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Performance efficiency of MIPOH polymers as organic filler on cellulose pulp waste to form cellulosic paper sheets with biological evaluation and computational studies

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Abstract

In this elucidation, we synthesized novel molecularly imprinted polymers (MIPOH1-4) that were used as organic fillers on bagasse pulp to form cellulosic paper sheets, the formation of MIPOH1-4 from the reaction of enaminone 3 with methyl methacrylate monomer in the presence of ethylene glycol dimethyl acrylate and 2,2’-azobisisobutyronitrile. The obtained MIPOH1-4 was confirmed via FT-IR and SEM with different pore sizes. And we noticed that the increase of template 3 increases the hydrogen bond between monomer and template and gave sponge surface of MIPOH4. Furthermore, the computational energies of the template with different monomers utilize DFT/B3LYP/6-31G (d) level to know the stability of polymers and hydrogen bonding between them. So that we applied that in paper manufacture through the adsorption of MIPOH4 as an organic filler on bagasse pulp to form novel cellulosic paper sheets with different concentrations and these sheets which characteristic through FT-IR, SEM, sizing test, tensile strength, and elucidation their antimicrobial activity with theoretical and docking studies. The MIPOH4 and cellulosic paper sheets showed the thermal stability and high tendency of sizability of these paper sheets and concluded the interaction between cellulose fibers of pulp with MIPOH polymer with physical hydrogen bonding.

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Authors and Affiliations

  1. Department of Green Chemistry, National Research Center Dokki, P.O. Box.12622, Cairo, Egypt

    Asmaa M. Fahim

  2. Cellulose and Paper Department, National Research Centre Dokki, P.O. Box.12622, Cairo, Egypt

    Ehab E. Abu-El Magd

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  1. Asmaa M. Fahim
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  2. Ehab E. Abu-El Magd
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Correspondence to Asmaa M. Fahim.

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Fahim, A.M., Abu-El Magd, E.E. Performance efficiency of MIPOH polymers as organic filler on cellulose pulp waste to form cellulosic paper sheets with biological evaluation and computational studies. Polym. Bull. 79, 4099–4131 (2022). https://doi.org/10.1007/s00289-021-03685-y

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  • DOI: https://doi.org/10.1007/s00289-021-03685-y

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