Abstract
Ca3Co4O9+δ thin films were prepared on 5° vicinal cut LaAlO3 (001) substrates by pulsed laser deposition and subsequently annealed at various temperatures. Under the irradiation energy density of 8 mJ cm−2, a large laser-induced transverse voltage (LITV) signal with 6.4 V peak voltage and 33 ns rising edge was obtained in the 800 °C annealed film, which was nearly 11 times larger and 2 times faster than that in the as-grown film without annealing (0.54 V, 100 ns). The results suggested that the significant enhancement of LITV by annealing was mainly owing to the improved crystallization and electrical transport property. Based on the LITV results and heat flow model, a nearly intrinsic Seebeck coefficient anisotropy ΔS = |S ab–S c | ≈ 33.4 μV K−1 was obtained, demonstrating the c-axis inclined Ca3Co4O9+δ thin film with large thermopower anisotropy has great application potentials in high sensitive and fast response thermoelectric detectors.
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References
T. Kanno, K. Takahashi, A. Sakai, H. Tamaki, H. Kusada, Y. Yamada, Detection of thermal radiation, sensing of heat flux, and recovery of waste heat by the transverse thermoelectric effect. J. Electron. Mater. 43(6), 2072–2080 (2014)
T. Meier, P. Stathopoulos, P.R. von Rohr, Design and convective calibration of a transverse heat flux sensor. Exp. Heat. Transf. 29(2), 139–150 (2016)
C. Zhou, S. Birne, Y. Tang, K. Heinselaman, M. Grayson, Driving perpendicular heat flow: (p × n)-type transverse thermoelectrics for microscale and cryogenic peltier cooling. Phys. Rev. Lett. 110(22), 227701 (2013). (1–5)
Y. Tang, B. Cui, C. Zhou, M. Grayson, P × N-type transverse thermoelectrics: a novel type of thermal management material. J. Electron. Mater. 44(6), 2095–2104 (2015)
B. Qian, F. Ren, Cooling performance of transverse thermoelectric devices[J]. Int. J. Heat Mass Transf. 95, 787–794 (2016)
H. Lengfellner, G. Kremb, A. Schnellbögl, J. Betz, K.F. Renk, W. Prettl, Giant voltages upon surface heating in normal YBa2Cu3O7-δ films suggesting an atomic layer thermopile. Appl. Phys. Lett. 60(4), 501–503 (1992)
H. Lengfellner, S. Zeuner, W. Prettl, K.F. Renk, Thermoelectric effect in normal-state YBa2Cu3O7-δ films. Europhys. Lett. 25(5), 375–378 (1994)
A.C. Masset, C. Michel, A. Maignan, M. Hervieu, O. Toulemonde, F. Studer, B. Raveau, Misfit-layered cobaltite with an anisotropic giant magnetoresistance: Ca3Co4O9. Phys. Rev. B 62(1), 166–174 (2000)
G. Yang, Q. Ramasse, R.F. Klie, Direct measurement of charge transfer in thermoelectric Ca3Co4O9. Phys. Rev. B 78(15), 153109 (2008)
G.D. Tang, H.H. Guo, T. Yang, D.W. Zhang, X.N. Xu, L.Y. Wang, Z.H. Wang, H.H. Wen, Z.D. Zhang, Y.W. Du, Anisotropic thermopower and magneto thermopower in a misfit-layered calcium cobaltite. Appl. Phys. Lett. 98(20), 202109 (2011). (1–3)
S. Bhattacharya, D.K. Aswal, A. Singh, C. Thinaharan, N. Kulkarni, S.K. Gupta, J.V. Yakhmi, Anisotropic electrical transport studies of Ca3Co4O9 single crystals grown by the flux method. J. Cryst. Growth 277(1), 246–251 (2005)
A. Sakai, T. Kanno, S. Yotsuhashi, A. Odagawa, H. Adachi, Control of epitaxial growth orientation and anisotropic thermoelectric properties of misfit-type Ca3Co4O9 thin films. Jpn. J. Appl. Phys. 44(30), 966–969 (2005)
A. Satake, H. Tanaka, T. Ohkawa, T. Fujii, I. Terasaki, Thermal conductivity of the thermoelectric layered cobalt oxides measured by the Harman method. J. Appl. Phys. 96(1), 931–933 (2004)
S.F. Wang, M.J. Chen, S.R. Zhao, J.C. Chen, L.P. He, W. Yu, J.L. Wang, G.S. Fu, Laser-induced voltage effects in Ca3Co4O9 thin films on tilted LaAlO3 (001) substrates grown by chemical solution deposition. Chin. Phys. B 19(10), 107201 (2010). (1–4)
T. Zahner, R. Schreiner, R. Stierstorfer, O. Kus, S.T. Li, R. Roessler, J.D. Pedarnig, D. Bauerle, H. Lengfellner, Off-diagonal Seebeck effect and anisotropic thermopower in Bi2Sr2CaCu2O8 thin films. Europhys. Lett. 40(6), 673–678 (1997)
L. Yu, Y. Wang, P.X. Zhang, H.U. Habermeier, Epitaxial La0.9Ca0.1MnO3 films grown on vicinal cut substrates for the investigation of resistivity and thermoelectric anisotropy. J. Cryst. Growth 322(1), 41–44 (2011)
X. Liu, M. Zhang, M.G. Cao, Enhancement of laser-induced voltage (LIV) in La2/3Ca1/3MnO3: Ag0.04 films. Appl. Phys. A 123(1), 36 (2017)
S.F. Wang, S.S. Chen, F.Q. Liu, G.Y. Yan, J.C. Chen, H.L. Li, J.L. Wang, W. Yu, G.S. Fu, Laser-induced voltage effects in c-axis inclined NaxCoO2 thin films. Appl. Surf. Sci. 258(19), 7330–7333 (2012)
L. Wang, G. Yan, G. Dong, S. Qiao, G. Fu, S. Wang, Enhanced light-induced transverse thermoelectric effect in c-axis inclined BiCuSeO thin films via Pb doping. Opt. Mater. Express 6(8), 2537–2544 (2016)
K. Takahashi, T. Kanno, A. Sakai, H. Adachi, Y. Yamada, Gigantic transverse voltage induced via off-diagonal thermoelectric effect in CaxCoO2 thin films. Appl. Phys. Lett. 97(2), 021906 (2010). (1–3)
Q. Qiao, A. Gulec, T. Paulauskas, S. Kolesnik, B. Dabrowski, M. Ozdemir, C. Boyraz, D. Mazumdar, A. Gupta, R.F. Klie, Effect of substrate on the atomic structure and physical properties of thermoelectric Ca3Co4O9 thin films. J. Phys. Condens. Mat. 23(30), 305005 (2011). (1–6)
T. Sun, J. Ma, Q.Y. Yan, Y.Z. Huang, J.K. Wang, H.H. Hng, Influence of pulsed laser deposition rate on the microstructure and thermoelectric properties of Ca3Co4O9 thin films. J. Cryst. Growth 311(16), 4123–4128 (2009)
P. Jood, G. Peleckis, X. Wang, S.X. Dou, Thermoelectric properties of Ca3Co4O9 and Ca2.8Bi0.2Co4O9 thin films in their island formation mode. J. Mater. Res. 28(14), 1932–1939 (2013)
P. Brinks, B. Kuiper, E. Breckenfeld, G. Koster, L.W. Martin, G. Rijnders, M. Huijben, Enhanced thermoelectric power factor of NaxCoO2 thin films by structural engineering. Adv. Energy Mater. 4(8), 1301927 (2014). (1-7)
W. Hong, H.N. Lee, M. Yoon, H.M. Christen, D.H. Lowndes, Z. Suo, Z. Zhang, Persistent step-flow growth of strained films on vicinal substrates. Phys. Rev. Lett. 95(5), 095501 (2005)
J. Tersoff, Y.H. Phang, Z. Zhang, M.G. Lagally, Step-bunching instability of vicinal surfaces under stress. Phys. Rev. Lett. 75(14), 2730–2733 (1995)
M. Karppinen, H. Fjellvåg, T. Konno, Y. Morita, T. Motohashi, H. Yamauchi, Evidence for oxygen vacancies in misfit-layered calcium cobalt oxide, [CoCa2O3]qCoO2. Chem. Mater. 16(14), 2790–2793 (2004)
R. Tian, R. Donelson, C.D. Ling, P.E.R. Blanchard, T. Zhang, D. Chu, T.T. Tan, S. Li, Ga substitution and oxygen diffusion kinetics in Ca3Co4O9+δ-based thermoelectric oxides. J. Phys. Chem. C 117(26), 13382–13387 (2013)
M. Sano, S. Horii, I. Matsubara, R. Funahashi, M. Shikano, J. Shimoyama, K. Kishio, Synthesis and thermoelectric properties of magnetically c-axis-oriented [Ca2CoO3-δ]0.62CoO2 bulk with various oxygen contents. Jpn. J. Appl. Phys. 42(2B), 198–200 (2003)
P. Mele, H. Kamei, H. Yasumune, K. Matsumoto, K. Miyazaki, Development of thermoelectric module based on dense Ca3Co4O9 and Zn0.98Al0.02O legs. Met. Mater. Int. 20(2), 389–397 (2014)
L. Yu, Y. Wang, P. Zhang, H.U. Habermeier, Ultrafast transverse thermoelectric response in c-axis inclined epitaxial La0.5Sr0.5CoO3 thin films. Phys. Status Solidi R 7(3), 180–183 (2013)
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We gratefully acknowledge the support for this work from the National Natural Science Foundation of China (Grant No. 51462017, No. 51262016).
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Song, S., Yu, L., Hu, J. et al. Laser-induced transverse voltage effect and thermopower anisotropy of c-axis inclined Ca3Co4O9 thin film. Appl. Phys. A 123, 595 (2017). https://doi.org/10.1007/s00339-017-1188-7
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DOI: https://doi.org/10.1007/s00339-017-1188-7