Crystals: Physical Properties and Nonlinear Optical Phenomena (Wiley, New York, 1995)

    Google Scholar 

  12. P. Klysubun, Nonlinear optical studies of dye-doped nematic liquid crystals. Ph.D. Dissertation, Virginia Polytechnic Institute and State University, Virginia (2002)

  13. S. Yilmaz, A. Bozkurt, Spectroscopic measurement of liquid crystal anisotropy in the ultraviolet/visible region. Mater. Chem. Phys. 107, 410–412 (2008)

    Article  Google Scholar 

  14. L. Marrucci, Y.R. Shen, The Optics of Thermotropic Liquid Crystals, ed. by R. Sambles, S. Elston (Taylor and Francis, London, 1997)

    Google Scholar 

  15. I. J´anossy, L. Csillag, A.D. Lloyd, Temperature dependence of the optical Fréedericksz transition in dyed nematic liquid crystals. Phys. Rev. A 44, 8410–8416 (1991)

    Article  ADS  Google Scholar 

  16. I. J´anossy, Molecular interpretation of the absorption-induced optical reorientation of nematic liquid crystals. Phys. Rev. E. 49, 2957–2962 (1994)

    Article  ADS  Google Scholar 

  17. S. Marino, M. Castriota, V. Bruno, E. Cazzanelli, G. Strangi, C. Versace, N. Scaramuzza, Changes of the electro-optic response of nematic liquid crystal cells due to inserted titania–vanadia films. Appl. Phys. 97, 013523–013529 (2005)

    Article  Google Scholar 

  18. C. Motoc, G. Iacobescu, Birefringence of azo-dye doped nematic liquid crystals. J. Optoelectron. Adv. Mater. 8, 295–298 (2006)

    MATH  Google Scholar 

  19. S. Shoarinejad, M.S. Zakerhamidi, Ordering behavior and linear dichroism of pure and doped liquid crystals. Mol. Cryst. Liq. Cryst. 613, 149–155 (2015)

    Article  Google Scholar 

  20. P. Klysubun, G. Indebetouw, Transient and steady state photorefractive responses in dye doped nematic liquid crystal cells. J. Appl. Phys. 91, 897 (2002)

    Article  ADS  Google Scholar 

  21. S. Ghosh, G.O. Carlisle, Carbon nanotube enhanced diffraction efficiency in dye-doped liquid crystal. J. Mat. Sci. Mat. Elect. 16, 753 (2005)

    Article  Google Scholar 

  22. M.T. Sims, R.J. Mandle, J.W. Mandle, J.W. Goodby, M.B. Nielson, Guest–host systems containing anthraquinone dyes with multiple visible transitions giving positive and negative dichroic order parameters: an assessment of principal molecular axes and computational methods. Liq. Cryst. 44, 2029–2045 (2017)

    Google Scholar 

  23. M. Petersen, Jevric, R.J. Mandle, T. Mark, J.N. Sims, S.J. Moore, J.W. Cowling, J.W. Goodby, B. Nielsen, Photoswitching of dihydroazulene derivatives in liquid crystalline host systems. Chem. Eur. J. 23, 5090–5103 (2017)

    Article  Google Scholar 

  24. J. Stephen, C. Cowling, Ellis, J.W. Goodby, Anthraquinone liquid crystal dichroic dyes—a new form of chromonic dye? Liq. Cryst. 38, 1683–1698 (2011)

    Article  Google Scholar 

  25. D.J. Gardiner, H.J. Coles, Organosiloxane liquid crystals for fast-switching bistable scattering devices. J. Phys. D Appl. Phys. 39, 4948–4955 (2006)

    Article  ADS  Google Scholar 

  26. R.J. Mandle, E.A. Davis, C.-C.J. Voll, D.J. Lewis, S.J. Cowling, J.W. Goodby. Self-organisation through size-exclusion in soft materials. J. Mater. Chem. C 3, 2380–2388 (2015)

    Article  Google Scholar 

  27. A.K. Misra, P.K. Tripathi, R. Manohar, Fluorescence, UV absorbance and dielectric studies of fluorescent dye doped ferroelectric liquid crystal. J. Non Cryst. Solids 412, 1–4 (2015)

    Article  ADS  Google Scholar 

  28. G. Pathak, S. Pandey, R. Katiyar, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar, Analysis of photoluminescence, UV absorbance, optical band gap and threshold voltage of TiO2 nanoparticles dispersed in high birefringence nematic liquid crystal towards its application in display and photovoltaic devices. J. Lumin. 192, 33–39 (2017)

    Article  Google Scholar 

  29. G. Pathak, R. Katiyar, K. Agrahari, A. Srivastava, R. Dabrowski, K. Garbat, R. Manohar, Analysis of birefringence property of three different nematic liquid crystals dispersed with TiO2 nanoparticles. Opto Electron. Rev. 26, 11–18 (2017)

    Article  Google Scholar 

  30. J. Dziaduszek, R. D˛abrowski, S. Urban, K. Garbat, A. Glushchenko, K. Czupryński, Selected fluorosubstituted phenyltolanes with a terminal group: NCS, CN, F, OCF3 and their mesogenic and dielectric properties and use for the formulation of high birefringence nematic mixtures to GHz and THz applications. Liq. Cryst. 44, 1277–1292 (2017)

    Article  Google Scholar 

  31. A.K. Misra, P.K. Tripathi, R. Manohar, Reduction of optical response time for fluorescent dye doped ferroelectric liquid crystal. J. Mol. Liq. 175, 67–71 (2012)

    Article  Google Scholar 

  32. T. Vimal, S. Pandey, S.K. Gupta, D.P. Singh, K. Agrahari, G. Pathak, S. Kumar, P.K. Tripathi, R. Manohar, Manifestation of strong magneto-electric dipolar coupling in ferromagnetic nanoparticles–FLC composite: evaluation of time-dependent memory effect. Liq. Cryst. 45, 687–697 (2017)

    Article  Google Scholar 

  33. P.K. Tripathi, M. Pande, S. Singh, Dielectric and electro-optical properties of polymer-stabilized liquid crystal. II. Polymer PiBMA dispersed in MBBA. Appl. Phys. A. 122, 847–853 (2016)

    Article  ADS  Google Scholar 

  34. S. Pandey, T. Vimal, D.P. Singh, S.K. Gupta, G. Pathak, R. Katiyar, R. Manohar, Core/shell quantum dots in ferroelectric liquid crystals matrix: effect of spontaneous polarisation coupling with dopant. Liq. Cryst. 43, 980–993 (2016)

    Article  Google Scholar 

  35. R. Manohar, K.K. Pandey, S.P. Yadav, A.K. Srivastava, A.K. Misra, Surface anchoring effect on guest–host ferroelectric liquid crystal response time—an electro-optical investigation. Philos. Mag. 90(34), 4529–4539 (2010)

    Article  ADS  Google Scholar 

  36. D.M. Potukuchi, A.K. George, C. Carboni, S.H. Al-Harthi, J. Naciri, Frequency dielectric relaxation, spontaneous polarization, optical tilt angle and response time investigations in a fluorinated ferroelectric liquid crystal, N125F2(R*). Ferroelectrics 300, 79–93 (2004)

    Article  Google Scholar 

  37. L.M. Blinov, V.G. Chigrinov, Electrooptic Effects in Liquid Crystal Materials (Springer, New York, 1996)

    Google Scholar 

  38. V.S. Chandel, S. Manohar, J.P. Shukla, R. Manohar, Optical studies of a pure and dye doped nematic liquid crystal E-24. Trans. Electr. Electron. Mater. 13, 221–224 (2012)

    Article  Google Scholar 

  39. W. Haase, O. Trinquet, U. Quotschalla, J.K. Foitzik, Properties of guest–host systems with higher concentrations of pleochroic dyes. Mol. Cryst. Liq. Cryst. 148(1), 15–27 (1987)

    Article  Google Scholar 

  40. A.K. Misra, A.K. Srivastava, J.P. Shukla, R. Manohar, Dielectric and electro optical parameters of two ferroelectric liquid crystals: a comparative study. Phys. Scr. 78, 065602 (2008)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

The authors are thankful to DST for grant of Indo-Polish Project and UPCST for grant of project. We are also thankful to Dr. Swadesh Kumar Gupta, working at Hong Kong University of Science and Technology and Dr. Satya Prakash Yadav, working at Banaras Hindu University, for informative discussion about experiments.

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Correspondence to Rajiv Manohar.

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Pathak, G., Agrahari, K., Yadav, G. et al. Tuning of birefringence, response time, and dielectric anisotropy by the dispersion of fluorescent dye into the nematic liquid crystal. Appl. Phys. A 124, 463 (2018). https://doi.org/10.1007/s00339-018-1878-9

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  • DOI: https://doi.org/10.1007/s00339-018-1878-9

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